Unexpected Formation of a Silicon-Centered Spirocyclic Oligosiloxane Bearing Eight Pendant Ferrocene Units

An intriguing but rare silicon-centered spirocyclic compound, spiro[5.5]octaferrocenylpentasiloxane (4) featuring silicon fused six-membered ferrocenyl-functionalized siloxane rings, has been obtained during the thermally induced transformation of triferrocenylsilane Fc3Si–H (1) into triferrocenylsi...

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Published inCrystals (Basel) Vol. 12; no. 8; p. 1122
Main Authors Bruña, Sonia, Cuadrado, Isabel, Perles, Josefina
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.08.2022
Subjects
Carbonyls
Catalysis
Chemical properties
Chemistry
Chromatography
Crystal structure
cyclosiloxanes
Diffraction
Dimethylformamide
ferrocene
inorganic macrocycles
Iron compounds
Jewelry
Mass spectrometry
Metallocenes
SCXRD
Silica
Silicates
Silicon
Silicon compounds
Siloxanes
Single crystals
Solvents
spirocyclic
X-rays
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Abstract An intriguing but rare silicon-centered spirocyclic compound, spiro[5.5]octaferrocenylpentasiloxane (4) featuring silicon fused six-membered ferrocenyl-functionalized siloxane rings, has been obtained during the thermally induced transformation of triferrocenylsilane Fc3Si–H (1) into triferrocenylsilanol Fc3Si–OH (2), when N,N-dimethylformamide (DMF) was used as a solvent in the presence of the metal carbonyl Mo(CO)6. The unexpected formation of the maximally ferrocenyl substituted silicon centered spirocyclic 4 involves the obtention, and subsequent condensation, of different ferrocenylsilanol intermediates. Spirocyclic silicate 4 has been characterized using a combination of MALDI-TOF mass spectrometry, elemental analysis, and single crystal X-ray diffraction analysis.
AbstractList An intriguing but rare silicon-centered spirocyclic compound, spiro[5.5]octaferrocenylpentasiloxane (4) featuring silicon fused six-membered ferrocenyl-functionalized siloxane rings, has been obtained during the thermally induced transformation of triferrocenylsilane Fc3Si–H (1) into triferrocenylsilanol Fc3Si–OH (2), when N,N-dimethylformamide (DMF) was used as a solvent in the presence of the metal carbonyl Mo(CO)6. The unexpected formation of the maximally ferrocenyl substituted silicon centered spirocyclic 4 involves the obtention, and subsequent condensation, of different ferrocenylsilanol intermediates. Spirocyclic silicate 4 has been characterized using a combination of MALDI-TOF mass spectrometry, elemental analysis, and single crystal X-ray diffraction analysis.
An intriguing but rare silicon-centered spirocyclic compound, spiro[5.5]octaferrocenylpentasiloxane (4) featuring silicon fused six-membered ferrocenyl-functionalized siloxane rings, has been obtained during the thermally induced transformation of triferrocenylsilane Fc[sub.3]Si-H (1) into triferrocenylsilanol Fc[sub.3]Si-OH (2), when N,N-dimethylformamide (DMF) was used as a solvent in the presence of the metal carbonyl Mo(CO)[sub.6]. The unexpected formation of the maximally ferrocenyl substituted silicon centered spirocyclic 4 involves the obtention, and subsequent condensation, of different ferrocenylsilanol intermediates. Spirocyclic silicate 4 has been characterized using a combination of MALDI-TOF mass spectrometry, elemental analysis, and single crystal X-ray diffraction analysis.
