From Alkynes to Heterocycles through Metal-Promoted Silylformylation and Silylcarbocyclization Reactions

Oxygen and nitrogen heterocyclic systems are present in a large number of natural and synthetic compounds. In particular, oxa- and aza-silacyclane, tetrahydrofuran, benzofuran, cycloheptadifuranone, cycloheptadipyrrolone, pyrrolidine, lactone, lactam, phthalan, isochromanone, tetrahydroisoquinolinon...

Full description

Saved in:
Bibliographic Details
Published inCatalysts Vol. 10; no. 9; p. 1012
Main Authors Albano, Gianluigi, Aronica, Laura Antonella
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.09.2020
Subjects
Alkynes
Amides
Carbon
Carbonyls
Catalysts
Chemical bonds
Chemical reactions
Chemical synthesis
Functional groups
Heterocyclic compounds
N-heterocycles
O-heterocycles
silylcarbocyclization
silylformylation
Tetrahydrofuran
Online AccessGet full text

Cover

Abstract Oxygen and nitrogen heterocyclic systems are present in a large number of natural and synthetic compounds. In particular, oxa- and aza-silacyclane, tetrahydrofuran, benzofuran, cycloheptadifuranone, cycloheptadipyrrolone, pyrrolidine, lactone, lactam, phthalan, isochromanone, tetrahydroisoquinolinone, benzoindolizidinone, indoline and indolizidine scaffolds are present in many classes of biologically active molecules. Most of these contain a C=O moiety which can be easily introduced using carbonylative reaction conditions. In this field, intramolecular silylformylation and silylcarbocyclization reactions may afford heterocyclic compounds containing a carbonyl functional group together with a vinylsilane moiety which can be further transformed. Considering these two aspects, in this review a detailed analysis of the literature data regarding the application of silylformylation and silylcarbocyclization reactions to the synthesis of several heterocyclic derivatives is reported.
AbstractList Oxygen and nitrogen heterocyclic systems are present in a large number of natural and synthetic compounds. In particular, oxa- and aza-silacyclane, tetrahydrofuran, benzofuran, cycloheptadifuranone, cycloheptadipyrrolone, pyrrolidine, lactone, lactam, phthalan, isochromanone, tetrahydroisoquinolinone, benzoindolizidinone, indoline and indolizidine scaffolds are present in many classes of biologically active molecules. Most of these contain a C=O moiety which can be easily introduced using carbonylative reaction conditions. In this field, intramolecular silylformylation and silylcarbocyclization reactions may afford heterocyclic compounds containing a carbonyl functional group together with a vinylsilane moiety which can be further transformed. Considering these two aspects, in this review a detailed analysis of the literature data regarding the application of silylformylation and silylcarbocyclization reactions to the synthesis of several heterocyclic derivatives is reported.
Author Aronica, Laura Antonella
Albano, Gianluigi
Author_xml – sequence: 1
  givenname: Gianluigi
  orcidid: 0000-0002-2466-5598
  surname: Albano
  fullname: Albano, Gianluigi
– sequence: 2
  givenname: Laura Antonella
  orcidid: 0000-0002-1771-2667
  surname: Aronica
  fullname: Aronica, Laura Antonella
BookMark eNpVkUtPwkAQxzdGExE5em_iubrPbnskRIQEo_Fx3uxjCsXSxW051E9vS4nRzGHn8Zv_zGau0HnlK0DohuA7xjJ8b3WjS4JxRjChZ2hEsWQxZ5yf__Ev0aSutxj3GEuJGKHNPPhdNC0_2wrqqPHRAhoI3ra27ONN8If1JnqCTjx-6VDfgIveirItcx92bambwleRrk5Jq4M5NhffQ-UVtO2d-hpd5LqsYXJ6x-hj_vA-W8Sr58flbLqKLZO4iSmxwtA8weAymkCSEUqozDQ3XEjIhcmtsB0gpdFSJ06YFJwF7AByngrGxmg56Dqvt2ofip0OrfK6UMeED2ulQ1N031OEZiljzBAuHHcZSY0BmQJzzORGaNtp3Q5a--C_DlA3ausPoerWV5RzLElnoqPigbLB13WA_Hcqwaq_jfp3G_YDRrqGdw
CitedBy_id crossref_primary_10_3390_catal12040353
crossref_primary_10_3390_catal11060706
crossref_primary_10_1021_acs_orglett_1c02364
crossref_primary_10_1016_j_jorganchem_2022_122481
crossref_primary_10_3390_molecules25245950
crossref_primary_10_1016_j_ica_2023_121763
crossref_primary_10_1039_D1CC02176A
crossref_primary_10_3390_catal11121531
crossref_primary_10_3390_molecules26247544
crossref_primary_10_1021_acs_orglett_1c03141
crossref_primary_10_3390_molecules27030630
crossref_primary_10_2139_ssrn_4112837
crossref_primary_10_3390_catal12010068
Cites_doi 10.1016/j.ijantimicag.2006.09.003
10.1021/om00016a012
10.1021/om970549f
10.1016/S0040-4020(98)00160-4
10.1021/om00047a021
10.1080/10408410902733979
10.1016/0040-4039(95)01894-N
10.1016/0040-4039(94)02182-B
10.1021/jo034064e
10.1021/jo101790z
10.7164/antibiotics.45.240
10.1002/slct.201900524
10.1055/s-2001-9739
10.1002/3527604693
10.1021/cr3001803
10.1021/jo502265a
10.1016/0022-328X(96)06359-0
10.1070/MC1995v005n06ABEH000534
10.1016/j.tet.2007.04.064
10.1021/ol035895+
10.7164/antibiotics.53.1022
10.1021/cr200164y
10.1016/j.jorganchem.2006.04.030
10.1023/A:1013837417361
10.1039/c39760000679
10.1021/ol016153o
10.1021/ja00373a055
10.1007/s11882-016-0594-9
10.1039/C5CY00691K
10.1021/ja993977g
10.1021/ja00172a033
10.1002/9783527619979
10.1016/j.tetlet.2016.03.083
10.1021/acs.orglett.8b00742
10.1021/om060478x
10.1002/ejoc.201700455
10.1002/ejoc.200701219
10.1016/j.jorganchem.2009.12.018
10.1021/ol302221s
10.1246/cl.2001.650
10.1021/ja0258982
10.1021/ja00042a061
10.1039/c39760000734
10.1021/ol0156594
10.1111/j.1600-0463.2009.02563.x
10.1021/ja00120a033
10.1055/s-0033-1339136
10.1021/ol048500a
10.1021/ja00087a078
10.1016/S0040-4039(00)02234-6
10.1055/s-0037-1609175
10.1021/ja9815529
10.1021/om9904549
10.1007/BF00702749
10.1021/ja00188a074
10.1016/j.tet.2009.10.112
10.1002/anie.201208330
10.1021/om960112s
10.1021/ja9063475
10.1021/jm0580510
10.1016/1381-1169(95)00130-1
10.1002/1099-0690(200004)2000:7<1131::AID-EJOC1131>3.0.CO;2-1
10.1002/ejoc.201701041
10.1002/ejoc.201601392
10.1016/j.tet.2003.04.004
10.1021/ja026511y
10.1055/s-1996-5441
10.1016/0040-4039(91)80126-Q
10.1021/om00162a026
10.1021/om049677b
10.1021/ar5000055
10.3390/catal10010025
10.1002/1099-0690(200111)2001:22<4321::AID-EJOC4321>3.0.CO;2-T
10.1002/hlca.19830660802
10.1002/ejoc.200500883
10.1002/slct.201601736
10.1016/S0040-4039(01)01086-3
10.1016/S0040-4020(01)93277-6
10.2174/138527206778018230
10.1021/ja054221m
10.1039/C9CC07197K
10.1016/S0040-4039(02)01178-4
10.1021/om00017a015
10.1016/j.tetlet.2008.12.060
10.1016/S0020-1693(97)82717-X
10.1021/ol500051e
10.1021/om0342560
10.1021/jo0351062
10.1016/j.jorganchem.2011.11.008
10.1021/ja980907l
10.3390/catal10050510
10.3390/catal10040434
10.1351/pac200274010159
10.1021/jo00104a012
10.1016/j.tetlet.2005.11.054
10.1021/jo991129y
10.1016/S0040-4020(01)87260-4
10.1007/s10562-019-02959-5
10.1016/S0020-1693(97)05855-6
10.1021/ar400222k
10.1021/om00025a005
10.1021/ja067854p
10.1016/S0065-2725(10)09904-6
10.1021/ol802489w
10.1021/acs.orglett.5b03034
10.1021/ja00130a027
10.1021/om960471n
10.1016/0040-4020(79)87006-4
10.1016/j.tet.2006.04.065
10.1021/acs.joc.0c01282
10.1002/anie.201400793
10.1016/S0040-4039(99)00849-7
10.1016/j.apcata.2014.04.029
ContentType Journal Article
Copyright 2020. This work is licensed under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
Copyright_xml – notice: 2020. This work is licensed under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
DBID AAYXX
CITATION
7SR
8BQ
8FD
8FE
8FG
ABJCF
ABUWG
AFKRA
AZQEC
BENPR
BGLVJ
CCPQU
D1I
DWQXO
HCIFZ
JG9
KB.
