Ternary copper(II) complexes with N-carboxymethyl-l-prolinato(2−) ion and imidazole or creatinine: A comparative study of the interligand interactions influencing the molecular recognition and stability

• Published in: Journal of inorganic biochemistry Vol. 99; no. 7; pp. 1424 - 1432
• Main Authors: Tribet, M., Covelo, B., Sicilia-Zafra, A.G., Navarrete-Casas, R., Choquesillo-Lazarte, D., González-Pérez, J.M., Castiñeiras, A., Niclós-Gutiérrez, J.
• Format: Journal Article
• Language: English
• Published: United States Elsevier Inc 01.07.2005
• Subjects: Copper - chemistry; Copper(II); Creatinine; Creatinine - chemistry; Crystal structure; Crystallography, X-Ray; Imidazole; Imidazoles - chemistry; Interligand interactions; Ligands; Models, Molecular; Molecular recognition; Molecular Structure; N-carboxymethyl-l-proline; Organometallic Compounds - chemical synthesis; Organometallic Compounds - chemistry; Proline - analogs & derivatives; Proline - chemistry; Creatinine; Imidazole; Molecular recognition; N-carboxymethyl-l-proline; Interligand interactions; Copper(II); Crystal structure

The compounds {[Cu(CMP)(Him)]·H2O}n (I) and [Cu(CMP)(crea)H2O]·3H2O (II) were synthesized and characterized by X-ray diffraction, thermal, spectral and magnetic methods (CMP=N-carboxymethyl-;l-prolinato(2−) ion, Him=imidazole and crea=creatinine). Appropriate structural comparison with other compoun...