Fabrication of high surface area ribbon electrodes for use in redox flow batteries via coaxial electrospinning
•A simple and reliable technique was developed electrospinning fibers with a flat ribbon-like morphology.•A ribbon-based electrode layer shows increased surface to volume ratio.•The ribbon-based electrode showed 2x higher permeability and 40x higher volumetric specific surface higher than commercial...
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Published in | Journal of energy storage Vol. 33; no. C; p. 102079 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
01.01.2021
Elsevier |
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Abstract | •A simple and reliable technique was developed electrospinning fibers with a flat ribbon-like morphology.•A ribbon-based electrode layer shows increased surface to volume ratio.•The ribbon-based electrode showed 2x higher permeability and 40x higher volumetric specific surface higher than commercial electrodes.•The proposed materials were validated in an operating cell and shown to outperform commercial materials at low to moderate current density.
A method for the preparation of electrospun with fibers possessing a ribbon-like cross-sectional shape was developed. These materials could prove beneficial as flow-through electrodes, since ribbons provide a higher surface-to-volume ratio compared to fibers, thereby providing higher reactive surface area at a given porosity. Fabrication of these materials was accomplished by electrospinning a coaxial fiber with a polystyrene core and polyacrylonitrile shell, followed by leaching of the core material leading to the collapse of the shell into a flat ribbon. The surviving shell was then carbonized to make an electrically conductive and electrochemically reactive fibrous structure. Analysis by x-ray computed tomography showed that ribbons of approximately 400 nm × 800 nm were produced, and experimental characterization revealed that they did indeed offer higher volumetric surface area than previously reported electrospun cylindrical fiber electrodes. The electrodes were characterized for various physical and transport properties and compared to commercial Freudenberg H23 carbon paper in terms of performance in a vanadium redox flow battery. The ribbon-based electrode had better performance and higher power density than commercial Freudenberg H23 electrode in the activation region, though suffered early onset of mass transfer limitations. |
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AbstractList | •A simple and reliable technique was developed electrospinning fibers with a flat ribbon-like morphology.•A ribbon-based electrode layer shows increased surface to volume ratio.•The ribbon-based electrode showed 2x higher permeability and 40x higher volumetric specific surface higher than commercial electrodes.•The proposed materials were validated in an operating cell and shown to outperform commercial materials at low to moderate current density.
A method for the preparation of electrospun with fibers possessing a ribbon-like cross-sectional shape was developed. These materials could prove beneficial as flow-through electrodes, since ribbons provide a higher surface-to-volume ratio compared to fibers, thereby providing higher reactive surface area at a given porosity. Fabrication of these materials was accomplished by electrospinning a coaxial fiber with a polystyrene core and polyacrylonitrile shell, followed by leaching of the core material leading to the collapse of the shell into a flat ribbon. The surviving shell was then carbonized to make an electrically conductive and electrochemically reactive fibrous structure. Analysis by x-ray computed tomography showed that ribbons of approximately 400 nm × 800 nm were produced, and experimental characterization revealed that they did indeed offer higher volumetric surface area than previously reported electrospun cylindrical fiber electrodes. The electrodes were characterized for various physical and transport properties and compared to commercial Freudenberg H23 carbon paper in terms of performance in a vanadium redox flow battery. The ribbon-based electrode had better performance and higher power density than commercial Freudenberg H23 electrode in the activation region, though suffered early onset of mass transfer limitations. |
ArticleNumber | 102079 |
Author | Gostick, Jeff T. Kok, Matt D.R. Shearing, Paul R. Tenny, Kevin M. Chiang, Yet-Ming Brushett, Fikile R. Brett, Dan Jervis, Rhodri Roberts, Edward P.L. Forner-Cuenca, Antoni Yadav, Shashi |
Author_xml | – sequence: 1 givenname: Shashi surname: Yadav fullname: Yadav, Shashi organization: Porous Materials Engineering and Analysis Lab, Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L3G1, Canada – sequence: 2 givenname: Matt D.R. surname: Kok fullname: Kok, Matt D.R. organization: Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London WC1E 6BT, UK – sequence: 3 givenname: Antoni surname: Forner-Cuenca fullname: Forner-Cuenca, Antoni organization: Membrane Materials and Processes, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven, Netherlands – sequence: 4 givenname: Kevin M. surname: Tenny fullname: Tenny, Kevin M. organization: Joint Center for Energy Storage Research, US, Massachusetts Institute of Technology, Cambridge, MA 02139, USA – sequence: 5 givenname: Yet-Ming surname: Chiang fullname: Chiang, Yet-Ming organization: Joint Center for Energy Storage Research, US, Massachusetts Institute of Technology, Cambridge, MA 02139, USA – sequence: 6 givenname: Fikile R. surname: Brushett fullname: Brushett, Fikile R. organization: Joint Center for Energy Storage Research, US, Massachusetts Institute of Technology, Cambridge, MA 02139, USA – sequence: 7 givenname: Rhodri surname: Jervis fullname: Jervis, Rhodri organization: Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London WC1E 6BT, UK – sequence: 8 givenname: Paul R. surname: Shearing fullname: Shearing, Paul R. organization: Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London WC1E 6BT, UK – sequence: 9 givenname: Dan surname: Brett fullname: Brett, Dan organization: Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London WC1E 6BT, UK – sequence: 10 givenname: Edward P.L. surname: Roberts fullname: Roberts, Edward P.L. organization: Department of Chemical and Petroleum Engineering, University of Calgary, 2500 University Dr NW, Calgary, Alberta T2N 1N4, Canada – sequence: 11 givenname: Jeff T. surname: Gostick fullname: Gostick, Jeff T. email: jgostick@uwaterloo.ca organization: Porous Materials Engineering and Analysis Lab, Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L3G1, Canada |
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Keywords | Green energy Electrospun flat fibers Electrospun ribbon electrode Coaxial electrospinning Flow battery Energy storage |
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SubjectTerms | Coaxial electrospinning Electrospun flat fibers Electrospun ribbon electrode Energy storage Flow battery Green energy |
Title | Fabrication of high surface area ribbon electrodes for use in redox flow batteries via coaxial electrospinning |
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