PDBOC
PIMPY
PQEST
PQQKQ
PQUKI
PRINS
DOA
DOI 10.3390/catal10091012
DatabaseName CrossRef
Engineered Materials Abstracts
METADEX
Technology Research Database
ProQuest SciTech Collection
ProQuest Technology Collection
Materials Science & Engineering Collection
ProQuest Central (Alumni)
ProQuest Central UK/Ireland
ProQuest Central Essentials
AUTh Library subscriptions: ProQuest Central
Technology Collection
ProQuest One Community College
ProQuest Materials Science Collection
ProQuest Central
SciTech Premium Collection (Proquest) (PQ_SDU_P3)
Materials Research Database
Materials Science Database
Materials Science Collection
Publicly Available Content Database
ProQuest One Academic Eastern Edition (DO NOT USE)
ProQuest One Academic
ProQuest One Academic UKI Edition
ProQuest Central China
DOAJ Directory of Open Access Journals
DatabaseTitle CrossRef
Publicly Available Content Database
ProQuest Materials Science Collection
Materials Research Database
Technology Collection
Technology Research Database
ProQuest Central Essentials
ProQuest One Academic Eastern Edition
Materials Science Collection
ProQuest Central (Alumni Edition)
SciTech Premium Collection
ProQuest One Community College
ProQuest Technology Collection
ProQuest SciTech Collection
ProQuest Central China
METADEX
ProQuest Central
Engineered Materials Abstracts
ProQuest One Academic UKI Edition
ProQuest Central Korea
Materials Science & Engineering Collection
Materials Science Database
ProQuest One Academic
DatabaseTitleList
Publicly Available Content Database
CrossRef
Database_xml – sequence: 1
  dbid: DOA
  name: Directory of Open Access Journals
  url: https://www.doaj.org/
  sourceTypes: Open Website
– sequence: 2
  dbid: 8FG
  name: ProQuest Technology Collection
  url: https://search.proquest.com/technologycollection1
  sourceTypes: Aggregation Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 2073-4344
ExternalDocumentID oai_doaj_org_article_1298333b145d4d918bbe78e3d3bfb5ac
10_3390_catal10091012
GroupedDBID 5VS
8FE
8FG
AADQD
AAFWJ
AAYXX
ABDBF
ABJCF
ADBBV
AENEX
AFKRA
AFPKN
AFZYC
ALMA_UNASSIGNED_HOLDINGS
BCNDV
BENPR
BGLVJ
CCPQU
CITATION
D1I
ESX
GROUPED_DOAJ
HCIFZ
IAO
KB.
KQ8
MODMG
M~E
OK1
PDBOC
PIMPY
PROAC
RIG
7SR
8BQ
8FD
ABUWG
AZQEC
DWQXO
JG9
PQEST
PQQKQ
PQUKI
PRINS
ID FETCH-LOGICAL-c370t-21c5b2f60ed926e69121279a4b457ef5bfc5cb2f77ba7a6d5b8edce0deef48533
IEDL.DBID DOA
ISSN 2073-4344
IngestDate Mon Oct 07 19:33:23 EDT 2024
Thu Oct 10 14:55:22 EDT 2024
Thu Sep 26 21:31:47 EDT 2024
IsDoiOpenAccess true
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 9
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c370t-21c5b2f60ed926e69121279a4b457ef5bfc5cb2f77ba7a6d5b8edce0deef48533
ORCID 0000-0002-2466-5598
0000-0002-1771-2667
OpenAccessLink https://doaj.org/article/1298333b145d4d918bbe78e3d3bfb5ac
PQID 2440717175
PQPubID 2032420
ParticipantIDs doaj_primary_oai_doaj_org_article_1298333b145d4d918bbe78e3d3bfb5ac
proquest_journals_2440717175
crossref_primary_10_3390_catal10091012
PublicationCentury 2000
PublicationDate 2020-09-01
PublicationDateYYYYMMDD 2020-09-01
PublicationDate_xml – month: 09
  year: 2020
  text: 2020-09-01
  day: 01
PublicationDecade 2020
PublicationPlace Basel
PublicationPlace_xml – name: Basel
PublicationTitle Catalysts
PublicationYear 2020
Publisher MDPI AG
Publisher_xml – name: MDPI AG
References Chatani (ref_1) 1996; 1996
Wiese (ref_10) 2006; 18
Bonafoux (ref_58) 2001; 3
Ojima (ref_72) 1996; 521
Franke (ref_11) 2012; 112
Bennacer (ref_87) 2005; 127
Zhou (ref_33) 1994; 13
Fukuta (ref_74) 1999; 40
Matsuda (ref_83) 1995; 36
ref_15
Denmark (ref_79) 2011; 76
Zhou (ref_32) 1996; 15
Biffis (ref_24) 2010; 695
Aronica (ref_51) 2014; 480
Ojima (ref_85) 2000; 122
Aronica (ref_92) 2010; 66
Murai (ref_76) 2006; 62
Harrison (ref_65) 2012; 14
Yoshikai (ref_29) 2006; 25
Jain (ref_40) 1995; 36
Aronica (ref_5) 2008; 2008
Ojima (ref_26) 1993; 49
Ojima (ref_82) 1998; 120
Basato (ref_23) 2006; 691
Shibata (ref_84) 2004; 23
Konishi (ref_117) 2014; 25
Ojima (ref_69) 2002; 19
Albano (ref_116) 2020; 85
Bonafoux (ref_59) 2001; 3
Okazaki (ref_34) 2001; 30
Eilbracht (ref_41) 2000; 2000
Albano (ref_94) 2017; 2017
Denmark (ref_45) 1982; 104
Ojima (ref_56) 1995; 117
Romano (ref_97) 2016; 16
Ojima (ref_25) 1991; 10
Aronica (ref_17) 2006; 2006
Monteil (ref_47) 1995; 117
Ojima (ref_108) 1990; 9
Ojima (ref_68) 2002; 74
Bouthillier (ref_99) 1992; 45
Ojima (ref_81) 1996; 15
Jung (ref_43) 1979; 35
Broccolo (ref_98) 2006; 49
Albano (ref_109) 2019; 4
ref_57
Golemi (ref_102) 2000; 53
Spletstoser (ref_63) 2008; 10
Rolinson (ref_101) 2007; 29
Ojima (ref_71) 1992; 114
Xu (ref_110) 2014; 47
Beller (ref_6) 1995; 104
Matsuda (ref_16) 1989; 111
Fleming (ref_39) 1981; 37
Shahid (ref_96) 2009; 35
Bennacer (ref_86) 2004; 6
Denmark (ref_60) 2003; 68
Zhu (ref_104) 2015; 80
Aronica (ref_114) 2017; 2017
Ojima (ref_73) 2002; 124
