Chiral Induction in Liquid Crystals with Dopants Derived from 1-Phenyl-2-Aminoalcohols
New chiral additives derived from 1-phenyl-2-aminoalcohols have been prepared and tested. Especially ephedrine and pseudoephedrine as chiral auxiliaries with two asymmetric C atoms offer functional groups of divergent reactivity. Dopants prepared by acylation with promesogenic agents can be used in...
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Published in | Molecular Crystals and Liquid Crystals Vol. 588; no. 1; pp. 51 - 60 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Philadelphia
Taylor & Francis Group
01.01.2014
Taylor & Francis Ltd |
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Abstract | New chiral additives derived from 1-phenyl-2-aminoalcohols have been prepared and tested. Especially ephedrine and pseudoephedrine as chiral auxiliaries with two asymmetric C atoms offer functional groups of divergent reactivity. Dopants prepared by acylation with promesogenic agents can be used in various electro-optic devices. A specific utilization concerns bistable cholesteric liquid crystal displays with stacked double layer construction in order to enhance the luminance of reflected light. Further, the solubility in nematic mixtures, the long term phase behavior, the dopant's impact on textures and phase behavior, the electro-optic response and the photostability of cholesteric mixtures have been investigated. |
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AbstractList | New chiral additives derived from 1-phenyl-2-aminoalcohols have been prepared and tested. Especially ephedrine and pseudoephedrine as chiral auxiliaries with two asymmetric C atoms offer functional groups of divergent reactivity. Dopants prepared by acylation with promesogenic agents can be used in various electro-optic devices. A specific utilization concerns bistable cholesteric liquid crystal displays with stacked double layer construction in order to enhance the luminance of reflected light. Further, the solubility in nematic mixtures, the long term phase behavior, the dopant's impact on textures and phase behavior, the electro-optic response and the photostability of cholesteric mixtures have been investigated. New chiral additives derived from 1-phenyl-2-aminoalcohols have been prepared and tested. Especially ephedrine and pseudoephedrine as chiral auxiliaries with two asymmetric C atoms offer functional groups of divergent reactivity. Dopants prepared by acylation with promesogenic agents can be used in various electro-optic devices. A specific utilization concerns bistable cholesteric liquid crystal displays with stacked double layer construction in order to enhance the luminance of reflected light. Further, the solubility in nematic mixtures, the long term phase behavior, the dopant's impact on textures and phase behavior, the electro-optic response and the photostability of cholesteric mixtures have been investigated. [PUBLICATION ABSTRACT] |
Author | Bauer, Monika Weissflog, Wolfgang Hartmann, Lutz Kuschel, Frank |
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References | The carboxylic acids were prepared following known protocols: trans-(4-n-pentylcyclohexane)carboxylic acid (CIT0023) 1972; 12 CIT0014 Heppke G. (CIT0015) 1986; 41 CIT0016 Kozachenko A. G. (CIT0012) 2002 Valyukh I. (CIT0013) 2003 CIT0018 CIT0017 Kawata Y. (CIT0010) 1997 CIT0019 CIT0021 CIT0020 CIT0001 CIT0022 Khan A. (CIT0011) 2001 Wu C.-M. (CIT0009) 2008 CIT0003 CIT0025 CIT0002 CIT0024 CIT0005 CIT0027 CIT0004 CIT0026 CIT0007 CIT0029 CIT0006 CIT0008 |
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Snippet | New chiral additives derived from 1-phenyl-2-aminoalcohols have been prepared and tested. Especially ephedrine and pseudoephedrine as chiral auxiliaries with... |
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SubjectTerms | Additives Aminoalcohols Atoms & subatomic particles bistable displays cholesteric Devices Dopants Double layer Electric properties Electro-optics LCDs Liquid crystal displays Liquid crystals Luminance Optical properties photostability Surface layer Texture Trace elements |
Title | Chiral Induction in Liquid Crystals with Dopants Derived from 1-Phenyl-2-Aminoalcohols |
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