Facile Fabrication of Rhodium/Nanodiamond Hybrid as Advanced Catalyst toward Hydrogen Production from Ammonia–Borane
Hydrogen generation through ammonia–borane (AB) hydrolysis has been regarded as one of the most promising pathways to tap renewable green energy. The design and synthesis of highly effective catalysts toward hydrogen production from aqueous AB is of paramount significance. Here, the facile synthesis...
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| Published in | Catalysts Vol. 10; no. 9; p. 1037 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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01.09.2020
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| Abstract | Hydrogen generation through ammonia–borane (AB) hydrolysis has been regarded as one of the most promising pathways to tap renewable green energy. The design and synthesis of highly effective catalysts toward hydrogen production from aqueous AB is of paramount significance. Here, the facile synthesis of Rh nanoparticles (NPs) immobilized on nanodiamond (nano-DA) and concomitant AB hydrolysis to produce hydrogen was successfully achieved. The in situ generated Rh/nano-DA exhibited excellent catalytic activity toward AB hydrolysis, with a high turnover frequency (TOF) value of 729.4 min−1 at 25 °C and a low activation energy of 25.6 kJ mol−1. Moreover, the catalyst could be reused four times. The unique properties of DA with abundant oxygen-containing groups enable the homogeneous distribution of small and surface-clean Rh NPs on the nano-DA surface, which can supply abundant accessible active sites for hydrogen evolution from AB hydrolysis. This study demonstrated that nano-DA can be applied as an ideal matrix to deposit efficient Rh nanocatalyst toward hydrogen evolution reaction. |
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| AbstractList | Hydrogen generation through ammonia–borane (AB) hydrolysis has been regarded as one of the most promising pathways to tap renewable green energy. The design and synthesis of highly effective catalysts toward hydrogen production from aqueous AB is of paramount significance. Here, the facile synthesis of Rh nanoparticles (NPs) immobilized on nanodiamond (nano-DA) and concomitant AB hydrolysis to produce hydrogen was successfully achieved. The in situ generated Rh/nano-DA exhibited excellent catalytic activity toward AB hydrolysis, with a high turnover frequency (TOF) value of 729.4 min−1 at 25 °C and a low activation energy of 25.6 kJ mol−1. Moreover, the catalyst could be reused four times. The unique properties of DA with abundant oxygen-containing groups enable the homogeneous distribution of small and surface-clean Rh NPs on the nano-DA surface, which can supply abundant accessible active sites for hydrogen evolution from AB hydrolysis. This study demonstrated that nano-DA can be applied as an ideal matrix to deposit efficient Rh nanocatalyst toward hydrogen evolution reaction. |
| Author | Wu, Jie Wen, Zhaoyu Fan, Guangyin |
| Author_xml | – sequence: 1 givenname: Zhaoyu surname: Wen fullname: Wen, Zhaoyu – sequence: 2 givenname: Jie surname: Wu fullname: Wu, Jie – sequence: 3 givenname: Guangyin orcidid: 0000-0001-9334-0810 surname: Fan fullname: Fan, Guangyin |
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| CitedBy_id | crossref_primary_10_1002_smll_202102759 crossref_primary_10_1016_j_ijhydene_2022_03_127 crossref_primary_10_1016_j_ijhydene_2023_03_322 crossref_primary_10_1039_D1RA07470A crossref_primary_10_1016_j_apsusc_2022_154795 crossref_primary_10_1016_j_fuel_2021_121722 crossref_primary_10_1016_j_cherd_2022_09_028 crossref_primary_10_1016_j_cplett_2021_138365 crossref_primary_10_1021_acs_energyfuels_0c03215 |