Ojima (ref_37) 1994; 116
Aronica (ref_35) 2001; 2001
Denmark (ref_78) 2009; 131
Ojima (ref_107) 1996; 251
Knochel (ref_13) 2014; Volume 4
Varchi (ref_70) 2006; 10
Donskaya (ref_20) 1995; 5
Matsuda (ref_2) 1997; 16
Doyle (ref_31) 1993; 12
Ojima (ref_55) 1999; 18
Wu (ref_14) 2014; 47
Albano (ref_113) 2017; 2017
Gilmore (ref_49) 2011; 111
ref_115
Gautam (ref_119) 2015; 5
Ojima (ref_80) 1994; 59
Foley (ref_67) 2015; 17
Zacuto (ref_62) 2003; 59
Sinner (ref_100) 2019; 55
Ojima (ref_88) 1999; 121
Aronica (ref_46) 2002; 43
ref_112
Albano (ref_111) 2018; 50
Doyle (ref_30) 1994; 13
Pospech (ref_12) 2013; 52
Basato (ref_22) 2004; 23
ref_38
Hollmann (ref_42) 1998; 54
Alonso (ref_21) 2001; 42
Matsuda (ref_89) 1990; 112
Wu (ref_118) 2014; 53
Ojima (ref_28) 1998; 270
Jones (ref_44) 1983; 66
Albano (ref_53) 2020; 150
Denmark (ref_77) 2007; 129
Liang (ref_103) 2009; 50
Albano (ref_52) 2017; 2
Katritzky (ref_54) 2010; Volume 99
Zacuto (ref_61) 2002; 124
Kim (ref_64) 2008; 10
Zhang (ref_106) 2018; 20
Kong (ref_95) 2010; 118
Aronica (ref_19) 2006; 47
Foley (ref_66) 2014; 16
Aronica (ref_36) 2007; 63
ref_3
Ojima (ref_27) 1992; 3
Breit (ref_9) 2001; 2001
Matsuda (ref_90) 1991; 32
ref_48
Park (ref_75) 2003; 5
Hussein (ref_105) 2016; 57
ref_8
Aronica (ref_50) 1999; 64
Aronica (ref_18) 2003; 68
ref_4
Aronica (ref_93) 2012; 700
ref_7
Fukuta (ref_91) 2001; 42
References_xml – volume: 29
  start-page: 3
  year: 2007
  ident: ref_101
  article-title: The 50th anniversary of the discovery of 6-aminopenicillanic acid (6-APA)
  publication-title: Int. J. Antimicrob. Agents
  doi: 10.1016/j.ijantimicag.2006.09.003
  contributor:
    fullname: Rolinson
– volume: 13
  start-page: 1081
  year: 1994
  ident: ref_30
  article-title: Highly Regioselective and stereoselective silylformylation of alkynes under mild conditions promoted by dirhodium(II) perfluorobutyrate
  publication-title: Organometallics
  doi: 10.1021/om00016a012
  contributor:
    fullname: Doyle
– volume: 16
  start-page: 4327
  year: 1997
  ident: ref_2
  article-title: Rhodium-catalyzed silylformylation of Acetylenic bonds: Its scope and mechanistic considerations
  publication-title: Organometallics
  doi: 10.1021/om970549f
  contributor:
    fullname: Matsuda
– volume: 54
  start-page: 4493
  year: 1998
  ident: ref_42
  article-title: Rhodium(I)-catalysed hydrocarbonylation and silylcarbonylation reactions of alkynes in the presence of primary amines leading to 2-pyrrolidinones and 4-silylated 1-aza-1,3-butadienes
  publication-title: Tetrahedron
  doi: 10.1016/S0040-4020(98)00160-4
  contributor:
    fullname: Hollmann
– volume: 10
  start-page: 38
  year: 1991
  ident: ref_25
  article-title: Silylformylation of 1-hexyne catalyzed by rhodium-cobalt mixed-metal carbonyl clusters
  publication-title: Organometallics
  doi: 10.1021/om00047a021
  contributor:
    fullname: Ojima
– volume: 35
  start-page: 81
  year: 2009
  ident: ref_96
  article-title: Beta-lactams and Beta-lactamase-inhibitors in current-or potential-clinical practice: A comprehensive update
  publication-title: Crit. Rev. Microbiol.
  doi: 10.1080/10408410902733979
  contributor:
    fullname: Shahid
– volume: 36
  start-page: 8723
  year: 1995
  ident: ref_40
  article-title: An efficient procedure for the preparation of chiral β-substituted (E)-crotylsilanes: Application of a rhodium(II) catalyzed silylformylation of terminal alkynes
  publication-title: Tetrahedron Lett.
  doi: 10.1016/0040-4039(95)01894-N
  contributor:
    fullname: Jain
– volume: 36
  start-page: 241
  year: 1995
  ident: ref_83
  article-title: Silylative cyclocarbonylation of acetylenic bonds catalyzed by Rh4(CO)12: An easy access to bicyclo[3.3.0]octenone skeletons
  publication-title: Tetrahedron Lett.
  doi: 10.1016/0040-4039(94)02182-B
  contributor:
    fullname: Matsuda
– volume: 10
  start-page: 5593
  year: 2008
  ident: ref_64
  article-title: A More comprehensive and highly practical solution to enantioselective aldehyde crotylation
  publication-title: Org. Lett.
  contributor:
    fullname: Kim
– volume: 68
  start-page: 5153
  year: 2003
  ident: ref_60
  article-title: Tandem Intramolecular silylformylation and silicon-assisted cross-coupling reactions. Synthesis of geometrically defined α,β-unsaturated aldehydes
  publication-title: J. Org. Chem.
  doi: 10.1021/jo034064e
  contributor:
    fullname: Denmark
– ident: ref_4
– volume: 76
  start-page: 201
  year: 2011
  ident: ref_79
  article-title: Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy
  publication-title: J. Org. Chem.
  doi: 10.1021/jo101790z
  contributor:
    fullname: Denmark
– volume: 45
  start-page: 240
  year: 1992
  ident: ref_99
  article-title: The synthesis, antibacterial, and beta-lactamase inhibitory activity of a novel asparenomycin analog
  publication-title: J. Antibiot.
