Identification of bound water through infrared spectroscopy in methylcellulose

This paper describes the interaction of water with solid polymers. A portion of the water adsorbed in hydrophilic materials is strongly bound to individual sites (bound water), while an additional amount is bound less firmly to the polymeric chain (free water). Both, free and bound water, have been...

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Published inJournal of food engineering Vol. 59; no. 1; pp. 79 - 84
Main Authors Velazquez, G., Herrera-Gómez, A., Martı́n-Polo, M.O.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 01.08.2003
Elsevier
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ISSN0260-8774
1873-5770
DOI10.1016/S0260-8774(02)00428-4

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Abstract This paper describes the interaction of water with solid polymers. A portion of the water adsorbed in hydrophilic materials is strongly bound to individual sites (bound water), while an additional amount is bound less firmly to the polymeric chain (free water). Both, free and bound water, have been the subject of many studies that have uncovered, in some cases, qualitative evidence of the presence of bound water. In this paper we report a method to quantify the fraction of water adsorbed in the first layer in contact with an hydrophilic material. The measurement was carried out on infrared spectroscopy data of methylcellulose films exposed to several humid environments. The quantification was based on the determination of the change in the natural vibration frequency brought about by the interaction of water molecules with the solid.
AbstractList This paper describes the interaction of water with solid polymers. A portion of the water adsorbed in hydrophilic materials is strongly bound to individual sites (bound water), while an additional amount is bound less firmly to the polymeric chain (free water). Both, free and bound water, have been the subject of many studies that have uncovered, in some cases, qualitative evidence of the presence of bound water. In this paper we report a method to quantify the fraction of water adsorbed in the first layer in contact with an hydrophilic material. The measurement was carried out on infrared spectroscopy data of methylcellulose films exposed to several humid environments. The quantification was based on the determination of the change in the natural vibration frequency brought about by the interaction of water molecules with the solid.
Author Martı́n-Polo, M.O.
Velazquez, G.
Herrera-Gómez, A.
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  surname: Herrera-Gómez
  fullname: Herrera-Gómez, A.
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  surname: Martı́n-Polo
  fullname: Martı́n-Polo, M.O.
  organization: Oregon State University, 100 Wiegand Hall, Corvallis, OR 97331-6602, USA
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Issue 1
Keywords Relative humidity
Infrared spectrometry
Free water
Analysis method
Polymer
Identification
Cellulose(methyl)
Bound water
Language English
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SSID ssj0005022
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Snippet This paper describes the interaction of water with solid polymers. A portion of the water adsorbed in hydrophilic materials is strongly bound to individual...
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SubjectTerms adsorption
Biological and medical sciences
bound water
dried foods
food chemistry
Food industries
Fundamental and applied biological sciences. Psychology
General aspects
hydrophilic polymers
infrared spectroscopy
Methods of analysis, processing and quality control, regulation, standards
methylcellulose
relative humidity
water
Title Identification of bound water through infrared spectroscopy in methylcellulose
URI https://dx.doi.org/10.1016/S0260-8774(02)00428-4
https://www.proquest.com/docview/49138249
Volume 59
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