| Cites_doi | 10.1039/C8TA03572E 10.1016/j.apcatb.2017.11.067 10.1016/j.apsusc.2018.10.051 10.1039/C6NJ02695H 10.1021/ma200176r 10.1016/j.carbon.2016.03.034 10.1016/j.apcatb.2008.12.004 10.1016/j.ijhydene.2018.02.148 10.1016/j.jpowsour.2007.03.015 10.1016/j.ijhydene.2020.03.016 10.1063/1.4922315 10.1016/j.ijhydene.2018.11.162 10.1039/C9GC03986D 10.1039/c3cc48027e 10.1016/j.ijhydene.2015.01.122 10.1039/C4RA00469H 10.1016/j.ijhydene.2020.07.255 10.1021/ic700806b 10.1021/acscatal.6b02209 10.1016/j.jallcom.2015.07.249 10.1039/C7EE01553D 10.1016/j.jallcom.2017.02.239 10.1016/j.jcis.2019.06.038 10.1016/j.ijhydene.2014.12.047 10.1021/acs.inorgchem.7b02466 10.1021/acssuschemeng.8b01581 10.1002/cssc.201801204 10.1016/j.apcatb.2016.06.057 10.1016/j.jcis.2017.08.086 10.1021/ja208834v 10.1016/j.ijhydene.2015.10.083 10.1016/j.ijhydene.2014.07.179 10.1016/j.ijhydene.2017.12.079 10.1016/j.jpowsour.2014.01.122 10.1016/j.apcata.2009.08.031 10.1002/aenm.201801698 10.1016/j.ijhydene.2019.04.200 10.1016/j.ijhydene.2019.06.072 10.1002/smll.201903057 10.1002/anie.201701089 10.1021/jp4044094 10.1039/C4TA02486A 10.1016/j.ijhydene.2020.01.121 10.1039/C7DT04549B 10.1016/j.apsusc.2018.05.192 10.1016/j.ijhydene.2014.11.031 10.1016/j.carbon.2013.08.052 10.1016/j.ijhydene.2013.01.150 10.1016/j.cclet.2010.10.047 10.1016/j.ijhydene.2010.10.066 10.1039/c3ee40507a 10.1016/j.apcatb.2016.05.061 10.1016/j.jallcom.2018.11.189 10.1016/j.jcis.2019.03.070 10.1016/j.apcatb.2017.04.017 10.1016/j.ijhydene.2018.05.102 10.1016/j.ijhydene.2020.07.097 10.1021/acs.analchem.9b01715 |
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| References | Zhan (ref_12) 2016; 6 Clark (ref_22) 2007; 46 Varga (ref_39) 2016; 199 Ding (ref_47) 2020; 22 Wen (ref_13) 2014; 39 Yao (ref_58) 2015; 40 Akdere (ref_38) 2018; 225 Zhang (ref_37) 2019; 91 Li (ref_45) 2015; 40 Cheng (ref_1) 2018; 6 Hou (ref_10) 2017; 10 Morimune (ref_28) 2011; 44 Chang (ref_42) 2014; 66 Zhang (ref_43) 2017; 56 Hu (ref_57) 2018; 43 Li (ref_4) 2013; 6 Ma (ref_25) 2017; 708 Chandra (ref_52) 2007; 168 Yao (ref_23) 2014; 257 Zhang (ref_35) 2011; 22 Ming (ref_40) 2017; 210 Fan (ref_11) 2017; 41 Dong (ref_48) 2020; 45 Hu (ref_15) 2018; 11 Chen (ref_32) 2015; 106 Durap (ref_21) 2009; 369 Xu (ref_14) 2018; 6 (ref_20) 2009; 89 Fan (ref_31) 2016; 41 Ma (ref_34) 2019; 778 Yang (ref_46) 2011; 36 Duan (ref_29) 2016; 103 Teimouri (ref_36) 2018; 43 Zhu (ref_50) 2013; 38 Hu (ref_3) 2020; 45 ref_33 Xu (ref_2) 2019; 466 Chen (ref_16) 2014; 50 Shen (ref_27) 2015; 40 Rakap (ref_54) 2015; 649 Akbayrak (ref_55) 2019; 546 Akbayrak (ref_18) 2016; 198 Tonbul (ref_26) 2019; 553 Liu (ref_19) 2019; 44 Akbayrak (ref_24) 2014; 4 Luo (ref_5) 2011; 133 Lin (ref_56) 2019; 44 Xu (ref_8) 2018; 47 Liu (ref_30) 2013; 117 Tonbul (ref_53) 2019; 44 Chen (ref_51) 2018; 43 Zhong (ref_9) 2018; 455 Su (ref_44) 2014; 2 Yola (ref_41) 2017; 508 Wang (ref_17) 2017; 56 ref_7 ref_6 Ming (ref_49) 2019; 15 |
| References_xml | – volume: 6 start-page: 14380 year: 2018 ident: ref_14 article-title: Facile synthesis of effective Ru nanoparticles on carbon by adsorption-low temperature pyrolysis strategy for hydrogen evolution publication-title: J. Mater. Chem. A doi: 10.1039/C8TA03572E contributor: fullname: Xu – volume: 225 start-page: 148 year: 2018 ident: ref_38 article-title: A novel thiocarbamide functionalized graphene oxide supported bimetallic monodisperse Rh-Pt nanoparticles (RhPt/TC@GO NPs) for Knoevenagel condensation of aryl aldehydes together with malononitrile publication-title: Appl. Catal. Environ. doi: 10.1016/j.apcatb.2017.11.067 contributor: fullname: Akdere – volume: 466 start-page: 193 year: 2019 ident: ref_2 article-title: Ruthenium coordinated with triphenylphosphine-hyper-crosslinked polymer: An efficient catalyst for hydrogen evolution reaction and hydrolysis of ammonia borane publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2018.10.051 contributor: fullname: Xu – volume: 41 start-page: 2793 year: 2017 ident: ref_11 article-title: