Visible-light activation of carbon-supported BiVO4 photocatalysts

[Display omitted] •Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline degradation.•Recovery and reuse of BiVO4/carbon photocatalysts. Bismuth vanadate (BiVO4) has gained attention for several applications, including ph...

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Published inJournal of photochemistry and photobiology. A, Chemistry. Vol. 447; p. 115174
Main Authors Lopes, Joana L., Estrada, Ana C., Fateixa, Sara, Sobolev, Nikolai A., Daniel-da-Silva, Ana L., Trindade, Tito
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.01.2024
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Online AccessGet full text
ISSN1010-6030
1873-2666
DOI10.1016/j.jphotochem.2023.115174

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Abstract [Display omitted] •Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline degradation.•Recovery and reuse of BiVO4/carbon photocatalysts. Bismuth vanadate (BiVO4) has gained attention for several applications, including photocatalysis applied to water purification technologies. This applies to the most stable BiVO4 polymorph (monoclinic scheelite), exhibiting photocatalytic activity under visible-light irradiation. However, this semiconductor presents some limitations, namely the cost and low adsorption capacity for organic pollutants. Finding green chemical strategies aiming at a more sustainable use of this semiconductor is the subject of the present research. By the hydrothermal carbonization of κ-carrageenan, a biopolymer extracted from red seaweeds, we describe the preparation of monoclinic BiVO4 supported on carbon spheres. These hybrid materials show visible-light photocatalytic activity to remove tetracycline (TC) in water through a hydroxyl radical mechanism. The hybrid photocatalysts feature adequate wavelength range for photon harvesting, good adsorption capacity, durability, and the ability to reuse in subsequent catalytic steps, thus making them less costly and more sustainable.
AbstractList [Display omitted] •Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline degradation.•Recovery and reuse of BiVO4/carbon photocatalysts. Bismuth vanadate (BiVO4) has gained attention for several applications, including photocatalysis applied to water purification technologies. This applies to the most stable BiVO4 polymorph (monoclinic scheelite), exhibiting photocatalytic activity under visible-light irradiation. However, this semiconductor presents some limitations, namely the cost and low adsorption capacity for organic pollutants. Finding green chemical strategies aiming at a more sustainable use of this semiconductor is the subject of the present research. By the hydrothermal carbonization of κ-carrageenan, a biopolymer extracted from red seaweeds, we describe the preparation of monoclinic BiVO4 supported on carbon spheres. These hybrid materials show visible-light photocatalytic activity to remove tetracycline (TC) in water through a hydroxyl radical mechanism. The hybrid photocatalysts feature adequate wavelength range for photon harvesting, good adsorption capacity, durability, and the ability to reuse in subsequent catalytic steps, thus making them less costly and more sustainable.
ArticleNumber 115174
Author Sobolev, Nikolai A.
Daniel-da-Silva, Ana L.
Estrada, Ana C.
Trindade, Tito
Lopes, Joana L.
Fateixa, Sara
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  givenname: Ana C.
  surname: Estrada
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  givenname: Nikolai A.
  surname: Sobolev
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  givenname: Ana L.
  surname: Daniel-da-Silva
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  givenname: Tito
  orcidid: 0000-0002-5456-7243
  surname: Trindade
  fullname: Trindade, Tito
  email: tito@ua.pt
  organization: Department of Chemistry and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal
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CitedBy_id crossref_primary_10_1016_j_ijhydene_2025_01_393
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crossref_primary_10_1016_j_inoche_2024_113023
crossref_primary_10_1016_j_physb_2025_416990
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Keywords Carbon spheres
Bismuth vanadate
Hydrothermal carbonization
Visible-light photocatalysis
Wastewater treatment
Tetracycline
Language English
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Snippet [Display omitted] •Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline...
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StartPage 115174
SubjectTerms Bismuth vanadate
Carbon spheres
Hydrothermal carbonization
Tetracycline
Visible-light photocatalysis
Wastewater treatment
Title Visible-light activation of carbon-supported BiVO4 photocatalysts
URI https://dx.doi.org/10.1016/j.jphotochem.2023.115174
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