Quantum dynamics of the collinear CsHH system
Quantum-mechanical transition probabilities for the collinear reaction Cs( nl)+HH( v) → CsH( v')+H have been computed using hyperspherical coordinates. The reaction involves a strong non-localized ionic-covalent electronic coupling. Large probabilities, with sharp resonance features, are obtain...
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Published in | Chemical physics letters Vol. 135; no. 4; pp. 377 - 380 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
10.04.1987
Elsevier Science Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | Quantum-mechanical transition probabilities for the collinear reaction Cs(
nl)+HH(
v) → CsH(
v')+H have been computed using hyperspherical coordinates. The reaction involves a strong non-localized ionic-covalent electronic coupling. Large probabilities, with sharp resonance features, are obtained for nearly thermoneutral transitions such as Cs(6s) + HH(
v= 6), Cs(7p) + HH(
v = 0) → CsH(
v' = 0) + H. |
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ISSN: | 0009-2614 1873-4448 |
DOI: | 10.1016/0009-2614(87)85175-8 |