Sequencing of metals in multivariate metal-organic frameworks
Most metal-organic frameworks (MOFs) contain just one type of metal in the nodes connecting the organic linkers. Multivariate MOFs containing multiple metals can offer greater selectivity in sorption and catalytic properties, but determining the arrangement of metals in these materials is challengin...
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| Published in | Science (American Association for the Advancement of Science) Vol. 369; no. 6504; pp. 674 - 680 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Washington
The American Association for the Advancement of Science
07.08.2020
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Most metal-organic frameworks (MOFs) contain just one type of metal in the nodes connecting the organic linkers. Multivariate MOFs containing multiple metals can offer greater selectivity in sorption and catalytic properties, but determining the arrangement of metals in these materials is challenging. Ji
et al.
found that atom-probe tomography can reveal sequences of metals for MOF-74 single crystals containing combinations of cobalt, cadmium, lead, and manganese ions. In this MOF, the metals form oxide rods that are connected by the organic linker into a honeycomb lattice. The obtained sequences, which were tuned by varying the proportion of metals and synthesis temperature, could be random, short and long duplicates, and single metal insertions.
Science
, this issue p.
674
Atom-probe tomography revealed the metal sequences in the oxide rods in a multivariate metal-organic framework compound.
We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-organic framework–74 containing mixed combinations of cobalt (Co), cadmium (Cd), lead (Pb), and manganese (Mn). Atom probe tomography of these crystals revealed the presence of heterogeneous spatial sequences of metal ions that we describe, depending on the metal and synthesis temperature used, as random (Co, Cd, 120°C), short duplicates (Co, Cd, 85°C), long duplicates (Co, Pb, 85°C), and insertions (Co, Mn, 85°C). Three crystals were examined for each sequence type, and the molar fraction of Co among all 12 samples was observed to vary from 0.4 to 0.9, without changing the sequence type. Compared with metal oxides, metal-organic frameworks have high tolerance for coexistence of different metal sizes in their rods and therefore assume various metal sequences. |
|---|---|
| AbstractList | Most metal-organic frameworks (MOFs) contain just one type of metal in the nodes connecting the organic linkers. Multivariate MOFs containing multiple metals can offer greater selectivity in sorption and catalytic properties, but determining the arrangement of metals in these materials is challenging. Ji
et al.
found that atom-probe tomography can reveal sequences of metals for MOF-74 single crystals containing combinations of cobalt, cadmium, lead, and manganese ions. In this MOF, the metals form oxide rods that are connected by the organic linker into a honeycomb lattice. The obtained sequences, which were tuned by varying the proportion of metals and synthesis temperature, could be random, short and long duplicates, and single metal insertions.
Science
, this issue p.
674
Atom-probe tomography revealed the metal sequences in the oxide rods in a multivariate metal-organic framework compound.
We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-organic framework–74 containing mixed combinations of cobalt (Co), cadmium (Cd), lead (Pb), and manganese (Mn). Atom probe tomography of these crystals revealed the presence of heterogeneous spatial sequences of metal ions that we describe, depending on the metal and synthesis temperature used, as random (Co, Cd, 120°C), short duplicates (Co, Cd, 85°C), long duplicates (Co, Pb, 85°C), and insertions (Co, Mn, 85°C). Three crystals were examined for each sequence type, and the molar fraction of Co among all 12 samples was observed to vary from 0.4 to 0.9, without changing the sequence type. Compared with metal oxides, metal-organic frameworks have high tolerance for coexistence of different metal sizes in their rods and therefore assume various metal sequences. Mapping metal sequences in MOFsMost metal-organic frameworks (MOFs) contain just one type of metal in the nodes connecting the organic linkers. Multivariate MOFs containing multiple metals can offer greater selectivity in sorption and catalytic properties, but determining the arrangement of metals in these materials is challenging. Ji et al. found that atom-probe tomography can reveal sequences of metals for MOF-74 single crystals containing combinations of cobalt, cadmium, lead, and manganese ions. In this MOF, the metals form oxide rods that are connected by the organic linker into a honeycomb lattice. The obtained sequences, which were tuned by varying