Application of cyclophosphazene derivatives as flame retardants for ABS
Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol, catechol, or 2,3-dihydroxynaphthalene, respectively, and the fire retardant ability of each product in ABS resin was characterized by UL 94 and LO...
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| Published in | Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 16; no. 3; pp. 364 - 367 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
25.05.2010
한국공업화학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1226-086X 1876-794X |
| DOI | 10.1016/j.jiec.2009.08.001 |
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| Abstract | Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol, catechol, or 2,3-dihydroxynaphthalene, respectively, and the fire retardant ability of each product in ABS resin was characterized by UL 94 and LOI tests. The mechanical properties of ABS compounds containing one of these flame retardants were also examined. The derivative (HNCP) synthesized from 2,3-dihydroxynaphthalene showed the best flame retardance among these derivatives studied. Synergistic effects with novolac were observed in the cases using the derivative (PNCP) obtained from phenol, but little synergistic effects were observed in cases using HNCP. |
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| AbstractList | Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol, catechol, or 2,3-dihydroxynaphthalene, respectively, and the fire retardant ability of each product in ABS resin was characterized by UL 94 and LOI tests. The mechanical properties of ABS compounds containing one of these flame retardants were also examined. The derivative (HNCP) synthesized from 2,3-dihydroxynaphthalene showed the best flame retardance among these derivatives studied. Synergistic effects with novolac were observed in the cases using the derivative (PNCP) obtained from phenol, but little synergistic effects were observed in cases using HNCP. Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol, catechol, or 2,3-dihydroxynaphthalene,respectively, and the fire retardant ability of each product in ABS resin was characterized by UL 94 and LOI tests. The mechanical properties of ABS compounds containing one of these flame retardants were also examined. The derivative (HNCP) synthesized from 2,3-dihydroxynaphthalene showed the best flame retardance among these derivatives studied. Synergistic effects with novolac were observed in the cases using the derivative (PNCP) obtained from phenol, but little synergistic effects were observed in cases using HNCP. 2010 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved. KCI Citation Count: 40 |
| Author | Kim, Sun Hee Ham, Young Rok Park, Chul Soon Shin, Jae Sup Lee, Dae Hee Kim, Sang Beom Yoo, Young Mi Shin, Young Jae Kwon, Soo Han Kim, Jin Gon |
| Author_xml | – sequence: 1 givenname: Young Jae surname: Shin fullname: Shin, Young Jae organization: Department of Electrical and Computer Engineering, Texas A&M University, College Station, TX 77843, USA – sequence: 2 givenname: Young Rok surname: Ham fullname: Ham, Young Rok organization: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea – sequence: 3 givenname: Sun Hee surname: Kim fullname: Kim, Sun Hee organization: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea – sequence: 4 givenname: Dae Hee surname: Lee fullname: Lee, Dae Hee organization: Doobon Inc., Cheongwon, Chungbuk 363-893, Republic of Korea – sequence: 5 givenname: Sang Beom surname: Kim fullname: Kim, Sang Beom organization: Doobon Inc., Cheongwon, Chungbuk 363-893, Republic of Korea – sequence: 6 givenname: Chul Soon surname: Park fullname: Park, Chul Soon organization: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea – sequence: 7 givenname: Young Mi surname: Yoo fullname: Yoo, Young Mi organization: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea – sequence: 8 givenname: Jin Gon surname: Kim fullname: Kim, Jin Gon organization: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea – sequence: 9 givenname: Soo Han surname: Kwon fullname: Kwon, Soo Han organization: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea – sequence: 10 givenname: Jae Sup surname: Shin fullname: Shin, Jae Sup email: jsshin@chungbuk.ac.kr organization: Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763, Republic of Korea |
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| Snippet | Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol,... Cyclotriphosphazene derivatives were synthesized for use as a non-halogen flame retardant for ABS. Hexachlorocyclotriphosphazene was reacted with phenol,... |
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| SubjectTerms | ABS ABS resins Cyclotriphosphazene Derivatives Flame retardant Flame retardants Mechanical properties Novolacs Phenol Synergistic effect 화학공학 |
| Title | Application of cyclophosphazene derivatives as flame retardants for ABS |
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