Magnetic, recyclable PtyCo1−y/Ti3C2X2 (X = O, F) catalyst: A facile synthesis and enhanced catalytic activity for hydrogen generation from the hydrolysis of ammonia borane publication-title: New J. Chem. doi: 10.1039/C6NJ02695H contributor: fullname: Fan – volume: 44 start-page: 4415 year: 2011 ident: ref_28 article-title: Poly(vinyl alcohol) Nanocomposites with Nanodiamond publication-title: Macromolecules doi: 10.1021/ma200176r contributor: fullname: Morimune – volume: 103 start-page: 404 year: 2016 ident: ref_29 article-title: Surface-tailored nanodiamonds as excellent metal-free catalysts for organic oxidation publication-title: Carbon doi: 10.1016/j.carbon.2016.03.034 contributor: fullname: Duan – volume: 89 start-page: 104 year: 2009 ident: ref_20 article-title: Zeolite framework stabilized rhodium(0) nanoclusters catalyst for the hydrolysis of ammonia-borane in air: Outstanding catalytic activity, reusability and lifetime publication-title: Appl. Catal. Environ. doi: 10.1016/j.apcatb.2008.12.004 – volume: 43 start-page: 7038 year: 2018 ident: ref_57 article-title: Hydrogen evolution from hydrolysis of ammonia borane catalyzed by Rh/g-C3N4 under mild conditions publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2018.02.148 contributor: fullname: Hu – volume: 168 start-page: 135 year: 2007 ident: ref_52 article-title: Room temperature hydrogen generation from aqueous ammonia-borane using noble metal nano-clusters as highly active catalysts publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2007.03.015 contributor: fullname: Chandra – volume: 45 start-page: 12849 year: 2020 ident: ref_48 article-title: Synergistic catalysis of Pd–Ni(OH)2 hybrid anchored on porous carbon for hydrogen evolution from the dehydrogenation of formic acid publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2020.03.016 contributor: fullname: Dong – volume: 106 start-page: 233103 year: 2015 ident: ref_32 article-title: Effective improvement in microwave absorption by uniform dispersion of nanodiamond in polyaniline through in-situ polymerization publication-title: Appl. Phys. Lett. doi: 10.1063/1.4922315 contributor: fullname: Chen – volume: 44 start-page: 14164 year: 2019 ident: ref_53 article-title: Group 4 oxides supported Rhodium(0) catalysts in hydrolytic dehydrogenation of ammonia borane publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2018.11.162 contributor: fullname: Tonbul – volume: 22 start-page: 835 year: 2020 ident: ref_47 article-title: Salt template-assisted in situ construction of Ru nanoclusters and porous carbon: Excellent catalysts toward hydrogen evolution, ammonia-borane hydrolysis, and 4-nitrophenol reduction publication-title: Green Chem. doi: 10.1039/C9GC03986D contributor: fullname: Ding – volume: 50 start-page: 2142 year: 2014 ident: ref_16 article-title: Unique reactivity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane publication-title: Chem. Commun. doi: 10.1039/c3cc48027e contributor: fullname: Chen – volume: 40 start-page: 3883 year: 2015 ident: ref_45 article-title: Ultrafast hydrogen generation from the hydrolysis of ammonia borane catalyzed by highly efficient bimetallic RuNi nanoparticles stabilized on Ti3C2X2 (X = OH and/or F) publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2015.01.122 contributor: fullname: Li – volume: 4 start-page: 13742 year: 2014 ident: ref_24 article-title: Rhodium(0) nanoparticles supported on nanotitania as highly active catalyst in hydrogen generation from the hydrolysis of ammonia borane publication-title: RSC Adv. doi: 10.1039/C4RA00469H contributor: fullname: Akbayrak – ident: ref_7 doi: 10.1016/j.ijhydene.2020.07.255 – volume: 46 start-page: 7522 year: 2007 ident: ref_22 article-title: Highly efficient colloidal cobalt- and rhodium-catalyzed hydrolysis of H3N·BH3 in air publication-title: Inorg. Chem. doi: 10.1021/ic700806b