Selectivity in Cationic Cyclizations Involving Alkynes: A Computational Study on the Biomimetic Synthesis of Steroids
Computational studies on the electrophilic cyclization between alkynes and transient carbocations or Lewis‐acid‐activated epoxides show that the regiochemistry of the reaction depends on the terminal or internal position of the triple bond. Reactants possessing terminal alkynyl groups lead to six‐me...
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Published in | Chemistry : a European journal Vol. 29; no. 19; pp. e202204028 - n/a |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Germany
Wiley Subscription Services, Inc
03.04.2023
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Subjects | |
Online Access | Get full text |
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