Palladium Supported on Bioinspired Materials as Catalysts for C–C Coupling Reactions

In recent years, the immobilization of palladium nanoparticles on solid supports to prepare active and stable catalytic systems has been deeply investigated. Compared to inorganic materials, naturally occurring organic solids are inexpensive, available and abundant. Moreover, the surface of these so...

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Published inCatalysts Vol. 13; no. 1; p. 210
Main Authors Albano, Gianluigi, Petri, Antonella, Aronica, Laura Antonella
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.01.2023
Subjects
Biomedical materials
Biomimetics
Catalysts
Cellulose
Chelation
Chemical reactions
Chitosan
Covalent bonds
Heterogeneity
Inorganic materials
Mizoroki–Heck reaction
Morphology
Nanocrystals
Nanoparticles
Organic solids
Palladium
palladium catalyst
Pectin
polysaccharide
protein
Recyclability
Solvents
Sonogashira reaction
Suzuki–Miyaura reaction
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Abstract In recent years, the immobilization of palladium nanoparticles on solid supports to prepare active and stable catalytic systems has been deeply investigated. Compared to inorganic materials, naturally occurring organic solids are inexpensive, available and abundant. Moreover, the surface of these solids is fully covered by chelating groups which can stabilize the metal nanoparticles. In the present review, we have focused our attention on natural biomaterials-supported metal catalysts applied to the formation of C–C bonds by Mizoroki–Heck, Suzuki–Miyaura and Sonogashira reactions. A systematic approach based on the nature of the organic matrix will be followed: (i) metal catalysts supported on cellulose; (ii) metal catalysts supported on starch; (iii) metal catalysts supported on pectin; (iv) metal catalysts supported on agarose; (v) metal catalysts supported on chitosan; (vi) metal catalysts supported on proteins and enzymes. We will emphasize the effective heterogeneity and recyclability of each catalyst, specifying which studies were carried out to evaluate these aspects.
AbstractList In recent years, the immobilization of palladium nanoparticles on solid supports to prepare active and stable catalytic systems has been deeply investigated. Compared to inorganic materials, naturally occurring organic solids are inexpensive, available and abundant. Moreover, the surface of these solids is fully covered by chelating groups which can stabilize the metal nanoparticles. In the present review, we have focused our attention on natural biomaterials-supported metal catalysts applied to the formation of C–C bonds by Mizoroki–Heck, Suzuki–Miyaura and Sonogashira reactions. A systematic approach based on the nature of the organic matrix will be followed: (i) metal catalysts supported on cellulose; (ii) metal catalysts supported on starch; (iii) metal catalysts supported on pectin; (iv) metal catalysts supported on agarose; (v) metal catalysts supported on chitosan; (vi) metal catalysts supported on proteins and enzymes. We will emphasize the effective heterogeneity and recyclability of each catalyst, specifying which studies were carried out to evaluate these aspects.
Author Aronica, Laura Antonella
Petri, Antonella
Albano, Gianluigi
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  surname: Aronica
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SSID ssj0000913815
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Snippet In recent years, the immobilization of palladium nanoparticles on solid supports to prepare active and stable catalytic systems has been deeply investigated....
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crossref
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StartPage 210
SubjectTerms Biomedical materials
Biomimetics
Catalysts
Cellulose
Chelation
Chemical reactions
Chitosan
Covalent bonds
Heterogeneity
Inorganic materials
Mizoroki–Heck reaction
Morphology
Nanocrystals
Nanoparticles
Organic solids
Palladium
palladium catalyst
Pectin
polysaccharide
protein
Recyclability
Solvents
Sonogashira reaction
Suzuki–Miyaura reaction
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Title Palladium Supported on Bioinspired Materials as Catalysts for C–C Coupling Reactions
URI https://www.proquest.com/docview/2767193203
https://doaj.org/article/584c230f1cbc41ef918fc626c783a3dc
Volume 13
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