contributor: fullname: Clark – volume: 6 start-page: 6892 year: 2016 ident: ref_12 article-title: Dehydrogenation of Ammonia Borane by Metal Nanoparticle Catalysts publication-title: ACS Catal. doi: 10.1021/acscatal.6b02209 contributor: fullname: Zhan – volume: 649 start-page: 1025 year: 2015 ident: ref_54 article-title: PVP-stabilized Ru–Rh nanoparticles as highly efficient catalysts for hydrogen generation from hydrolysis of ammonia borane publication-title: J. Alloy. Compd. doi: 10.1016/j.jallcom.2015.07.249 contributor: fullname: Rakap – volume: 10 start-page: 1770 year: 2017 ident: ref_10 article-title: Ternary Ni–Co–P nanoparticles as noble-metal-free catalysts to boost the hydrolytic dehydrogenation of ammonia-borane publication-title: Energy Environ. Sci. doi: 10.1039/C7EE01553D contributor: fullname: Hou – volume: 708 start-page: 270 year: 2017 ident: ref_25 article-title: Ruthenium nanoparticles supported on TiO2 (B) nanotubes: Effective catalysts in hydrogen evolution from the hydrolysis of ammonia borane publication-title: J. Alloy. Compd. doi: 10.1016/j.jallcom.2017.02.239 contributor: fullname: Ma – volume: 553 start-page: 581 year: 2019 ident: ref_26 article-title: Magnetically separable rhodium nanoparticles as catalysts for releasing hydrogen from the hydrolysis of ammonia borane publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2019.06.038 contributor: fullname: Tonbul – volume: 40 start-page: 2207 year: 2015 ident: ref_58 article-title: In situ facile synthesis of Rh nanoparticles supported on carbon nanotubes as highly active catalysts for H2 generation from NH3BH3 hydrolysis publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2014.12.047 contributor: fullname: Yao – volume: 56 start-page: 13651 year: 2017 ident: ref_43 article-title: Surface Modification of a NiS2 Nanoarray with Ni(OH)2 toward Superior Water Reduction Electrocatalysis in Alkaline Media publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.7b02466 contributor: fullname: Zhang – volume: 6 start-page: 11487 year: 2018 ident: ref_1 article-title: Well-Defined Ru Nanoclusters Anchored on Carbon: Facile Synthesis and High Electrochemical Activity toward Alkaline Water Splitting publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.8b01581 contributor: fullname: Cheng – volume: 11 start-page: 3253 year: 2018 ident: ref_15 article-title: Towards High-Efficiency Hydrogen Production through in situ Formation of Well-Dispersed Rhodium Nanoclusters publication-title: ChemSusChem doi: 10.1002/cssc.201801204 contributor: fullname: Hu – volume: 199 start-page: 473 year: 2016 ident: ref_39 article-title: Photo-induced reactions in the CO 2 -methane system on titanate nanotubes modified with Au and Rh nanoparticles publication-title: Appl. Catal. Environ. doi: 10.1016/j.apcatb.2016.06.057 contributor: fullname: Varga – volume: 508 start-page: 525 year: 2017 ident: ref_41 article-title: A novel electrochemical sensor based on calixarene functionalized reduced graphene oxide: Application to simultaneous determination of Fe(III), Cd(II) and Pb(II) ions publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2017.08.086 contributor: fullname: Yola – volume: 133 start-page: 19326 year: 2011 ident: ref_5 article-title: A Single-Component Liquid-Phase Hydrogen Storage Material publication-title: J. Am. Chem. Soc. doi: 10.1021/ja208834v contributor: fullname: Luo – volume: 41 start-page: 1542 year: 2016 ident: ref_31 article-title: Nanodiamond supported Ru nanoparticles as an effective catalyst for hydrogen evolution from hydrolysis of ammonia borane publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2015.10.083 contributor: fullname: Fan – volume: 39 start-page: 17129 year: 2014 ident: ref_13 article-title: Ruthenium supported on MIL-96: An efficient catalyst for hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2014.07.179 