  doi: 10.7164/antibiotics.45.240
  contributor:
    fullname: Bouthillier
– volume: 4
  start-page: 2505
  year: 2019
  ident: ref_109
  article-title: Synthesis of functionalised indoline and isoquinoline derivatives through a silylcarbocyclisation/desilylation sequence
  publication-title: ChemistrySelect
  doi: 10.1002/slct.201900524
  contributor:
    fullname: Albano
– volume: 2001
  start-page: 0001
  year: 2001
  ident: ref_9
  article-title: Recent advances on chemo-, regio-and stereoselective hydroformylation
  publication-title: Synthesis
  doi: 10.1055/s-2001-9739
  contributor:
    fullname: Breit
– ident: ref_3
  doi: 10.1002/3527604693
– volume: 112
  start-page: 5675
  year: 2012
  ident: ref_11
  article-title: Applied hydroformylation
  publication-title: Chem. Rev.
  doi: 10.1021/cr3001803
  contributor:
    fullname: Franke
– volume: 80
  start-page: 628
  year: 2015
  ident: ref_104
  article-title: Synthesis of α-methylene-β-lactams via PPh3-catalyzed umpolung cyclization of propiolamides
  publication-title: J. Org. Chem.
  doi: 10.1021/jo502265a
  contributor:
    fullname: Zhu
– volume: 521
  start-page: 421
  year: 1996
  ident: ref_72
  article-title: New cascade silylcarbocyclization (SiCaC) of enediynes
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(96)06359-0
  contributor:
    fullname: Ojima
– volume: 5
  start-page: 220
  year: 1995
  ident: ref_20
  article-title: Silylformylation of alkynes catalysed by Di-μ-chlorotetrakis(η2-methylene-cyclopropane)dirhodium
  publication-title: Mendeleev Commun.
  doi: 10.1070/MC1995v005n06ABEH000534
  contributor:
    fullname: Donskaya
– volume: 63
  start-page: 6843
  year: 2007
  ident: ref_36
  article-title: Silylation–desilylation of propargyl amides: Rapid synthesis of functionalised aldehydes and β-lactams
  publication-title: Tetrahedron
  doi: 10.1016/j.tet.2007.04.064
  contributor:
    fullname: Aronica
– volume: 5
  start-page: 4967
  year: 2003
  ident: ref_75
  article-title: Immobilized cobalt/rhodium heterobimetallic nanoparticle-catalyzed silylcarbocylization and carbonylative silylcarbocyclization of 1,6-enynes
  publication-title: Org. Lett.
  doi: 10.1021/ol035895+
  contributor:
    fullname: Park
– volume: 53
  start-page: 1022
  year: 2000
  ident: ref_102
  article-title: 6-(hydroxyalkyl)penicillanates as probes for mechanisms of beta-lactamases
  publication-title: J. Antibiot.
  doi: 10.7164/antibiotics.53.1022
  contributor:
    fullname: Golemi
– volume: 111
  start-page: 6513
  year: 2011
  ident: ref_49
  article-title: Cyclizations of alkynes: Revisiting baldwin’s rules for ring closure
  publication-title: Chem. Rev.
  doi: 10.1021/cr200164y
  contributor:
    fullname: Gilmore
– volume: 691
  start-page: 3464
  year: 2006
  ident: ref_23
  article-title: Cationic complexes of dirhodium(II) with 1,8-naphthyridine: Catalysis of reactions involving silanes
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2006.04.030
  contributor:
    fullname: Basato
– volume: 19
  start-page: 89
  year: 2002
  ident: ref_69
  article-title: Recent advances in rhodium-catalyzed cyclization reactions
  publication-title: Top. Catal.
  doi: 10.1023/A:1013837417361
  contributor:
    fullname: Ojima
– ident: ref_38
  doi: 10.1039/c39760000679
– volume: 3
  start-page: 2333
  year: 2001
  ident: ref_59
  article-title: Novel DMAP-Catalyzed Skeletal Rearrangement of 5-exo-(2-Hydroxy- ethylene)oxasilacyclopentanes
  publication-title: Org. Lett.
  doi: 10.1021/ol016153o
  contributor:
    fullname: Bonafoux
– volume: 104
  start-page: 2642
  year: 1982
  ident: ref_45
  article-title: Silicon-directed Nazarov cyclization
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00373a055
  contributor:
    fullname: Denmark
– volume: 16
  start-page: 24
  year: 2016
  ident: ref_97
  article-title: Cross-reactivity among beta-lactams
  publication-title: Curr. Allergy Asthma Rep.
  doi: 10.1007/s11882-016-0594-9
  contributor:
    fullname: Romano
– volume: 5
  start-page: 4663
  year: 2015
  ident: ref_119
  article-title: Recent advances in the transition metal catalyzed carbonylation of alkynes, arenes and aryl halides using CO surrogates
  publication-title: Catal. Sci. Technol.
  doi: 10.1039/C5CY00691K
  contributor:
    fullname: Gautam
– volume: 122
  start-page: 2385
  year: 2000
  ident: ref_85
  article-title: Rhodium-catalyzed novel carbonylative carbotricyclization of enediynes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja993977g
  contributor:
    fullname: Ojima
– volume: 112
  start-page: 6120
  year: 1990
  ident: ref_89
  article-title: Ready access of .alpha.-(triorganosilyl)methylene .beta.-lactones by means of rhodium-catalyzed cyclocarbonylation of substituted propargyl alcohols
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00172a033
  contributor:
    fullname: Matsuda
– ident: ref_7
  doi: 10.1002/9783527619979
– volume: 57
  start-page: 1990
  year: 2016
  ident: ref_105
  article-title: A new direct synthesis of α-methylene- and α-alkylidene-β-lactams
  publication-title: Tetrahedron Lett.
  doi: 10.1016/j.tetlet.2016.03.083
  contributor:
    fullname: Hussein
– volume: 20
  start-page: 2407
  year: 2018
  ident: ref_106
  article-title: Synthesis of α-methylene-β-lactams enabled by base-promoted intramolecular 1,2-addition of N-propiolamide and C–C bond migrating cleavage of aziridine
  publication-title: Org. Lett.
  doi: 10.1021/acs.orglett.8b00742
  contributor:
    fullname: Zhang
– volume: 25
  start-page: 3867
  year: 2006
  ident: ref_29
  article-title: Bimetallic synergism in alkyne silylformylation catalyzed by a cobalt−rhodium mixed-metal cluster
  publication-title: Organometallics
  doi: 10.1021/om060478x
  contributor:
    fullname: Yoshikai
– volume: 2017
  start-page: 3473
  year: 2017
  ident: ref_94
  article-title: Synthesis of functionalised 3-isochromanones by silylcarbocyclisation/desilylation reactions
  publication-title: Eur. J. Org. Chem.
  doi: 10.1002/ejoc.201700455
  contributor:
    fullname: Albano
– volume: 2008
  start-page: 3039
  year: 2008
  ident: ref_5
  article-title: Synthesis and reactivity of silylformylation products derived from alkynes
  publication-title: Eur. J. Org. Chem.
  doi: 10.1002/ejoc.200701219
  contributor:
    fullname: Aronica
– volume: 695
  start-page: 792
  year: 2010
  ident: ref_24
  article-title: Highly selective silylformylation of internal and functionalised alkynes with a cationic dirhodium(II) complex catalyst
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2009.12.018
  contributor:
    fullname: Biffis
– volume: 14
  start-page: 4890
  year: 2012
  ident: ref_65
  article-title: An “aprotic” tamao oxidation/syn-selective tautomerization reaction for the efficient synthesis of the C(1)–C(9) fragment of fludelone
  publication-title: Org. Lett.
