Tailoring the Functional Properties of Ferroelectric Perovskite Thin Films: Mechanisms of Dielectric and Photoelectrochemical Enhancement

Various types of strain, as well as chemical pressure induced by dopants, can effectively tailor the performance of perovskite thin films, including their optical, electrical or photoelectrochemical properties. The control of these functional properties through such engineering techniques is key to...

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Published inCrystals (Basel) Vol. 15; no. 6; p. 496
Main Authors Ghitiu, Ioan-Mihail, Nemnes, George Alexandru, Scarisoreanu, Nicu Doinel
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.06.2025
Subjects
Alternative energy sources
Analysis
dielectric
Dielectric films
Dielectric loss
Dielectric properties
Dielectrics
doping
Electric fields
Electrical conductivity
Electrons
Energy storage
Engineering
Epitaxy
ferroelectric
Ferroelectric domains
Ferroelectric materials
Ferroelectricity
Ferroelectrics
Iron compounds
Optical properties
Perovskite
Perovskites
phase field
Photocatalysis
photoelectrochemical
Strain
strain engineering
Surface reactions
Thin films
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Abstract Various types of strain, as well as chemical pressure induced by dopants, can effectively tailor the performance of perovskite thin films, including their optical, electrical or photoelectrochemical properties. The control of these functional properties through such engineering techniques is key to fulfilling the application-specific requirements of ferroelectric devices in various fields. Numerous models and experimental data have been published on this subject, especially on ferrite-based ferroelectric materials. Within this paper, the mechanisms of tuning ferroelectric intrinsic properties, such as polarization and ferroelectric domain configurations, through epitaxial strain and doping, as well as the role of these techniques in influencing functional properties such as dielectric and photoelectrochemical ones, are presented. This review examines the significant improvements in dielectric properties and photoelectrochemical efficiency achieved by the strategical control of key functionalities including dielectric losses, domain structures, charge separation and surface reactions in strained/doped ferroelectric thin films, highlighting the advancements and research progress made in this field in recent years.
AbstractList Various types of strain, as well as chemical pressure induced by dopants, can effectively tailor the performance of perovskite thin films, including their optical, electrical or photoelectrochemical properties. The control of these functional properties through such engineering techniques is key to fulfilling the application-specific requirements of ferroelectric devices in various fields. Numerous models and experimental data have been published on this subject, especially on ferrite-based ferroelectric materials. Within this paper, the mechanisms of tuning ferroelectric intrinsic properties, such as polarization and ferroelectric domain configurations, through epitaxial strain and doping, as well as the role of these techniques in influencing functional properties such as dielectric and photoelectrochemical ones, are presented. This review examines the significant improvements in dielectric properties and photoelectrochemical efficiency achieved by the strategical control of key functionalities including dielectric losses, domain structures, charge separation and surface reactions in strained/doped ferroelectric thin films, highlighting the advancements and research progress made in this field in recent years.
Audience Academic
Author Ghitiu, Ioan-Mihail
Scarisoreanu, Nicu Doinel
Nemnes, George Alexandru
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  givenname: Nicu Doinel
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  surname: Scarisoreanu
  fullname: Scarisoreanu, Nicu Doinel
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Snippet Various types of strain, as well as chemical pressure induced by dopants, can effectively tailor the performance of perovskite thin films, including their...
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SubjectTerms Alternative energy sources
Analysis
dielectric
Dielectric films
Dielectric loss
Dielectric properties
Dielectrics
doping
Electric fields
Electrical conductivity
Electrons
Energy storage
Engineering
Epitaxy
ferroelectric
Ferroelectric domains
Ferroelectric materials
Ferroelectricity
Ferroelectrics
Iron compounds
Optical properties
Perovskite
Perovskites
phase field
Photocatalysis
photoelectrochemical
Strain
strain engineering
Surface reactions
Thin films
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Title Tailoring the Functional Properties of Ferroelectric Perovskite Thin Films: Mechanisms of Dielectric and Photoelectrochemical Enhancement
URI https://www.proquest.com/docview/3223892486
https://doaj.org/article/308a70ae7bc0410eba196a06ec41eb44
Volume 15
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