Rare earth complex dopants in a.c. thin-film electroluminescent cells
The authors have carried out some comparative studies between the different dopants used in thin-film a.c. electroluminescent devices; as well as the Mn 2+ ion leading to high luminosity and long-lived devices, the use of trivalent rare earth ions (Ln 3+ and rare earth fluoride centers LnF 3 (lumoce...
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| Published in | Journal of luminescence Vol. 23; no. 1; pp. 175 - 190 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.1981
|
| Online Access | Get full text |
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| Abstract | The authors have carried out some comparative studies between the different dopants used in thin-film a.c. electroluminescent devices; as well as the Mn
2+ ion leading to high luminosity and long-lived devices, the use of trivalent rare earth ions (Ln
3+ and rare earth fluoride centers LnF
3 (lumocen center) has been investigated.
In the first part the author explain the nature of LnF
3 centers and they have shown that these centers are a new type of luminescent center, which are strongly linked to the ZnS matrix: the authors propose labeling these centers “complex centers”.
In the second part they have searched for other promising centers and have chosen the rare earth oxysulphides Y
2O
2S (Ln) and La
2O
2S (Ln). These compounds have been introduced as complex centers in the ZnS matrix by RF sputtering methods. Using the following trivalent ions: Tm
3+, Tb
3+, Eu
3+, the authors have realized some devices emitting respectively the three basic colours (blue, green, red). The authors have presented some properties of these centers. |
|---|---|
| AbstractList | The authors have carried out some comparative studies between the different dopants used in thin-film a.c. electroluminescent devices; as well as the Mn
2+ ion leading to high luminosity and long-lived devices, the use of trivalent rare earth ions (Ln
3+ and rare earth fluoride centers LnF
3 (lumocen center) has been investigated.
In the first part the author explain the nature of LnF
3 centers and they have shown that these centers are a new type of luminescent center, which are strongly linked to the ZnS matrix: the authors propose labeling these centers “complex centers”.
In the second part they have searched for other promising centers and have chosen the rare earth oxysulphides Y
2O
2S (Ln) and La
2O
2S (Ln). These compounds have been introduced as complex centers in the ZnS matrix by RF sputtering methods. Using the following trivalent ions: Tm
3+, Tb
3+, Eu
3+, the authors have realized some devices emitting respectively the three basic colours (blue, green, red). The authors have presented some properties of these centers. |
| Author | Benoit, J. Blanzat, B. Benalloul, P. |
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| Cites_doi | 10.1016/0025-5408(76)90061-1 10.1016/0025-5408(79)90185-5 10.1016/0038-1098(66)90034-2 10.1016/0022-4596(76)90174-2 10.1103/PhysRev.127.750 10.1116/1.1318401 10.1021/ja01106a052 |
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| References_xml | – volume: 19 start-page: 245 year: 1976 ident: BIB18 publication-title: J. Solid State Chem. contributor: fullname: Niinistö – volume: 75 start-page: 2453 year: 1953 ident: BIB17 publication-title: J. Am. Chem. Soc. contributor: fullname: Templeton – volume: Vol. 17 start-page: 197 year: 1977 ident: BIB1 article-title: Phosphor Films publication-title: Topics in Appl. Phys. Electroluminescence contributor: fullname: Mito – volume: 11 start-page: 1463 year: 1976 ident: BIB11 publication-title: Mat. Res. Bull. contributor: fullname: Blanzat – volume: 127 start-page: 750 year: 1962 ident: BIB15 publication-title: Phys. Rev. contributor: fullname: Judd – volume: 4 start-page: 227 year: 1966 ident: BIB16 publication-title: Solid State Comm. contributor: fullname: Blasse – volume: 14 start-page: 455 year: 1979 ident: BIB19 publication-title: Met. Res. Bull. contributor: fullname: Charreire – year: 1979 ident: BIB12 publication-title: thesis contributor: fullname: Benoit – volume: 10 start-page: 616 year: 1973 ident: BIB20 publication-title: J. Vac. Sci. Technol. contributor: fullname: Buchanan – volume: 11 start-page: 1463 year: 1976 ident: 10.1016/0022-2313(81)90196-4_BIB11 publication-title: Mat. Res. Bull. doi: 10.1016/0025-5408(76)90061-1 contributor: fullname: Benoit – volume: 14 start-page: 455 year: 1979 ident: 10.1016/0022-2313(81)90196-4_BIB19 publication-title: Met. Res. Bull. doi: 10.1016/0025-5408(79)90185-5 contributor: fullname: Leskelä – volume: 4 start-page: 227 year: 1966 ident: 10.1016/0022-2313(81)90196-4_BIB16 publication-title: Solid State Comm. doi: 10.1016/0038-1098(66)90034-2 contributor: fullname: Niewport – ident: 10.1016/0022-2313(81)90196-4_BIB21 – year: 1979 ident: 10.1016/0022-2313(81)90196-4_BIB12 publication-title: thesis contributor: fullname: Benoit – volume: 19 start-page: 245 year: 1976 ident: 10.1016/0022-2313(81)90196-4_BIB18 publication-title: J. Solid State Chem. doi: 10.1016/0022-4596(76)90174-2 contributor: fullname: Leskelä – volume: 127 start-page: 750 year: 1962 ident: 10.1016/0022-2313(81)90196-4_BIB15 publication-title: Phys. Rev. doi: 10.1103/PhysRev.127.750 contributor: fullname: Judd – volume: 10 start-page: 616 year: 1973 ident: 10.1016/0022-2313(81)90196-4_BIB20 publication-title: J. Vac. Sci. Technol. doi: 10.1116/1.1318401 contributor: fullname: Mapple – volume: Vol. 17 start-page: 197 year: 1977 ident: 10.1016/0022-2313(81)90196-4_BIB1 article-title: Phosphor Films contributor: fullname: Inoguchi – ident: 10.1016/0022-2313(81)90196-4_BIB13 – ident: 10.1016/0022-2313(81)90196-4_BIB14 – volume: 75 start-page: 2453 year: 1953 ident: 10.1016/0022-2313(81)90196-4_BIB17 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01106a052 contributor: fullname: Zalkin |
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| Title | Rare earth complex dopants in a.c. thin-film electroluminescent cells |
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