  doi: 10.1021/ol302221s
  contributor:
    fullname: Harrison
– volume: 30
  start-page: 650
  year: 2001
  ident: ref_34
  article-title: The Silylformylation of simple 1-alkynes catalyzed by [Rh(cod)][BPh4] in an Ionic liquid, [Bmim][PF6], under biphasic conditions: An efficiently reusable Catalyst system
  publication-title: Chem. Lett.
  doi: 10.1246/cl.2001.650
  contributor:
    fullname: Okazaki
– volume: 124
  start-page: 9164
  year: 2002
  ident: ref_73
  article-title: Rhodium-catalyzed silylcarbocyclization (SiCaC) and carbonylative silylcarbocyclization (CO−SiCaC) reactions of enynes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja0258982
  contributor:
    fullname: Ojima
– volume: 114
  start-page: 6580
  year: 1992
  ident: ref_71
  article-title: Silylcarbocyclization reactions catalyzed by rhodium and rhodium-cobalt complexes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00042a061
  contributor:
    fullname: Ojima
– ident: ref_48
  doi: 10.1039/c39760000734
– volume: 3
  start-page: 1303
  year: 2001
  ident: ref_58
  article-title: Desymmetrization of 4-dimethylsiloxy-1,6-heptadiynes through sequential double silylformylation
  publication-title: Org. Lett.
  doi: 10.1021/ol0156594
  contributor:
    fullname: Bonafoux
– volume: 118
  start-page: 1
  year: 2010
  ident: ref_95
  article-title: Beta-lactam antibiotics: From antibiosis to resistance and bacteriology
  publication-title: APMIS
  doi: 10.1111/j.1600-0463.2009.02563.x
  contributor:
    fullname: Kong
– volume: 117
  start-page: 4419
  year: 1995
  ident: ref_47
  article-title: Rhodium-catalyzed intramolecular silylformylation of acetylenes: A vehicle for complete regio-and stereoselectivity in the formylation of acetylenic bonds
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00120a033
  contributor:
    fullname: Monteil
– volume: 25
  start-page: 1971
  year: 2014
  ident: ref_117
  article-title: Formic acid derivatives as practical carbon monoxide surrogates for metal-catalyzed carbonylation reactions
  publication-title: Synlett
  doi: 10.1055/s-0033-1339136
  contributor:
    fullname: Konishi
– volume: 6
  start-page: 3589
  year: 2004
  ident: ref_86
  article-title: Novel [2 + 2 + 2 + 1] Cycloaddition of enediynes catalyzed by rhodium complexes
  publication-title: Org. Lett.
  doi: 10.1021/ol048500a
  contributor:
    fullname: Bennacer
– volume: 116
  start-page: 3643
  year: 1994
  ident: ref_37
  article-title: Extremely chemoselective silylformylation and silylcarbocyclization of alkynals
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00087a078
  contributor:
    fullname: Ojima
– volume: 42
  start-page: 1301
  year: 2001
  ident: ref_91
  article-title: Synthesis of 3-silyl-2(5H)-furanone by rhodium-catalyzed cyclocarbonylation
  publication-title: Tetrahedron Lett.
  doi: 10.1016/S0040-4039(00)02234-6
  contributor:
    fullname: Fukuta
– volume: 50
  start-page: 1209
  year: 2018
  ident: ref_111
  article-title: Cyclization reactions for the synthesis of phthalans and isoindolines
  publication-title: Synthesis
  doi: 10.1055/s-0037-1609175
  contributor:
    fullname: Albano
– volume: 121
  start-page: 3230
  year: 1999
  ident: ref_88
  article-title: Rhodium-catalyzed intramolecular silylcarbotricyclization (SiCaT) of triynes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja9815529
  contributor:
    fullname: Ojima
– volume: 18
  start-page: 5103
  year: 1999
  ident: ref_55
  article-title: Extremely regioselective intramolecular silylformylation of bis(silylamino)alkynes
  publication-title: Organometallics
  doi: 10.1021/om9904549
  contributor:
    fullname: Ojima
– volume: Volume 4
  start-page: 995
  year: 2014
  ident: ref_13
  article-title: Hydroformylation and related carbonylation reactions of alkenes, alkynes, and allenes
  publication-title: Comprehensive Organic Synthesis
  contributor:
    fullname: Knochel
– volume: 3
  start-page: 423
  year: 1992
  ident: ref_27
  article-title: Organometallic chemistry and homogeneous catalysis of Rh and Rh-Co mixed metal carbonyl clusters
  publication-title: J. Cluster Sci.
  doi: 10.1007/BF00702749
  contributor:
    fullname: Ojima
– volume: 111
  start-page: 2332
  year: 1989
  ident: ref_16
  article-title: An efficient silylformylation of alkynes catalyzed by tetrarhodium dodecacarbonyl
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00188a074
  contributor:
    fullname: Matsuda
– volume: 66
  start-page: 265
  year: 2010
  ident: ref_92
  article-title: Synthesis of functionalised β-lactones via silylcarbocyclisation/desilylation reactions of propargyl alcohols
  publication-title: Tetrahedron
  doi: 10.1016/j.tet.2009.10.112
  contributor:
    fullname: Aronica
– volume: 52
  start-page: 2852
  year: 2013
  ident: ref_12
  article-title: Alternative metals for homogeneous catalyzed hydroformylation reactions
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.201208330
  contributor:
    fullname: Pospech
– volume: 15
  start-page: 2496
  year: 1996
  ident: ref_32
  article-title: Interconversion between zwitterionic and cationic rhodium(I) complexes of demonstrated value as catalysts in hydroformylation, silylformylation, and hydrogenation reactions. dynamic 31P{1H} NMR studies of (η6-PhBPh3)-Rh+(DPPB) and [Rh(DPPB)2]+BPh4-in solution
  publication-title: Organometallics
  doi: 10.1021/om960112s
  contributor:
    fullname: Zhou
– volume: 131
  start-page: 14188
  year: 2009
  ident: ref_78
  article-title: Total syntheses of isodomoic acids G and H
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja9063475
  contributor:
    fullname: Denmark
– volume: 49
  start-page: 2804
  year: 2006
  ident: ref_98
  article-title: Design, synthesis, and biological evaluation of 4-alkyliden-beta lactams: New products with promising antibiotic activity against resistant bacteria
  publication-title: J. Med. Chem.
  doi: 10.1021/jm0580510
  contributor:
    fullname: Broccolo
– volume: 104
  start-page: 17
  year: 1995
  ident: ref_6
  article-title: Progress in hydroformylation and carbonylation
  publication-title: J. Mol. Catal. A Chem.
  doi: 10.1016/1381-1169(95)00130-1
  contributor:
    fullname: Beller
– volume: 2000
  start-page: 1131
  year: 2000
  ident: ref_41
  article-title: Tandem silylformylation/Wittig olefination of terminal alkynes: Stereoselective synthesis of 2,4-dienoic esters
  publication-title: Eur. J. Org. Chem.
  doi: 10.1002/1099-0690(200004)2000:7<1131::AID-EJOC1131>3.0.CO;2-1
  contributor:
    fullname: Eilbracht
– volume: 2017
  start-page: 7204
  year: 2017
  ident: ref_113
  article-title: Potentiality and synthesis of o-and n-heterocycles: Pd-catalyzed cyclocarbonylative sonogashira coupling as a valuable route to phthalans, isochromans, and isoindolines
  publication-title: Eur. J. Org. Chem.
