Visible-light activation of carbon-supported BiVO4 photocatalysts
[Display omitted] •Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline degradation.•Recovery and reuse of BiVO4/carbon photocatalysts. Bismuth vanadate (BiVO4) has gained attention for several applications, including ph...
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Published in | Journal of photochemistry and photobiology. A, Chemistry. Vol. 447; p. 115174 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
15.01.2024
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Subjects | |
Online Access | Get full text |
ISSN | 1010-6030 1873-2666 |
DOI | 10.1016/j.jphotochem.2023.115174 |
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Abstract | [Display omitted]
•Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline degradation.•Recovery and reuse of BiVO4/carbon photocatalysts.
Bismuth vanadate (BiVO4) has gained attention for several applications, including photocatalysis applied to water purification technologies. This applies to the most stable BiVO4 polymorph (monoclinic scheelite), exhibiting photocatalytic activity under visible-light irradiation. However, this semiconductor presents some limitations, namely the cost and low adsorption capacity for organic pollutants. Finding green chemical strategies aiming at a more sustainable use of this semiconductor is the subject of the present research. By the hydrothermal carbonization of κ-carrageenan, a biopolymer extracted from red seaweeds, we describe the preparation of monoclinic BiVO4 supported on carbon spheres. These hybrid materials show visible-light photocatalytic activity to remove tetracycline (TC) in water through a hydroxyl radical mechanism. The hybrid photocatalysts feature adequate wavelength range for photon harvesting, good adsorption capacity, durability, and the ability to reuse in subsequent catalytic steps, thus making them less costly and more sustainable. |
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AbstractList | [Display omitted]
•Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline degradation.•Recovery and reuse of BiVO4/carbon photocatalysts.
Bismuth vanadate (BiVO4) has gained attention for several applications, including photocatalysis applied to water purification technologies. This applies to the most stable BiVO4 polymorph (monoclinic scheelite), exhibiting photocatalytic activity under visible-light irradiation. However, this semiconductor presents some limitations, namely the cost and low adsorption capacity for organic pollutants. Finding green chemical strategies aiming at a more sustainable use of this semiconductor is the subject of the present research. By the hydrothermal carbonization of κ-carrageenan, a biopolymer extracted from red seaweeds, we describe the preparation of monoclinic BiVO4 supported on carbon spheres. These hybrid materials show visible-light photocatalytic activity to remove tetracycline (TC) in water through a hydroxyl radical mechanism. The hybrid photocatalysts feature adequate wavelength range for photon harvesting, good adsorption capacity, durability, and the ability to reuse in subsequent catalytic steps, thus making them less costly and more sustainable. |
ArticleNumber | 115174 |
Author | Sobolev, Nikolai A. Daniel-da-Silva, Ana L. Estrada, Ana C. Trindade, Tito Lopes, Joana L. Fateixa, Sara |
Author_xml | – sequence: 1 givenname: Joana L. surname: Lopes fullname: Lopes, Joana L. organization: Department of Chemistry and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal – sequence: 2 givenname: Ana C. surname: Estrada fullname: Estrada, Ana C. email: ana.estrada@ua.pt organization: Department of Chemistry and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal – sequence: 3 givenname: Sara surname: Fateixa fullname: Fateixa, Sara organization: Department of Chemistry and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal – sequence: 4 givenname: Nikolai A. surname: Sobolev fullname: Sobolev, Nikolai A. organization: Department of Physics and i3N, University of Aveiro, 3810-193 Aveiro, Portugal – sequence: 5 givenname: Ana L. surname: Daniel-da-Silva fullname: Daniel-da-Silva, Ana L. organization: Department of Chemistry and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal – sequence: 6 givenname: Tito orcidid: 0000-0002-5456-7243 surname: Trindade fullname: Trindade, Tito email: tito@ua.pt organization: Department of Chemistry and CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal |
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Keywords | Carbon spheres Bismuth vanadate Hydrothermal carbonization Visible-light photocatalysis Wastewater treatment Tetracycline |
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•Towards more sustainable synthesis of BiVO4/carbon materials.•BiVO4/carbon as visible-light activated photocatalyst for tetracycline... |
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SubjectTerms | Bismuth vanadate Carbon spheres Hydrothermal carbonization Tetracycline Visible-light photocatalysis Wastewater treatment |
Title | Visible-light activation of carbon-supported BiVO4 photocatalysts |
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