contributor: fullname: Wen – volume: 43 start-page: 2718 year: 2018 ident: ref_51 article-title: Carbon-supported small Rh nanoparticles prepared with sodium citrate: Toward high catalytic activity for hydrogen evolution from ammonia borane hydrolysis publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2017.12.079 contributor: fullname: Chen – volume: 257 start-page: 293 year: 2014 ident: ref_23 article-title: Ultrafine Ru nanoparticles embedded in SiO2 nanospheres: Highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2014.01.122 contributor: fullname: Yao – volume: 369 start-page: 53 year: 2009 ident: ref_21 article-title: Water soluble laurate-stabilized rhodium(0) nanoclusters catalyst with unprecedented catalytic lifetime in the hydrolytic dehydrogenation of ammonia-borane publication-title: Appl. Catal. Gen. doi: 10.1016/j.apcata.2009.08.031 contributor: fullname: Durap – ident: ref_33 doi: 10.1002/aenm.201801698 – volume: 44 start-page: 16548 year: 2019 ident: ref_19 article-title: Efficient hydrogen evolution from ammonia borane hydrolysis with Rh decorated on phosphorus-doped carbon publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2019.04.200 contributor: fullname: Liu – volume: 44 start-page: 21527 year: 2019 ident: ref_56 article-title: Facile and eco-friendly synthesis of porous carbon nanosheets as ideal platform for stabilizing rhodium nanoparticles in efficient hydrolysis of ammonia borane publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2019.06.072 contributor: fullname: Lin – volume: 15 start-page: e1903057 year: 2019 ident: ref_49 article-title: Room-Temperature Sustainable Synthesis of Selected Platinum Group Metal (PGM = Ir, Rh, and Ru) Nanocatalysts Well-Dispersed on Porous Carbon for Efficient Hydrogen Evolution and Oxidation publication-title: Small doi: 10.1002/smll.201903057 contributor: fullname: Ming – volume: 56 start-page: 4712 year: 2017 ident: ref_17 article-title: Supported rhodium catalysts for ammonia–borane hydrolysis: Dependence of the catalytic activity on the highest occupied state of the single rhodium atoms publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201701089 contributor: fullname: Wang – volume: 117 start-page: 14992 year: 2013 ident: ref_30 article-title: Boron and Nitrogen Codoped Nanodiamond as an Efficient Metal-Free Catalyst for Oxygen Reduction Reaction publication-title: J. Phys. Chem. C doi: 10.1021/jp4044094 contributor: fullname: Liu – volume: 2 start-page: 13845 year: 2014 ident: ref_44 article-title: Amorphous Ni(OH)2 @ three-dimensional Ni core–shell nanostructures for high capacitance pseudocapacitors and asymmetric supercapacitors publication-title: J. Mater. Chem. A doi: 10.1039/C4TA02486A contributor: fullname: Su – volume: 45 start-page: 8118 year: 2020 ident: ref_3 article-title: Spatially localized fabrication of uniform Rh nanoclusters on nanosheet-assembled hierarchical carbon architectures as excellent electrocatalysts for boosting alkaline hydrogen evolution publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2020.01.121 contributor: fullname: Hu – volume: 47 start-page: 2561 year: 2018 ident: ref_8 article-title: Hyper-cross-linked polymer supported rhodium: An effective catalyst for hydrogen evolution from ammonia borane publication-title: Dalton Trans. doi: 10.1039/C7DT04549B contributor: fullname: Xu – volume: 455 start-page: 326 year: 2018 ident: ref_9 article-title: Ultrafine and highly dispersed Ru nanoparticles supported on nitrogen-doped carbon nanosheets: Efficient catalysts for ammonia borane hydrolysis publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2018.05.192 contributor: fullname: Zhong – volume: 40 start-page: 1062 year: 2015 ident: ref_27 article-title: Rh nanoparticles supported on graphene as efficient catalyst for hydrolytic dehydrogenation