Novel bimetallic MOF derived hierarchical Co@C composites modified with carbon nanotubes and its excellent electromagnetic wave absorption properties

[Display omitted] In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin thickness and wide band. Under such a circumstance, it is of great significance to construct reasonable structure and composition for excellent e...

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Published inJournal of colloid and interface science Vol. 605; pp. 657 - 666
Main Authors Wen, Bo, Yang, Haibo, Lin, Ying, Qiu, Yun, cheng, Yan, Jin, lingxiang
Format Journal Article
LanguageEnglish
Published Elsevier Inc 01.01.2022
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Abstract [Display omitted] In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin thickness and wide band. Under such a circumstance, it is of great significance to construct reasonable structure and composition for excellent electromagnetic wave absorption. Therefore, the Co/C composites anchored with carbon nanotubes (Co@CNTs) have been successfully prepared by rationally regulating the growth of bimetallic MOF and subsequent pyrolysis process. It is revealed that the conduction loss and polarization loss caused by the carbon nanotubes with different lengths and densities and the porosity of the composites are together responsible for the attenuation of electromagnetic wave. As expected, the hierarchical Co@CNTs composites showed a strong reflection loss of −76.6 dB and a broad effective absorption bandwidth of 6.2 GHz through the improvement of impedance matching and electromagnetic wave absorption ability. Herein, this work presents a strategy for the development of composites as promising electromagnetic wave absorbent.
AbstractList In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin thickness and wide band. Under such a circumstance, it is of great significance to construct reasonable structure and composition for excellent electromagnetic wave absorption. Therefore, the Co/C composites anchored with carbon nanotubes (Co@CNTs) have been successfully prepared by rationally regulating the growth of bimetallic MOF and subsequent pyrolysis process. It is revealed that the conduction loss and polarization loss caused by the carbon nanotubes with different lengths and densities and the porosity of the composites are together responsible for the attenuation of electromagnetic wave. As expected, the hierarchical Co@CNTs composites showed a strong reflection loss of −76.6 dB and a broad effective absorption bandwidth of 6.2 GHz through the improvement of impedance matching and electromagnetic wave absorption ability. Herein, this work presents a strategy for the development of composites as promising electromagnetic wave absorbent.
[Display omitted] In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin thickness and wide band. Under such a circumstance, it is of great significance to construct reasonable structure and composition for excellent electromagnetic wave absorption. Therefore, the Co/C composites anchored with carbon nanotubes (Co@CNTs) have been successfully prepared by rationally regulating the growth of bimetallic MOF and subsequent pyrolysis process. It is revealed that the conduction loss and polarization loss caused by the carbon nanotubes with different lengths and densities and the porosity of the composites are together responsible for the attenuation of electromagnetic wave. As expected, the hierarchical Co@CNTs composites showed a strong reflection loss of −76.6 dB and a broad effective absorption bandwidth of 6.2 GHz through the improvement of impedance matching and electromagnetic wave absorption ability. Herein, this work presents a strategy for the development of composites as promising electromagnetic wave absorbent.
In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin thickness and wide band. Under such a circumstance, it is of great significance to construct reasonable structure and composition for excellent electromagnetic wave absorption. Therefore, the Co/C composites anchored with carbon nanotubes (Co@CNTs) have been successfully prepared by rationally regulating the growth of bimetallic MOF and subsequent pyrolysis process. It is revealed that the conduction loss and polarization loss caused by the carbon nanotubes with different lengths and densities and the porosity of the composites are together responsible for the attenuation of electromagnetic wave. As expected, the hierarchical Co@CNTs composites showed a strong reflection loss of -76.6 dB and a broad effective absorption bandwidth of 6.2 GHz through the improvement of impedance matching and electromagnetic wave absorption ability. Herein, this work presents a strategy for the development of composites as promising electromagnetic wave absorbent.In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin thickness and wide band. Under such a circumstance, it is of great significance to construct reasonable structure and composition for excellent electromagnetic wave absorption. Therefore, the Co/C composites anchored with carbon nanotubes (Co@CNTs) have been successfully prepared by rationally regulating the growth of bimetallic MOF and subsequent pyrolysis process. It is revealed that the conduction loss and polarization loss caused by the carbon nanotubes with different lengths and densities and the porosity of the composites are together responsible for the attenuation of electromagnetic wave. As expected, the hierarchical Co@CNTs composites showed a strong reflection loss of -76.6 dB and a broad effective absorption bandwidth of 6.2 GHz through the improvement of impedance matching and electromagnetic wave absorption ability. Herein, this work presents a strategy for the development of composites as promising electromagnetic wave absorbent.
Author Yang, Haibo
Qiu, Yun
Lin, Ying
Jin, lingxiang
Wen, Bo
cheng, Yan
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  fullname: Qiu, Yun
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  givenname: Yan
  surname: cheng
  fullname: cheng, Yan
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  givenname: lingxiang
  surname: Jin
  fullname: Jin, lingxiang
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Bimetallic metal organic frameworks
Electromagnetic wave absorption
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Snippet [Display omitted] In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin...
In the severe electromagnetic wave pollution situation, the absorbers must meet the requirements of lightweight, strong absorption, thin thickness and wide...
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SubjectTerms absorbents
absorption
Bimetallic metal organic frameworks
carbon nanotubes
electromagnetic radiation
Electromagnetic wave absorption
Hierarchical Co@CNTs composites
pollution
porosity
pyrolysis
Title Novel bimetallic MOF derived hierarchical Co@C composites modified with carbon nanotubes and its excellent electromagnetic wave absorption properties
URI https://dx.doi.org/10.1016/j.jcis.2021.07.118
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