Recent advances in preparation and morphology control of polymeric membranes formed by nonsolvent induced phase separation

•Recent advances in the fundamentals of nonsolvent induced phase separation (NIPS).•Preparation of membranes containing amphiphilic copolymers or inorganic particles by NIPS.•Review on three novel morphology control techniques based on NIPS. Nonsolvent induced phase separation (NIPS) is the most wid...

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Published inCurrent opinion in chemical engineering Vol. 2; no. 2; pp. 229 - 237
Main Authors Wang, Da-Ming, Lai, Juin-Yih
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.05.2013
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Abstract •Recent advances in the fundamentals of nonsolvent induced phase separation (NIPS).•Preparation of membranes containing amphiphilic copolymers or inorganic particles by NIPS.•Review on three novel morphology control techniques based on NIPS. Nonsolvent induced phase separation (NIPS) is the most widely used method to prepare membranes for separation processes. Even though it has been used for about five decades, NIPS still attracts much attention nowadays. In the present article, we first discuss some recent advances in the fundamentals of NIPS, including the mechanism of membrane formation and the selection of polymer, solvent, and nonsolvent. We will also review the recent researches about modification of membranes by blending copolymers or inorganic particles in the casting solution. The blending modification technique has drawn extensive attention because it can accomplish membrane fabrication and modification in one step. In addition, reviews are given for the development of three novel morphology control techniques based on NIPS: phase separation micromolding (a method combining lithography and NIPS), the ‘breath figure’ method (a phase separation process induced by water vapor), and a technique based on the combination of NIPS and self-assembly of block copolymers.
AbstractList •Recent advances in the fundamentals of nonsolvent induced phase separation (NIPS).•Preparation of membranes containing amphiphilic copolymers or inorganic particles by NIPS.•Review on three novel morphology control techniques based on NIPS. Nonsolvent induced phase separation (NIPS) is the most widely used method to prepare membranes for separation processes. Even though it has been used for about five decades, NIPS still attracts much attention nowadays. In the present article, we first discuss some recent advances in the fundamentals of NIPS, including the mechanism of membrane formation and the selection of polymer, solvent, and nonsolvent. We will also review the recent researches about modification of membranes by blending copolymers or inorganic particles in the casting solution. The blending modification technique has drawn extensive attention because it can accomplish membrane fabrication and modification in one step. In addition, reviews are given for the development of three novel morphology control techniques based on NIPS: phase separation micromolding (a method combining lithography and NIPS), the ‘breath figure’ method (a phase separation process induced by water vapor), and a technique based on the combination of NIPS and self-assembly of block copolymers.
Author Lai, Juin-Yih
Wang, Da-Ming
Author_xml – sequence: 1
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  surname: Wang
  fullname: Wang, Da-Ming
  email: daming@ntu.edu.tw
  organization: Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan
– sequence: 2
  givenname: Juin-Yih
  surname: Lai
  fullname: Lai, Juin-Yih
  organization: Department of Chemical Engineering, Chung Yuan University, Chung-Li, Taiwan
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