Audience Academic
Author Perles, Josefina
Cuadrado, Isabel
Bruña, Sonia
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  surname: Perles
  fullname: Perles, Josefina
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Cites_doi 10.1039/C5CC09569G
10.1021/acs.organomet.8b00537
10.1021/ja2101246
10.1016/j.jorganchem.2016.04.016
10.1002/ejic.202200055
10.1016/j.jorganchem.2013.07.052
10.1016/S0040-4020(01)00275-7
10.1039/C39930001577
10.1021/om300101w
10.1107/S0365110X48000077
10.1039/C7DT02286G
10.1021/om3001845
10.1038/353642a0
10.1021/cr900359c
10.1021/ma202521n
10.1021/om034176w
10.1021/om9809567
10.1002/anie.202014822
10.1007/BF00745351
10.1039/C5CS00022J
10.1021/om400453m
10.1007/978-94-011-3939-7
10.1039/D0QI00109K
10.1016/S0277-5387(99)00357-5
10.1016/j.inoche.2008.10.025
10.1038/nchem.2553
10.1002/anie.200903021
10.1021/acs.organomet.6b00559
10.1107/S0108767390000277
10.1002/chem.201805604
10.1039/C3CC48766K
10.1016/j.ccr.2015.07.005
10.1002/anie.199526791
10.1021/ja01001a082
10.1021/ma9018608
10.1021/om400123y
10.1002/ejic.202100275
10.1021/om1002733
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References Jitchum (ref_40) 2001; 57
Shklover (ref_44) 1978; 19
Nieto (ref_21) 2010; 29
Scottwella (ref_15) 2016; 52
Hildebrandt (ref_18) 2013; 32
MacLachlan (ref_36) 2000; 19
(ref_13) 2009; 12
Pop (ref_10) 2016; 314
Sollott (ref_35) 1967; 89
Inkpen (ref_16) 2016; 8
ref_34
ref_32
ref_31
Sheppard (ref_14) 2022; 2022
ref_30
Perles (ref_24) 2014; 751
Laine (ref_41) 1991; 353
Miles (ref_27) 2009; 42
Semler (ref_9) 2013; 32
Nieto (ref_23) 2012; 45
MacLachlan (ref_39) 1999; 18
Kamitani (ref_37) 2012; 31
Sharma (ref_28) 2012; 134
Gu (ref_19) 2016; 813
Perles (ref_25) 2017; 46
Dankert (ref_11) 2020; 7
Sarkar (ref_43) 2019; 25
Rossi (ref_20) 2018; 37
Nieto (ref_22) 2012; 31
Corey (ref_38) 2011; 111
ref_1
ref_3
Sharma (ref_29) 2009; 48
Roth (ref_42) 1948; 1
ref_2
Sheldrick (ref_33) 1990; 46
Churchill (ref_6) 1993; 20
Eaborn (ref_7) 1996; 34
Kung (ref_4) 2014; 50
Haiduc (ref_8) 2004; 23
Dankert (ref_12) 2021; 60
Dankert (ref_5) 2021; 2021
Xu (ref_17) 2015; 44
Perles (ref_26) 2016; 35
References_xml – volume: 52
  start-page: 2451
  year: 2016
  ident: ref_15
  article-title: Ferrocene-Containing non-Interlocked Molecular Machines
  publication-title: Chem. Commun.
  doi: 10.1039/C5CC09569G
  contributor:
    fullname: Scottwella
– ident: ref_30
– volume: 37
  start-page: 4242
  year: 2018
  ident: ref_20
  article-title: Testing the Conjugative Properties of Benzodithiophene and Benzotrithiophene in Charge Transfer Multi(ferrocenyl) Systems
  publication-title: Organometallics
  doi: 10.1021/acs.organomet.8b00537
  contributor:
    fullname: Rossi
– volume: 134
  start-page: 848
  year: 2012
  ident: ref_28
  article-title: Metal-Catalyzed Reduction of HCONR′2, R′ = Me (DMF), Et (DEF), by Silanes to Produce R′2NMe and Disiloxanes: A Mechanism Unraveled
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja2101246
  contributor:
    fullname: Sharma
– ident: ref_32
– ident: ref_3
– ident: ref_34
– volume: 813
  start-page: 95
  year: 2016
  ident: ref_19
  article-title: On Metallocene-Containing Macromolecules and their Applications
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2016.04.016
  contributor:
    fullname: Gu
– volume: 2022
  start-page: e202200055
  year: 2022
  ident: ref_14
  article-title: Development and Characterisation of Highly Conjugated Functionalised Ferrocenylene Macrocycles
  publication-title: Eur. J. Inorg. Chem.
  doi: 10.1002/ejic.202200055
  contributor:
    fullname: Sheppard
– volume: 751
  start-page: 769
  year: 2014
  ident: ref_24
  article-title: Triferrocenylsilane and Unexpected Formation of Diferrocenyl(3,3-dimethylbutyl)silane via Cleavage and Trapping of a Tetrahydrofuran Fragment. Redox Chemistry and Synthesis of (Fc)3Si–Co(CO)4 through Oxidative Addition of the Si–H Bond
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2013.07.052
  contributor:
    fullname: Perles
– volume: 57
  start-page: 3997
  year: 2001
  ident: ref_40
  article-title: Synthesis of Spirosilicates Directly from Silica and Ethylene Glycol Derivatives
  publication-title: Tetrahedron
  doi: 10.1016/S0040-4020(01)00275-7
  contributor:
    fullname: Jitchum
– volume: 20
  start-page: 1577
  year: 1993
  ident: ref_6
  article-title: Silicone Grease as a Precursor to a Pseudo Crown Ether Ligand: Crystal Structure of [K+]3[K(Me2SiO)7+][InH(CH2CMe3)3−]4
  publication-title: J. Chem. Soc. Chem. Commun.