  doi: 10.1002/ejoc.201701041
  contributor:
    fullname: Albano
– volume: 2017
  start-page: 955
  year: 2017
  ident: ref_114
  article-title: Synthesis of n-heteroaromatic compounds through cyclocarbonylative sonogashira reactions
  publication-title: Eur. J. Org. Chem.
  doi: 10.1002/ejoc.201601392
  contributor:
    fullname: Aronica
– volume: 59
  start-page: 8889
  year: 2003
  ident: ref_62
  article-title: Tandem silylformylation–allyl(crotyl)silylation: A new approach to polyketide synthesis
  publication-title: Tetrahedron
  doi: 10.1016/j.tet.2003.04.004
  contributor:
    fullname: Zacuto
– volume: 124
  start-page: 7890
  year: 2002
  ident: ref_61
  article-title: Tandem intramolecular silylformylation−crotylsilylation: Highly efficient synthesis of polyketide fragments
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja026511y
  contributor:
    fullname: Zacuto
– volume: 1996
  start-page: 414
  year: 1996
  ident: ref_1
  article-title: HSiR3/CO as the potent reactant combination in developing new transition-metal-catalyzed reactions
  publication-title: Synlett
  doi: 10.1055/s-1996-5441
  contributor:
    fullname: Chatani
– volume: 32
  start-page: 7431
  year: 1991
  ident: ref_90
  article-title: A novel approach to α-silylmethylene-β-lactams via Rh-catalyzed silylcarbonylation of propargylamine derivatives
  publication-title: Tetrahedron Lett.
  doi: 10.1016/0040-4039(91)80126-Q
  contributor:
    fullname: Matsuda
– volume: 9
  start-page: 3127
  year: 1990
  ident: ref_108
  article-title: Hydrosilylation of 1-hexyne catalyzed by rhodium and cobalt-rhodium mixed-metal complexes. Mechanism of apparent trans addition
  publication-title: Organometallics
  doi: 10.1021/om00162a026
  contributor:
    fullname: Ojima
– volume: 23
  start-page: 4116
  year: 2004
  ident: ref_84
  article-title: Chemo-and regioselective intramolecular hydrosilylative carbocyclization of allenynes
  publication-title: Organometallics
  doi: 10.1021/om049677b
  contributor:
    fullname: Shibata
– volume: 47
  start-page: 1396
  year: 2014
  ident: ref_110
  article-title: The [3 + 3]-cycloaddition alternative for heterocycle syntheses: Catalytically generated metalloenolcarbenes as dipolar adducts
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar5000055
  contributor:
    fullname: Xu
– ident: ref_115
  doi: 10.3390/catal10010025
– volume: 2001
  start-page: 4321
  year: 2001
  ident: ref_35
  article-title: Silylformylation of chiral 1-alkynes, catalysed by solvated rhodium atoms
  publication-title: Eur. J. Org. Chem.
  doi: 10.1002/1099-0690(200111)2001:22<4321::AID-EJOC4321>3.0.CO;2-T
  contributor:
    fullname: Aronica
– volume: 66
  start-page: 2377
  year: 1983
  ident: ref_44
  article-title: Silicon-directed nazarov reactions II. Preparation and cyclization of β-silyl-substituted divinyl ketones
  publication-title: Helv. Chim. Acta
  doi: 10.1002/hlca.19830660802
  contributor:
    fullname: Jones
– ident: ref_8
– volume: 2006
  start-page: 1845
  year: 2006
  ident: ref_17
  article-title: Silylformylation—Fluoride-assisted aryl migration of acetylenic derivatives in a versatile approach to the synthesis of polyfunctionalised compounds
  publication-title: Eur. J. Org. Chem.
  doi: 10.1002/ejoc.200500883
  contributor:
    fullname: Aronica
– volume: 2
  start-page: 384
  year: 2017
  ident: ref_52
  article-title: Hydrogenolysis of benzyl protected phenols and aniline promoted by supported palladium nanoparticles
  publication-title: ChemistrySelect
  doi: 10.1002/slct.201601736
  contributor:
    fullname: Albano
– volume: 42
  start-page: 5697
  year: 2001
  ident: ref_21
  article-title: Efficient silylformylation of alkynes catalyzed by rhodium complexes with P,N donor ligands
  publication-title: Tetrahedron Lett.
  doi: 10.1016/S0040-4039(01)01086-3
  contributor:
    fullname: Alonso
– volume: 37
  start-page: 4027
  year: 1981
  ident: ref_39
  article-title: The synthesis of αβ-unsaturated ketones from β-silylenones and β-silylynones
  publication-title: Tetrahedron
  doi: 10.1016/S0040-4020(01)93277-6
  contributor:
    fullname: Fleming
– volume: 10
  start-page: 1341
  year: 2006
  ident: ref_70
  article-title: Synthesis of heterocycles through hydrosilylation, silylformylation, silylcarbocyclization and cyclohydrocarbonylation reactions
  publication-title: Curr. Org. Chem.
  doi: 10.2174/138527206778018230
  contributor:
    fullname: Varchi
– volume: 127
  start-page: 17756
  year: 2005
  ident: ref_87
  article-title: Silicon-initiated carbonylative carbotricyclization and [2+2+2+1] cycloaddition of enediynes catalyzed by rhodium complexes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja054221m
  contributor:
    fullname: Bennacer
– volume: 55
  start-page: 14934
  year: 2019
  ident: ref_100
  article-title: Methylations in complex carbapenem biosynthesis are catalyzed by a single cobalamin-dependent radical S-adenosylmethionine enzyme
  publication-title: Chem. Commun.
  doi: 10.1039/C9CC07197K
  contributor:
    fullname: Sinner
– volume: 43
  start-page: 5813
  year: 2002
  ident: ref_46
  article-title: New synthesis of α-benzylaldehydes from 2-(dimethylphenylsilylmethylene)alkanals by fluoride promoted phenyl migration
  publication-title: Tetrahedron Lett.
  doi: 10.1016/S0040-4039(02)01178-4
  contributor:
    fullname: Aronica
– volume: 13
  start-page: 1586
  year: 1994
  ident: ref_33
  article-title: Zwitterionic rhodium(I) complex catalyzed net silylhydroformylation of terminal alkynes
  publication-title: Organometallics
  doi: 10.1021/om00017a015
  contributor:
    fullname: Zhou
– volume: 18
  start-page: 1
  year: 2006
  ident: ref_10
  article-title: Hydroformylation
  publication-title: Top. Organomet. Chem.
  contributor:
    fullname: Wiese
– volume: 50
  start-page: 1020
  year: 2009
  ident: ref_103
  article-title: Cross-metathesis of α-methylene-β-lactams: The first tetrasubstituted alkenes by CM
  publication-title: Tetrahedron Lett.
  doi: 10.1016/j.tetlet.2008.12.060
  contributor:
    fullname: Liang
– volume: 251
  start-page: 299
  year: 1996
  ident: ref_107
  article-title: Silylcyclocarbonylation (SiCCa) of alkynylamines catalyzed by rhodium complexes
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(97)82717-X
  contributor:
    fullname: Ojima
– volume: 16
  start-page: 1180
  year: 2014
  ident: ref_66
  article-title: Beyond the roche ester: A new approach to polypropionate stereotriad synthesis
  publication-title: Org. Lett.
