Polymer Structure of Lignophenol I -Structure and Function of Fractionated Lignophenol

A polymer structure and function of lignophenol was examined by various structural analysis of lignophenols fractionated with preparative SEC. The base unit of lignophenol is 1,1-bis (aryl) propane-2-O-aryl ether unit in all the molecular weight areas by NMR analysis. But the amounts of combined cre...

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Published inPolymer journal Vol. 38; no. 6; pp. 585 - 591
Main Authors MIKAME, Keigo, FUNAOKA, Masamitsu
Format Journal Article
LanguageEnglish
Published Tokyo Society of Polymer Science 15.06.2006
Nature Publishing Group
Subjects
Applied sciences
Exact sciences and technology
Lignin and derivatives
Natural polymers
Physicochemistry of polymers
Cresol
Lignin
Chemical modification
Molecular structure
Liquid solid adsorption
Adsorption capacity
Serum albumin
Experimental study
ctionation / Molecular Weight / Polymer Structure / Phase-separation System / Lignophenol
Protein
Chemical coupling
Lignin derivatives
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Abstract A polymer structure and function of lignophenol was examined by various structural analysis of lignophenols fractionated with preparative SEC. The base unit of lignophenol is 1,1-bis (aryl) propane-2-O-aryl ether unit in all the molecular weight areas by NMR analysis. But the amounts of combined cresol and phenolic hydroxyl groups were increased with decreasing molecular weight of fractionated lignophenols. The protein-adsorbing capacities and thermoplastic property of fractionated lignophenols differed with the molecular weights.
AbstractList A polymer structure and function of lignophenol was examined by various structural analysis of lignophenols fractionated with preparative SEC. The base unit of lignophenol is 1,1-bis (aryl) propane-2-O-aryl ether unit in all the molecular weight areas by NMR analysis. But the amounts of combined cresol and phenolic hydroxyl groups were increased with decreasing molecular weight of fractionated lignophenols. The protein-adsorbing capacities and thermoplastic property of fractionated lignophenols differed with the molecular weights.
Author FUNAOKA, Masamitsu
MIKAME, Keigo
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Cites_doi 10.1080/00218468408074929
10.3891/acta.chem.scand.22-1187
10.1016/0003-2697(76)90527-3
10.1126/science.148.3670.595
10.1093/oxfordjournals.jbchem.a126896
10.1002/bit.260460607
10.1002/(SICI)1097-0126(199811)47:3<277::AID-PI10>3.0.CO;2-P
10.1515/hfsg.1964.18.1-2.3
10.1042/bj1390285
10.1515/hfsg.1996.50.3.245
10.2115/fiber.57.75
10.1002/masy.200351124
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Keywords Cresol
Lignin
Chemical modification
Molecular structure
Liquid solid adsorption
Adsorption capacity
Serum albumin
Experimental study
ctionation / Molecular Weight / Polymer Structure / Phase-separation System / Lignophenol
Protein
Chemical coupling
Lignin derivatives
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SubjectTerms Applied sciences
Exact sciences and technology
Lignin and derivatives
Natural polymers
Physicochemistry of polymers
Title Polymer Structure of Lignophenol I -Structure and Function of Fractionated Lignophenol
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