of amine boranes for chemical hydrogen storage publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2014.11.031 contributor: fullname: Shen – volume: 66 start-page: 144 year: 2014 ident: ref_42 article-title: Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel publication-title: Carbon doi: 10.1016/j.carbon.2013.08.052 contributor: fullname: Chang – volume: 38 start-page: 10864 year: 2013 ident: ref_50 article-title: Fast hydrogen generation from NaBH4 hydrolysis catalyzed by carbon aerogels supported cobalt nanoparticles publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2013.01.150 contributor: fullname: Zhu – volume: 22 start-page: 485 year: 2011 ident: ref_35 article-title: Functionalization of nanodiamond with epoxy monomer publication-title: Chin. Chem. Lett. doi: 10.1016/j.cclet.2010.10.047 contributor: fullname: Zhang – volume: 36 start-page: 1411 year: 2011 ident: ref_46 article-title: Hydrogen generation by hydrolysis of ammonia borane with a nanoporous cobalt–tungsten–boron–phosphorus catalyst supported on Ni foam publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2010.10.066 contributor: fullname: Yang – volume: 6 start-page: 1656 year: 2013 ident: ref_4 article-title: Metal–organic frameworks as platforms for clean energy publication-title: Energy Environ. Sci. doi: 10.1039/c3ee40507a contributor: fullname: Li – volume: 198 start-page: 162 year: 2016 ident: ref_18 article-title: Ceria supported rhodium nanoparticles: Superb catalytic activity in hydrogen generation from the hydrolysis of ammonia borane publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2016.05.061 contributor: fullname: Akbayrak – volume: 778 start-page: 643 year: 2019 ident: ref_34 article-title: Effect of metal ion concentration in precursor solution on structure and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 publication-title: J. Alloy. Compd. doi: 10.1016/j.jallcom.2018.11.189 contributor: fullname: Ma – volume: 546 start-page: 324 year: 2019 ident: ref_55 article-title: Noble metal nanoparticles supported on activated carbon: Highly recyclable catalysts in hydrogen generation from the hydrolysis of ammonia borane publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2019.03.070 contributor: fullname: Akbayrak – volume: 210 start-page: 462 year: 2017 ident: ref_40 article-title: Promoted effect of alkalization on the catalytic performance of Rh/alk-Ti 3 C 2 X 2 (X O, F) for the hydrodechlorination of chlorophenols in base-free aqueous medium publication-title: Appl. Catal. Environ. doi: 10.1016/j.apcatb.2017.04.017 contributor: fullname: Ming – volume: 43 start-page: 14816 year: 2018 ident: ref_36 article-title: Catalytic oxidative desulfurization of dibenzothiophene utilizing molybdenum and vanadium oxides supported on MCM-41 publication-title: Int. J. Hydrog. Energy doi: 10.1016/j.ijhydene.2018.05.102 contributor: fullname: Teimouri – ident: ref_6 doi: 10.1016/j.ijhydene.2020.07.097 – volume: 91 start-page: 10589 year: 2019 ident: ref_37 article-title: AuPt/MOF–Graphene: A Synergistic Catalyst with Surprisingly High Peroxidase-Like Activity and Its Application for H2O2 Detection publication-title: Anal. Chem. doi: 10.1021/acs.analchem.9b01715 contributor: fullname: Zhang |
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| SubjectTerms | Ammonia ammonia–borane Boranes Catalysts Catalytic activity Chemical reactions Chemical synthesis Clean energy Diamonds Hydrogen hydrogen evolution Hydrogen evolution reactions Hydrogen production Hydrolysis Investigations nanodiamond Nanoparticles Nanostructure Particle size Rhodium rhodium nanoparticles |
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| Title | Facile Fabrication of Rhodium/Nanodiamond Hybrid as Advanced Catalyst toward Hydrogen Production from Ammonia–Borane |
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