  doi: 10.1021/ol500051e
  contributor:
    fullname: Foley
– volume: 23
  start-page: 1947
  year: 2004
  ident: ref_22
  article-title: Cationic carboxylato complexes of dirhodium(II) with oxo thioethers: Promising catalysts with unusual coordination modes
  publication-title: Organometallics
  doi: 10.1021/om0342560
  contributor:
    fullname: Basato
– volume: 68
  start-page: 9292
  year: 2003
  ident: ref_18
  article-title: Fluoride-promoted rearrangement of organo silicon compounds: A new synthesis of 2-(arylmethyl)aldehydes from 1-alkynes
  publication-title: J. Org. Chem.
  doi: 10.1021/jo0351062
  contributor:
    fullname: Aronica
– volume: 700
  start-page: 20
  year: 2012
  ident: ref_93
  article-title: Metal vapour derived supported rhodium nanoparticles in the synthesis of β-lactams and β-lactones derivatives
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2011.11.008
  contributor:
    fullname: Aronica
– volume: 120
  start-page: 6690
  year: 1998
  ident: ref_82
  article-title: Silylcarbocyclizations of 1,6-diynes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja980907l
  contributor:
    fullname: Ojima
– ident: ref_15
  doi: 10.3390/catal10050510
– ident: ref_112
  doi: 10.3390/catal10040434
– volume: 74
  start-page: 159
  year: 2002
  ident: ref_68
  article-title: New cyclization reactions in organic syntheses
  publication-title: Pure Appl. Chem.
  doi: 10.1351/pac200274010159
  contributor:
    fullname: Ojima
– volume: 59
  start-page: 7594
  year: 1994
  ident: ref_80
  article-title: Silylcarbobicyclization of 1,6-diynes: A novel Catalytic route to bicyclo[3.3.0]octenones
  publication-title: J. Org. Chem.
  doi: 10.1021/jo00104a012
  contributor:
    fullname: Ojima
– volume: 47
  start-page: 527
  year: 2006
  ident: ref_19
  article-title: Silylformylation–desilylation of propargyl amides: Synthesis of α,β-unsaturated aldehydes
  publication-title: Tetrahedron Lett.
  doi: 10.1016/j.tetlet.2005.11.054
  contributor:
    fullname: Aronica
– volume: 64
  start-page: 9711
  year: 1999
  ident: ref_50
  article-title: Diastereoselective intramolecular silylformylation of ω-silylacetylenes
  publication-title: J. Org. Chem.
  doi: 10.1021/jo991129y
  contributor:
    fullname: Aronica
– volume: 49
  start-page: 5431
  year: 1993
  ident: ref_26
  article-title: Silylformylation catalyzed by Rh and Rh-Co mixed metal complexes and its application to the synthesis of pyrrolizidine alkaloids
  publication-title: Tetrahedron
  doi: 10.1016/S0040-4020(01)87260-4
  contributor:
    fullname: Ojima
– volume: 150
  start-page: 652
  year: 2020
  ident: ref_53
  article-title: Polyvinylpyridine-supported palladium nanoparticles: A valuable catalyst for the synthesis of alkynyl ketones via acyl sonogashira reactions
  publication-title: Catal. Lett.
  doi: 10.1007/s10562-019-02959-5
  contributor:
    fullname: Albano
– volume: 270
  start-page: 279
  year: 1998
  ident: ref_28
  article-title: On the mechanism of silylformylation catalyzed by Rh-Co mixed metal complexes
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(97)05855-6
  contributor:
    fullname: Ojima
– volume: 47
  start-page: 1041
  year: 2014
  ident: ref_14
  article-title: Transition-metal-catalyzed carbonylation reactions of olefins and alkynes: A personal account
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar400222k
  contributor:
    fullname: Wu
– volume: 12
  start-page: 11
  year: 1993
  ident: ref_31
  article-title: Highly efficient regioselective silylcarbonylation of alkynes catalyzed by dirhodium(II) perfluorobutyrate
  publication-title: Organometallics
  doi: 10.1021/om00025a005
  contributor:
    fullname: Doyle
– volume: 129
  start-page: 3737
  year: 2007
  ident: ref_77
  article-title: Sequential silylcarbocyclization/silicon-based cross-coupling reactions
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja067854p
  contributor:
    fullname: Denmark
– volume: Volume 99
  start-page: 107
  year: 2010
  ident: ref_54
  article-title: Biologically active silacyclanes
  publication-title: Advances in Heterocyclic Chemistry
  doi: 10.1016/S0065-2725(10)09904-6
  contributor:
    fullname: Katritzky
– volume: 10
  start-page: 5593
  year: 2008
  ident: ref_63
  article-title: Tandem silylformylation−crotylsilylation/tamao oxidation of internal alkynes: A remarkable example of generating complexity from simplicity
  publication-title: Org. Lett.
  doi: 10.1021/ol802489w
  contributor:
    fullname: Spletstoser
– volume: 17
  start-page: 5858
  year: 2015
  ident: ref_67
  article-title: A Highly stereoselective, efficient, and scalable synthesis of the C(1)–C(9) Fragment of the epothilones
  publication-title: Org. Lett.
  doi: 10.1021/acs.orglett.5b03034
  contributor:
    fullname: Foley
– volume: 117
  start-page: 6797
  year: 1995
  ident: ref_56
  article-title: Extremely regioselective intramolecular silylformylation of alkynes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00130a027
  contributor:
    fullname: Ojima
– volume: 15
  start-page: 5191
  year: 1996
  ident: ref_81
  article-title: New and efficient catalytic route to bicyclo[3.3.0]octa-1,5-dien-3-ones
  publication-title: Organometallics
  doi: 10.1021/om960471n
  contributor:
    fullname: Ojima
– volume: 35
  start-page: 621
  year: 1979
  ident: ref_43
  article-title: Synthesis and diels-alder reactions of e-1-trimethylsilylbuta-1,3-diene
  publication-title: Tetrahedron
  doi: 10.1016/0040-4020(79)87006-4
  contributor:
    fullname: Jung
– volume: 62
  start-page: 6312
  year: 2006
  ident: ref_76
  article-title: Sequential addition reaction of lithium acetylides and Grignard reagents to thioiminium salts from thiolactams leading to 2,2-disubstituted cyclic amines
  publication-title: Tetrahedron
  doi: 10.1016/j.tet.2006.04.065
  contributor:
    fullname: Murai
– volume: 85
  start-page: 10022
  year: 2020
  ident: ref_116
  article-title: Synthesis of 3-Alkylideneisoindolin-1-ones via sonogashira cyclocarbonylative reactions of 2-ethynylbenzamides
  publication-title: J. Org. Chem.
  doi: 10.1021/acs.joc.0c01282
  contributor:
    fullname: Albano
– volume: 53
  start-page: 6310
  year: 2014
  ident: ref_118
  article-title: Carbonylations of alkenes with CO surrogates
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.201400793
  contributor:
    fullname: Wu
– ident: ref_57
– volume: 40
  start-page: 4703
  year: 1999
  ident: ref_74
  article-title: Rhodium-catalyzed domino silylformylation of enynes involving carbocyclization
  publication-title: Tetrahedron Lett.
  doi: 10.1016/S0040-4039(99)00849-7
  contributor:
    fullname: Fukuta
– volume: 480
  start-page: 1
  year: 2014
  ident: ref_51
  article-title: Palladium nanoparticles supported on Smopex® metal scavengers as catalyst for carbonylative Sonogashira reactions: Synthesis of α,β-alkynyl ketones
  publication-title: Appl. Catal. A Gen.
  doi: 10.1016/j.apcata.2014.04.029
  contributor:
    fullname: Aronica
SSID ssj0000913815
Score 2.3142889
Snippet Oxygen and nitrogen heterocyclic systems are present in a large number of natural and synthetic compounds. In particular, oxa- and aza-silacyclane,...
