Chitosan, starch, polyaniline and polypyrrole biocomposite with sugarcane bagasse for the efficient removal of Acid Black dye
Polymeric biocomposites (Polyaniline/sugarcane bagasse (Pan/SB), polypyrrole (PPy/SB), polyaniline/chitosan (PAn/Ch), polyaniline/starch (PAn/St) and polypyrrole/starch (PPy/St)) were prepared and applied for Acid Black-234 (AB-234) dye removal as a function of pH, reaction time, adsorbent dose, ini...
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Published in | International journal of biological macromolecules Vol. 147; pp. 439 - 452 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
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Elsevier B.V
15.03.2020
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Abstract | Polymeric biocomposites (Polyaniline/sugarcane bagasse (Pan/SB), polypyrrole (PPy/SB), polyaniline/chitosan (PAn/Ch), polyaniline/starch (PAn/St) and polypyrrole/starch (PPy/St)) were prepared and applied for Acid Black-234 (AB-234) dye removal as a function of pH, reaction time, adsorbent dose, initial dye concentration and temperature. The optimum pH for the efficient adsorption for SB, PPy/SB, PAn/SB, PPy/Ch, PAn/Ch, PPy/St and PAn/St were 2, 3, 4, 4, 5, 3 and 3, respectively using adsorbent dose of 0.05 g for the reaction time of 60 min. The pseudo-first-order-kinetic model better explained the biosorption processes of SB, PAn/SB, PAn/Ch, PPy/St and PAn/St, while pseudo-second-order kinetic model better fitted to the kinetic data of PPy/SB and PPy/Ch. It was observed that the biosorption process of dye showed the satisfactory fitness for Langmuir isotherm for the biosorbents with maximum adsorption capacities 52.6, 100, 90.91, 90.0, 71.4, 66.6 and 62.5 for SB, PPy/SB, PAn/SB, PPy/Ch, PAn/Ch, PPy/St and PAn/St, respectively. The thermodynamic study revealed the exothermic nature of adsorption of dye on to biocomposites. Results revealed that polymeric biocomposites are efficient adsorbent and could possibly be used for the adsorption of dyes from textile wastewater.
•Chitosan, starch, polyaniline and polypyrrole composites were prepared with sugarcane bagasse.•Composites were characterized and used for the adsorption of Acid Black-234 dye.•Dye adsorption followed the pseudo-first-order-kinetic model and Langmuir isotherm•The biocomposites have potential to remove dye from textile wastewater |
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AbstractList | Polymeric biocomposites (Polyaniline/sugarcane bagasse (Pan/SB), polypyrrole (PPy/SB), polyaniline/chitosan (PAn/Ch), polyaniline/starch (PAn/St) and polypyrrole/starch (PPy/St)) were prepared and applied for Acid Black-234 (AB-234) dye removal as a function of pH, reaction time, adsorbent dose, initial dye concentration and temperature. The optimum pH for the efficient adsorption for SB, PPy/SB, PAn/SB, PPy/Ch, PAn/Ch, PPy/St and PAn/St were 2, 3, 4, 4, 5, 3 and 3, respectively using adsorbent dose of 0.05 g for the reaction time of 60 min. The pseudo-first-order-kinetic model better explained the biosorption processes of SB, PAn/SB, PAn/Ch, PPy/St and PAn/St, while pseudo-second-order kinetic model better fitted to the kinetic data of PPy/SB and PPy/Ch. It was observed that the biosorption process of dye showed the satisfactory fitness for Langmuir isotherm for the biosorbents with maximum adsorption capacities 52.6, 100, 90.91, 90.0, 71.4, 66.6 and 62.5 for SB, PPy/SB, PAn/SB, PPy/Ch, PAn/Ch, PPy/St and PAn/St, respectively. The thermodynamic study revealed the exothermic nature of adsorption of dye on to biocomposites. Results revealed that polymeric biocomposites are efficient adsorbent and could possibly be used for the adsorption of dyes from textile wastewater.
•Chitosan, starch, polyaniline and polypyrrole composites were prepared with sugarcane bagasse.•Composites were characterized and used for the adsorption of Acid Black-234 dye.•Dye adsorption followed the pseudo-first-order-kinetic model and Langmuir isotherm•The biocomposites have potential to remove dye from textile wastewater Polymeric biocomposites (Polyaniline/sugarcane bagasse (Pan/SB), polypyrrole (PPy/SB), polyaniline/chitosan (PAn/Ch), polyaniline/starch (PAn/St) and polypyrrole/starch (PPy/St)) were prepared and applied for Acid Black-234 (AB-234) dye removal as a function of pH, reaction time, adsorbent dose, initial dye concentration and temperature. The optimum pH for the efficient adsorption for SB, PPy/SB, PAn/SB, PPy/Ch, PAn/Ch, PPy/St and PAn/St were 2, 3, 4, 4, 5, 3 and 3, respectively using adsorbent dose of 0.05 g for the reaction time of 60 min. The pseudo-first-order-kinetic model better explained the biosorption processes of SB, PAn/SB, PAn/Ch, PPy/St and PAn/St, while pseudo-second-order kinetic model better fitted to the kinetic data of PPy/SB and PPy/Ch. It was observed that the biosorption process of dye showed the satisfactory fitness for Langmuir isotherm for the biosorbents with maximum adsorption capacities 52.6, 100, 90.91, 90.0, 71.4, 66.6 and 62.5 for SB, PPy/SB, PAn/SB, PPy/Ch, PAn/Ch, PPy/St and PAn/St, respectively. The thermodynamic study revealed the exothermic nature of adsorption of dye on to biocomposites. Results revealed that polymeric biocomposites are efficient adsorbent and could possibly be used for the adsorption of dyes from textile wastewater. |
Author | Iqbal, Munawar Hussain, Fida Sarim, Fazli Malik Bhatti, Haq Nawaz Noreen, Saima |
Author_xml | – sequence: 1 givenname: Saima surname: Noreen fullname: Noreen, Saima email: saima_bashir03@yahoo.com organization: Department of Chemistry, University of Agriculture, Faisalabad 38040, Pakistan – sequence: 2 givenname: Haq Nawaz surname: Bhatti fullname: Bhatti, Haq Nawaz organization: Department of Chemistry, University of Agriculture, Faisalabad 38040, Pakistan – sequence: 3 givenname: Munawar surname: Iqbal fullname: Iqbal, Munawar email: bosalvee@yahoo.com organization: Department of Chemistry, The University of Lahore, Lahore 53700, Pakistan – sequence: 4 givenname: Fida surname: Hussain fullname: Hussain, Fida organization: Department of Botany, Qurtuba University of Science and Information Technology, Peshawar 25100, Pakistan – sequence: 5 givenname: Fazli Malik surname: Sarim fullname: Sarim, Fazli Malik organization: Department of Botany, Qurtuba University of Science and Information Technology, Peshawar 25100, Pakistan |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31917212$$D View this record in MEDLINE/PubMed |
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Keywords | Dye biosorption Biocomposite Wastewater Biopolymers |
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