A general strategy for development of a single benzene fluorophore with full-color-tunable, environmentally insensitive, and two-photon solid-state emission

We report here a single-benzene based fluorescent framework, amino-terephthalonitrile, denoted SB-Fluor . This scaffold displays versatile emission wavelength tunability via structure modification, covering the full visible light spectrum, both in the solution and solid state. Moreover, one molecule...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 55; no. 76; pp. 11462 - 11465
Main Authors Xiang, Zhen, Wang, Zhi-Yao, Ren, Tian-Bing, Xu, Wang, Liu, Yu-Peng, Zhang, Xing-Xing, Wu, Peng, Yuan, Lin, Zhang, Xiao-Bing
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 19.09.2019
Royal Society of Chemistry
Subjects
Benzene
chemical reactions
Chemistry
Chemistry, Multidisciplinary
Crystallography
Emission
Fluorescence
fluorescent dyes
Hydrocarbons
Mechanoluminescence
Physical Sciences
Polymorphism
Science & Technology
Solid state
wavelengths
DYES
ABSORPTION
FLUORESCENCE
CHARGE-TRANSFER
PROBES
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Summary:We report here a single-benzene based fluorescent framework, amino-terephthalonitrile, denoted SB-Fluor . This scaffold displays versatile emission wavelength tunability via structure modification, covering the full visible light spectrum, both in the solution and solid state. Moreover, one molecule, SBF3, exhibits polymorphism-dependent reversible mechanochromic luminescence. We report here a single-benzene based fluorescent framework, amino-terephthalonitrile, denoted SB-Fluor .
Bibliography:Electronic supplementary information (ESI) available. CCDC
1875005
For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/c9cc06260b
1875001
and
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c9cc06260b