SourceID doaj
proquest
crossref
SourceType Open Website
Aggregation Database
StartPage 1012
SubjectTerms Alkynes
Amides
Carbon
Carbonyls
Catalysts
Chemical bonds
Chemical reactions
Chemical synthesis
Functional groups
Heterocyclic compounds
N-heterocycles
O-heterocycles
silylcarbocyclization
silylformylation
Tetrahydrofuran
SummonAdditionalLinks – databaseName: ProQuest Technology Collection
  dbid: 8FG
  link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1LSwMxEA5aD3oRn1itkoN4W9xskk32JLVYi6CIWuhtyWtVrN3a1kP_vZndtFIEr3nAMpN57jczCJ0rYrxboIoo8c5qxLIii6SCNFysYmG5TXSNtnhIe312N-CDkHCbBljlQidWitqWBnLkl94MQejhrd3V-CuCqVHwdzWM0FhHGyQRAoIv2b1d5lig56UkvG6tSX10X9eDE9iISbJiiqqO_X8UcmVlujtoO7iHuF3zcxetudEe2uwsprLto7fupPzE7eHH3OsoPCtxD_AspZkDug2HqTv43vkPiB4rqJ2z-Pl9OB-CdzqvkW9YjcKiURNdXQ7lmPjJ1ZUO0wPU7968dHpRmJYQGSriWZQQw3VSpLGzWZK6NCPQvD1TTDMuXMF1YbjxB4TQSqjUci0BARpb5wrmjTY9RI1ROXJHCFPGCxMb4pSWXsCFZC6jKSPGc1BazproYkG4fFw3xch9MAEUzlco3ETXQNblIehlXS2Uk9c8iEbuPQ5JKdWEcctsRqTWTkhHLdWF5so0UWvBlDwI2DT_fQ7H_2-foK0EQuQKFtZCjdnk2516P2Kmz6rH8gNei8rH
  priority: 102
  providerName: ProQuest
Title From Alkynes to Heterocycles through Metal-Promoted Silylformylation and Silylcarbocyclization Reactions
URI https://www.proquest.com/docview/2440717175
https://doaj.org/article/1298333b145d4d918bbe78e3d3bfb5ac
Volume 10
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV07T8MwELagDLAgnqJQKg-ILSKO7cQe26qlQqKqCpW6RX5FIEqC2jL03-NHiooYWFgdR7Hu7Lvvos_fAXAjkLKwQBRRYsFqRHjBIybcb7hYxJmmOpGBbTFKh1PyMKOzrVZfjhMW5IGD4e5sPmIYY4kI1URzxKQ0GTNYY1lIKpSPvjHfKqZ8DObIpiIaRDWxrevDTXDkHsQo-ZGEvFb_r1Ds88vgCBzWwBB2woKOwY4pT8B-b9OP7RS8DBbVO-zM39Y2OsFVBYeOyVKpteO1wbrfDnw0dgHR2JPsjIZPr_P13OHSdeC8QVHWg0ospH-5vogJJybccViegemg_9wbRnWfhEjhLF5FCVJUJkUaG82T1KQcOdl2LogkNDMFlYWiyk7IMikykWoqmeN-xtqYgth0jc9Bo6xKcwEgJrRQsUJGSGaPdsaI4TglSFnfMU1JE9xuDJd_BDmM3JYRzsL5Dws3QdeZ9XuSU7H2A9a3ee3b_C_fNkFr45S8PlrL3OIRV4Na2HP5H9-4AgeJK6E9bawFGqvFp7m2OGMl22CXDe7bYK_bH40nbb_BvgDDENZE
link.rule.ids 315,783,787,867,2109,12777,21400,27936,27937,33385,33756,43612,43817,74363,74630
linkProvider Directory of Open Access Journals
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3JTsMwELVYDuWCWEVZfUDcIuLYTpwTAkQpSyvEInGLvAUQpSlpOfTv8SQOqELi6kWKZjxr3swgdCiJdm6BzIPIOasBS_M0EBLScKEME8NNpGq0RT_uPrHrZ_7sE25jD6tsdGKlqE2hIUd-7MwQhB7O2p2MPgOYGgV_V_0IjXm0yKiz1VAp3rn8ybFAz0tBeN1ak7rovq4HJ7ARkmjGFFUd-_8o5MrKdFbQsncP8WnNz1U0Z4drqHXeTGVbR6-dsvjAp4P3qdNReFLgLuBZCj0FdBv2U3dwz7oPCO4qqJ01-OFtMB2AdzqtkW9YDv2ilqWqLvtyTHxv60qH8QZ66lw8nncDPy0h0DQJJ0FENFdRHofWpFFs45RA8_ZUMsV4YnOucs21O5AkSiYyNlwJQICGxtqcOaNNN9HCsBjaLYQp47kONbFSCSfgiWA2pTEj2nFQGM7a6KghXDaqm2JkLpgACmczFG6jMyDrzyHoZV0tFOVL5kUjcx6HoJQqwrhhJiVCKZsISw1VueJSt9Fuw5TMC9g4-30O2_9vH6BW97F3m91e9W920FIE4XIFEdtFC5Pyy-45n2Ki9quH8w3wa82p
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1JS8QwFA4uoF7EFcc1B_FWbJqkTU_iVscVcQFvJauK43ScGQ_z781rM4oIXrNAeXl7v_ceQruSaO8WSBcl3lmNWO7ySEhIw8Uyzgw3iWrQFjdp-5FdPPGngH8aBFjlWCfWitpUGnLk-94MQejhrd2-C7CI25PioPcRwQQp-NMaxmlMomlvFVPgeVGcfedboP-lILxps0l9pN_UhhPYiEnyyyzV3fv_KOfa4hQLaD64iviwedtFNGG7S2j2eDyhbRm9FP3qHR923kZeX-FhhduAban0CJBuOEzgwdfWf0B0W8PurMH3r51RBzzVUYOCw7IbFrXsq_pyKM3Ed7apehisoMfi9OG4HYXJCZGmWTyMEqK5SlwaW5MnqU1zAo3cc8kU45l1XDnNtT-QZUpmMjVcCUCDxsZax7wBp6toqlt17RrClHGnY02sVMILeyaYzWnKiPavKQxnLbQ3JlzZaxpklD6wAAqXvyjcQkdA1u9D0Ne6Xqj6z2UQk9J7H4JSqgjjhpmcCKVsJiw1VDnFpW6hzfGjlEHYBuUPa6z_v72DZjzPlFfnN5cbaC6ByLlGi22iqWH_025592Kotmu--QJAptHh
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=From+Alkynes+to+Heterocycles+through+Metal-Promoted+Silylformylation+and+Silylcarbocyclization+Reactions&rft.jtitle=Catalysts&rft.au=Gianluigi+Albano&rft.au=Laura+Antonella+Aronica&rft.date=2020-09-01&rft.pub=MDPI+AG&rft.eissn=2073-4344&rft.volume=10&rft.issue=9&rft.spage=1012&rft_id=info:doi/10.3390%2Fcatal10091012&rft.externalDBID=DOA&rft.externalDocID=oai_doaj_org_article_1298333b145d4d918bbe78e3d3bfb5ac
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2073-4344&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2073-4344&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2073-4344&client=summon