Conversion of 5-hydroxymethylfurfural to chemicals: A review of catalytic routes and product applications

Biomass is the sole renewable organic carbon resource in nature. Conversion of Biomass can produce a series of platform molecules. As an essential multi-purpose bioderived furanic platform compound, 5-hydroxymethylfurfural (HMF) can be effectively transformed into a variety of value-added derivative...

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Published inFuel processing technology Vol. 209; p. 106528
Main Authors Kong, Qing-Shan, Li, Xing-Long, Xu, Hua-Jian, Fu, Yao
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.12.2020
Elsevier Science Ltd
Subjects
5-Hydroxymethylfurfural
Biomass
Catalysts
catalytic activity
Catalytic conversion
Catalytic converters
Conversion
Economic conditions
Fossil fuels
Furan derivatives
Hydrogenation
Hydroxymethylfurfural
Material monomers
Organic carbon
Platform chemicals
value added
Catalytic conversion
Platform chemicals
5-Hydroxymethylfurfural
Hydrogenation
Material monomers
Furan derivatives
Online AccessGet full text
ISSN0378-3820
1873-7188
DOI10.1016/j.fuproc.2020.106528

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Abstract Biomass is the sole renewable organic carbon resource in nature. Conversion of Biomass can produce a series of platform molecules. As an essential multi-purpose bioderived furanic platform compound, 5-hydroxymethylfurfural (HMF) can be effectively transformed into a variety of value-added derivatives due to its rich chemistry and potential availability, which is an ideal renewable alternative to fossil fuels. This review highlights recent advances in the development of efficient catalytic systems for the conversion of HMF, especially heterogeneous catalysts. Heterogeneous catalysts have advantages in facile separation and recovery, tunable performance by adjusting catalyst structures. Simultaneously, we mainly focus on the application of downstream products in material monomers, pharmaceutical intermediates, and fuels. Furthermore, a few potential research trends are also proposed, in order to provide some useful ideas for the further exploration of the utilization and conversion of HMF in a much simple, efficient, and economical way. •Highly summarized recent advances in the conversion of HMF into monomers, fuels, and pharmaceutical intermediates•Discussion of research priorities and current challenges in the preparation of HMF downstream products•Prospects for potential research directions downstream of HMF
AbstractList Biomass is the sole renewable organic carbon resource in nature. Conversion of Biomass can produce a series of platform molecules. As an essential multi-purpose bioderived furanic platform compound, 5-hydroxymethylfurfural (HMF) can be effectively transformed into a variety of value-added derivatives due to its rich chemistry and potential availability, which is an ideal renewable alternative to fossil fuels. This review highlights recent advances in the development of efficient catalytic systems for the conversion of HMF, especially heterogeneous catalysts. Heterogeneous catalysts have advantages in facile separation and recovery, tunable performance by adjusting catalyst structures. Simultaneously, we mainly focus on the application of downstream products in material monomers, pharmaceutical intermediates, and fuels. Furthermore, a few potential research trends are also proposed, in order to provide some useful ideas for the further exploration of the utilization and conversion of HMF in a much simple, efficient, and economical way.
Biomass is the sole renewable organic carbon resource in nature. Conversion of Biomass can produce a series of platform molecules. As an essential multi-purpose bioderived furanic platform compound, 5-hydroxymethylfurfural (HMF) can be effectively transformed into a variety of value-added derivatives due to its rich chemistry and potential availability, which is an ideal renewable alternative to fossil fuels. This review highlights recent advances in the development of efficient catalytic systems for the conversion of HMF, especially heterogeneous catalysts. Heterogeneous catalysts have advantages in facile separation and recovery, tunable performance by adjusting catalyst structures. Simultaneously, we mainly focus on the application of downstream products in material monomers, pharmaceutical intermediates, and fuels. Furthermore, a few potential research trends are also proposed, in order to provide some useful ideas for the further exploration of the utilization and conversion of HMF in a much simple, efficient, and economical way. •Highly summarized recent advances in the conversion of HMF into monomers, fuels, and pharmaceutical intermediates•Discussion of research priorities and current challenges in the preparation of HMF downstream products•Prospects for potential research directions downstream of HMF
ArticleNumber 106528
Author Xu, Hua-Jian
Fu, Yao
Li, Xing-Long
Kong, Qing-Shan
Author_xml – sequence: 1
  givenname: Qing-Shan
  surname: Kong
  fullname: Kong, Qing-Shan
  organization: Hefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, Institute of Energy, Hefei Comprehensive National Science Center, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
– sequence: 2
  givenname: Xing-Long
  surname: Li
  fullname: Li, Xing-Long
  organization: Hefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, Institute of Energy, Hefei Comprehensive National Science Center, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
– sequence: 3
  givenname: Hua-Jian
  surname: Xu
  fullname: Xu, Hua-Jian
  email: hjxu@hfut.edu.cn
  organization: School of Food and Biological Engineering, Hefei University of Technology, Hefei 230009, China
– sequence: 4
  givenname: Yao
  surname: Fu
  fullname: Fu, Yao
  email: fuyao@ustc.edu.cn
  organization: Hefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, Institute of Energy, Hefei Comprehensive National Science Center, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
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EFKBS
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ID FETCH-LOGICAL-c367t-13d132a51c8cfa542d031d3772a187fd6b6f59b8638bd1718868cb18d6d07dc63
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ISSN 0378-3820
IngestDate Fri Sep 05 04:45:19 EDT 2025
Fri Jul 25 01:26:02 EDT 2025
Tue Jul 01 03:04:38 EDT 2025
Thu Apr 24 22:56:44 EDT 2025
Fri Feb 23 02:47:55 EST 2024
IsPeerReviewed true
IsScholarly true
Keywords Catalytic conversion
Platform chemicals
5-Hydroxymethylfurfural
Hydrogenation
Material monomers
Furan derivatives
Language English
LinkModel DirectLink
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crossref_primary_10_1016_j_fuproc_2020_106528
elsevier_sciencedirect_doi_10_1016_j_fuproc_2020_106528
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2020-12-00
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  year: 2020
  text: 2020-12-01
  day: 01
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PublicationTitle Fuel processing technology
PublicationYear 2020
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Elsevier Science Ltd
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Snippet Biomass is the sole renewable organic carbon resource in nature. Conversion of Biomass can produce a series of platform molecules. As an essential...
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SubjectTerms 5-Hydroxymethylfurfural
Biomass
Catalysts
catalytic activity
Catalytic conversion
Catalytic converters
Conversion
Economic conditions
Fossil fuels
Furan derivatives
Hydrogenation
Hydroxymethylfurfural
Material monomers
Organic carbon
Platform chemicals
value added
Title Conversion of 5-hydroxymethylfurfural to chemicals: A review of catalytic routes and product applications
URI https://dx.doi.org/10.1016/j.fuproc.2020.106528
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