the proportion of metals and synthesis temperature, could be random, short and long duplicates, and single metal insertions.Science, this issue p. 674We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-organic framework–74 containing mixed combinations of cobalt (Co), cadmium (Cd), lead (Pb), and manganese (Mn). Atom probe tomography of these crystals revealed the presence of heterogeneous spatial sequences of metal ions that we describe, depending on the metal and synthesis temperature used, as random (Co, Cd, 120°C), short duplicates (Co, Cd, 85°C), long duplicates (Co, Pb, 85°C), and insertions (Co, Mn, 85°C). Three crystals were examined for each sequence type, and the molar fraction of Co among all 12 samples was observed to vary from 0.4 to 0.9, without changing the sequence type. Compared with metal oxides, metal-organic frameworks have high tolerance for coexistence of different metal sizes in their rods and therefore assume various metal sequences. We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-organic framework-74 containing mixed combinations of cobalt (Co), cadmium (Cd), lead (Pb), and manganese (Mn). Atom probe tomography of these crystals revealed the presence of heterogeneous spatial sequences of metal ions that we describe, depending on the metal and synthesis temperature used, as random (Co, Cd, 120°C), short duplicates (Co, Cd, 85°C), long duplicates (Co, Pb, 85°C), and insertions (Co, Mn, 85°C). Three crystals were examined for each sequence type, and the molar fraction of Co among all 12 samples was observed to vary from 0.4 to 0.9, without changing the sequence type. Compared with metal oxides, metal-organic frameworks have high tolerance for coexistence of different metal sizes in their rods and therefore assume various metal sequences.We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-organic framework-74 containing mixed combinations of cobalt (Co), cadmium (Cd), lead (Pb), and manganese (Mn). Atom probe tomography of these crystals revealed the presence of heterogeneous spatial sequences of metal ions that we describe, depending on the metal and synthesis temperature used, as random (Co, Cd, 120°C), short duplicates (Co, Cd, 85°C), long duplicates (Co, Pb, 85°C), and insertions (Co, Mn, 85°C). Three crystals were examined for each sequence type, and the molar fraction of Co among all 12 samples was observed to vary from 0.4 to 0.9, without changing the sequence type. Compared with metal oxides, metal-organic frameworks have high tolerance for coexistence of different metal sizes in their rods and therefore assume various metal sequences. |
| Author | Yaghi, Omar M. Ji, Zhe Li, Tong |
| Author_xml | – sequence: 1 givenname: Zhe orcidid: 0000-0002-8532-333X surname: Ji fullname: Ji, Zhe organization: Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA., Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA., Kavli Energy NanoSciences Institute at Berkeley, Berkeley, CA 94720, USA., Berkeley Global Science Institute, Berkeley, CA 94720, USA – sequence: 2 givenname: Tong orcidid: 0000-0001-5729-1839 surname: Li fullname: Li, Tong organization: Institute for Materials, Ruhr-Universität Bochum, Universitätsstraße 150, 44801 Bochum, Germany – sequence: 3 givenname: Omar M. orcidid: 0000-0002-5611-3325 surname: Yaghi fullname: Yaghi, Omar M. organization: Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, USA., Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA., Kavli Energy NanoSciences Institute at Berkeley, Berkeley, CA 94720, USA., Berkeley Global Science Institute, Berkeley, CA 94720, USA., University of California, Berkeley–King Abdulaziz City for Science and Technology (KACST) Joint Center of Excellence for Nanomaterials for Clean Energy Applications, KACST, Riyadh 11442, Saudi Arabia |
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| Copyright | Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. |
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| Snippet | Most metal-organic frameworks (MOFs) contain just one type of metal in the nodes connecting the organic linkers. Multivariate MOFs containing multiple metals... Mapping metal sequences in MOFsMost metal-organic frameworks (MOFs) contain just one type of metal in the nodes connecting the organic linkers. Multivariate... We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-organic framework-74 containing mixed combinations of cobalt (Co),... |
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| SubjectTerms | Cadmium Cobalt Coexistence Crystals Heavy metals Lead Manganese Manganese ions Mapping Metal ions Metal oxides Metal-organic frameworks Metals Multivariate analysis Reproduction (copying) Rods Selectivity Single crystals Tomography |
| Title | Sequencing of metals in multivariate metal-organic frameworks |
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