Essential Quality Attributes of Tangible Bio‐Oils from Catalytic Pyrolysis of Lignocellulosic Biomass

This review covers the characteristics of pyrolysis and catalytic pyrolysis bio‐oils by focusing on the fundamental factors that determine bio‐oil upgradability. The abundant works on the subject of bio‐oil production from lignocellulosic biomass were studied to establish the essential attributes of...

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Published inChemical record Vol. 19; no. 9; pp. 2044 - 2057
Main Authors Zhang, Cheng, Zhang, Z. Conrad
Format Journal Article
LanguageEnglish
Published United States Wiley Subscription Services, Inc 01.09.2019
Subjects
Bio-oils
Biofuels
Biomass
Calorific value
Catalysis
Catalysts
catalytic pyrolysis
higher heating value (HHV)
Lignin - chemistry
Lignocellulose
lignocellulosic biomass
Oxygen
Oxygen - chemistry
Oxygen content
Plant Oils - chemistry
Plants - chemistry
Pyrolysis
Quality management
Stability analysis
zeolite
biomass
catalytic pyrolysis
zeolite
Bio-oils
higher heating value (HHV)
oxygen content
lignocellulosic biomass
Online AccessGet full text
ISSN1527-8999
1528-0691
1528-0691
DOI10.1002/tcr.201900001

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Abstract This review covers the characteristics of pyrolysis and catalytic pyrolysis bio‐oils by focusing on the fundamental factors that determine bio‐oil upgradability. The abundant works on the subject of bio‐oil production from lignocellulosic biomass were studied to establish the essential attributes of the bio‐oils for assessment of the oil stability and upgradability. Bio‐oils from catalytic pyrolysis processes relating to catalysts of different compositions and structures are discussed. A general relationship between the higher heating value and the oxygen content in the catalytic pyrolysis oils exists, but this relationship does not apply to the thermal pyrolysis oil. Reporting bio‐oil yield is meaningful only when the oxygen content of the oil is measured because the pyrolytic oil stability is mainly determined by the oxygen content. Isoenergy plot that associates bio‐oil yield with oxygen content is presented and discussed. The quality of a pyrolytic bio‐oil determines whether the oil is feasible for downstream upgrading. This review shows that the oxygen content in bio‐oil is a prevailing quality descriptor with clear correlation to the heating value and the upgradability of the oil. Development of efficient catalytic pyrolysis is critically important in deep pyrolytic deoxygenation to produce tangible bio‐oil.
AbstractList This review covers the characteristics of pyrolysis and catalytic pyrolysis bio‐oils by focusing on the fundamental factors that determine bio‐oil upgradability. The abundant works on the subject of bio‐oil production from lignocellulosic biomass were studied to establish the essential attributes of the bio‐oils for assessment of the oil stability and upgradability. Bio‐oils from catalytic pyrolysis processes relating to catalysts of different compositions and structures are discussed. A general relationship between the higher heating value and the oxygen content in the catalytic pyrolysis oils exists, but this relationship does not apply to the thermal pyrolysis oil. Reporting bio‐oil yield is meaningful only when the oxygen content of the oil is measured because the pyrolytic oil stability is mainly determined by the oxygen content. Isoenergy plot that associates bio‐oil yield with oxygen content is presented and discussed.
This review covers the characteristics of pyrolysis and catalytic pyrolysis bio-oils by focusing on the fundamental factors that determine bio-oil upgradability. The abundant works on the subject of bio-oil production from lignocellulosic biomass were studied to establish the essential attributes of the bio-oils for assessment of the oil stability and upgradability. Bio-oils from catalytic pyrolysis processes relating to catalysts of different compositions and structures are discussed. A general relationship between the higher heating value and the oxygen content in the catalytic pyrolysis oils exists, but this relationship does not apply to the thermal pyrolysis oil. Reporting bio-oil yield is meaningful only when the oxygen content of the oil is measured because the pyrolytic oil stability is mainly determined by the oxygen content. Isoenergy plot that associates bio-oil yield with oxygen content is presented and discussed.This review covers the characteristics of pyrolysis and catalytic pyrolysis bio-oils by focusing on the fundamental factors that determine bio-oil upgradability. The abundant works on the subject of bio-oil production from lignocellulosic biomass were studied to establish the essential attributes of the bio-oils for assessment of the oil stability and upgradability. Bio-oils from catalytic pyrolysis processes relating to catalysts of different compositions and structures are discussed. A general relationship between the higher heating value and the oxygen content in the catalytic pyrolysis oils exists, but this relationship does not apply to the thermal pyrolysis oil. Reporting bio-oil yield is meaningful only when the oxygen content of the oil is measured because the pyrolytic oil stability is mainly determined by the oxygen content. Isoenergy plot that associates bio-oil yield with oxygen content is presented and discussed.
This review covers the characteristics of pyrolysis and catalytic pyrolysis bio‐oils by focusing on the fundamental factors that determine bio‐oil upgradability. The abundant works on the subject of bio‐oil production from lignocellulosic biomass were studied to establish the essential attributes of the bio‐oils for assessment of the oil stability and upgradability. Bio‐oils from catalytic pyrolysis processes relating to catalysts of different compositions and structures are discussed. A general relationship between the higher heating value and the oxygen content in the catalytic pyrolysis oils exists, but this relationship does not apply to the thermal pyrolysis oil. Reporting bio‐oil yield is meaningful only when the oxygen content of the oil is measured because the pyrolytic oil stability is mainly determined by the oxygen content. Isoenergy plot that associates bio‐oil yield with oxygen content is presented and discussed. The quality of a pyrolytic bio‐oil determines whether the oil is feasible for downstream upgrading. This review shows that the oxygen content in bio‐oil is a prevailing quality descriptor with clear correlation to the heating value and the upgradability of the oil. Development of efficient catalytic pyrolysis is critically important in deep pyrolytic deoxygenation to produce tangible bio‐oil.
Author Zhang, Cheng
Zhang, Z. Conrad
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Issue 9
Keywords biomass
catalytic pyrolysis
zeolite
Bio-oils
higher heating value (HHV)
oxygen content
lignocellulosic biomass
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Snippet This review covers the characteristics of pyrolysis and catalytic pyrolysis bio‐oils by focusing on the fundamental factors that determine bio‐oil...
This review covers the characteristics of pyrolysis and catalytic pyrolysis bio-oils by focusing on the fundamental factors that determine bio-oil...
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SubjectTerms Bio-oils
Biofuels
Biomass
Calorific value
Catalysis
Catalysts
catalytic pyrolysis
higher heating value (HHV)
Lignin - chemistry
Lignocellulose
lignocellulosic biomass
Oxygen
Oxygen - chemistry
Oxygen content
Plant Oils - chemistry
Plants - chemistry
Pyrolysis
Quality management
Stability analysis
zeolite
Title Essential Quality Attributes of Tangible Bio‐Oils from Catalytic Pyrolysis of Lignocellulosic Biomass
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Ftcr.201900001
https://www.ncbi.nlm.nih.gov/pubmed/31483089
https://www.proquest.com/docview/2283858029
https://www.proquest.com/docview/2284559917
Volume 19
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