Tri‐Coordinated Boron Species in Confined Boron Oxide Catalysts for Enhanced Low‐Temperature Oxidative Dehydrogenation of Propane

• Published in: Angewandte Chemie International Edition Vol. 64; no. 28; pp. e202507525 - n/a
• Main Authors: Zheng, Yuenan, Chen, Weixi, Liu, Zhankai, Lu, Wen‐Duo, Li, Wen‐Cui, Wang, Dongqi, Lu, An‐Hui
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 07.07.2025
• Edition: International ed. in English
• Subjects: Alkenes; Boron; Boron oxide; Boron oxides; Catalysts; Catalytic converters; Chemical synthesis; Confined structure; Dehydrogenation; Heterogeneous catalysis; Hydrogen bonding; Hydroxyl groups; Molecular dynamics; Oxidative dehydrogenation; Propane; Silica; Silicon dioxide; Species; Confined structure; Heterogeneous catalysis; Boron oxide; Oxidative dehydrogenation; Propane

Boron‐based catalysts exhibit great potential for oxidative dehydrogenation of propane (ODHP) to produce olefins. The straightforward synthesis of confined boron‐based catalysts commonly using H3BO3 is intractable because of its abundant hydroxyl groups easily interacting with the supports in a spat...