Demonstration of the thermally induced high spin–low spin transition for a transparent spin crossover complex film [Fe(II)(H-trz) 3]-Nafion (trz = triazole)
The spin transition in [Fe II(H-trz) 3] -Nafion takes place around room temperature. The color changes from transparent to purple with decreasing temperature. Transparent spin crossover complex films [Fe(R-trz) 3]-Nafion (R = H, NH 2), have been prepared by using an ion-exchange resin (Nafion) as co...
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| Published in | Polyhedron Vol. 24; no. 16; pp. 2909 - 2912 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
17.11.2005
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| Subjects | |
| Online Access | Get full text |
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| Abstract | The spin transition in [Fe
II(H-trz)
3] -Nafion takes place around room temperature. The color changes from transparent to purple with decreasing temperature.
Transparent spin crossover complex films [Fe(R-trz)
3]-Nafion (R
=
H, NH
2), have been prepared by using an ion-exchange resin (Nafion) as counter anion. We observed the spin crossover phenomenon around room temperature and revealed the LIESST (light-induced excited spin state trapping) effect at 4.2
K, for these films. In ICMM2004, we have demonstrated the spin crossover behavior as thermochromism for the transparent [Fe(H-trz)
3]-Nafion film, where the spin transition takes place between the high spin (HS) state (colorless at 300
K) and the low spin (LS) state (purple color at 77
K). Here, we review the synthesis and the spin crossover phenomenon for the spin crossover complex film [Fe(H-trz)
3]-Nafion. |
|---|---|
| AbstractList | The spin transition in [Fe
II(H-trz)
3] -Nafion takes place around room temperature. The color changes from transparent to purple with decreasing temperature.
Transparent spin crossover complex films [Fe(R-trz)
3]-Nafion (R
=
H, NH
2), have been prepared by using an ion-exchange resin (Nafion) as counter anion. We observed the spin crossover phenomenon around room temperature and revealed the LIESST (light-induced excited spin state trapping) effect at 4.2
K, for these films. In ICMM2004, we have demonstrated the spin crossover behavior as thermochromism for the transparent [Fe(H-trz)
3]-Nafion film, where the spin transition takes place between the high spin (HS) state (colorless at 300
K) and the low spin (LS) state (purple color at 77
K). Here, we review the synthesis and the spin crossover phenomenon for the spin crossover complex film [Fe(H-trz)
3]-Nafion. |
| Author | Nakamura, Arao Moritomo, Yutaka Kojima, Norimichi Nakamoto, Akio XiaoJun, Liu |
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| Cites_doi | 10.1016/0009-2614(86)85073-4 10.1021/cm00058a013 10.1246/cl.2003.336 10.1016/0376-7388(96)00155-X 10.1016/S0379-6779(00)00832-8 10.1021/ja00074a062 10.1080/713738447 10.1021/ic00186a038 10.1126/science.279.5347.44 10.1143/JPSJ.70.2521 10.1016/0009-2614(84)80403-0 10.1063/1.459851 |
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| Keywords | Spin-crossover complex film LIESST Ion-exchange film Nafion EXAFS |
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| Snippet | The spin transition in [Fe
II(H-trz)
3] -Nafion takes place around room temperature. The color changes from transparent to purple with decreasing temperature.... |
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| SubjectTerms | EXAFS Ion-exchange film LIESST Nafion Spin-crossover complex film |
| Title | Demonstration of the thermally induced high spin–low spin transition for a transparent spin crossover complex film [Fe(II)(H-trz) 3]-Nafion (trz = triazole) |
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