  doi: 10.1039/C39930001577
  contributor:
    fullname: Churchill
– volume: 31
  start-page: 3248
  year: 2012
  ident: ref_22
  article-title: Cubic Octasilsegsquioxanes, Cyclotetrasiloxanes, and Disiloxanes Maximally Functionalized with Silicon-Bridged Interacting Triferrocenyl Units
  publication-title: Organometallics
  doi: 10.1021/om300101w
  contributor:
    fullname: Nieto
– volume: 1
  start-page: 34
  year: 1948
  ident: ref_42
  article-title: The Crystal Structure of Octamethylspiro [5.5] pentasiloxane: Rotation about the Ionic Silicon–Oxygen Bond
  publication-title: Acta Cryst.
  doi: 10.1107/S0365110X48000077
  contributor:
    fullname: Roth
– volume: 46
  start-page: 11584
  year: 2017
  ident: ref_25
  article-title: Formation of Unexpected Silicon- and Disiloxane-bridged Multiferrocenyl Derivatives bearing Si–O–CH=CH2 and Si–(CH2)2C(CH3)3 Substituents via Cleavage of Tetrahydrofuran and Trapping of its Ring Fragments
  publication-title: Dalton Trans.
  doi: 10.1039/C7DT02286G
  contributor:
    fullname: Perles
– volume: 31
  start-page: 2957
  year: 2012
  ident: ref_37
  article-title: Catalytic Synthesis of Cyclic and Linear Germoxanes Mediated by an Iron Complex
  publication-title: Organometallics
  doi: 10.1021/om3001845
  contributor:
    fullname: Kamitani
– volume: 353
  start-page: 642
  year: 1991
  ident: ref_41
  article-title: Synthesis of Pentacoordinate Silicon Complexes from SiO2
  publication-title: Nature
  doi: 10.1038/353642a0
  contributor:
    fullname: Laine
– volume: 111
  start-page: 863
  year: 2011
  ident: ref_38
  article-title: Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products
  publication-title: Chem. Rev.
  doi: 10.1021/cr900359c
  contributor:
    fullname: Corey
– volume: 45
  start-page: 781
  year: 2012
  ident: ref_23
  article-title: Redox-Active Macrocyclic and Linear Oligo-Carbosiloxanes Prepared via Hydrosilylation from 1,3-Divinyl-1,3-Dimethyl-1,3-Diferrocenyldisiloxane
  publication-title: Macromolecules
  doi: 10.1021/ma202521n
  contributor:
    fullname: Nieto
– volume: 23
  start-page: 3
  year: 2004
  ident: ref_8
  article-title: Silicone Grease: A Serendipitous Reagent for the Synthesis of Exotic Molecular and Supramolecular Compounds
  publication-title: Organometallics
  doi: 10.1021/om034176w
  contributor:
    fullname: Haiduc
– volume: 18
  start-page: 1337
  year: 1999
  ident: ref_39
  article-title: Ferrocenylsiloxane Chemistry: Synthesis and Characterization of Hexaferrocenylcyclotrisiloxane and Tetraferrocenyldisiloxanediol
  publication-title: Organometallics
  doi: 10.1021/om9809567
  contributor:
    fullname: MacLachlan
– volume: 60
  start-page: 10393
  year: 2021
  ident: ref_12
  article-title: Construction of Inorganic Crown Ethers by s-Block-Metal-Templated Si–O Bond Activation
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.202014822
  contributor:
    fullname: Dankert
– volume: 19
  start-page: 98
  year: 1978
  ident: ref_44
  article-title: The Crystal Structure of Cyclic Siloxanes and Silazanes. VIII. Trans, trans-d,l-2,4,8,10-tetramethyl-2,4,8,10-tetraphenylspiro [5.5] pentasiloxane
  publication-title: J. Struct. Chem.
  doi: 10.1007/BF00745351
  contributor:
    fullname: Shklover
– volume: 44
  start-page: 2148
  year: 2015
  ident: ref_17
  article-title: Construction of Multiferrocenyl Metallacycles and Metallacages via Coordination-Driven Self-Assembly
  publication-title: Chem. Soc. Rev.
  doi: 10.1039/C5CS00022J
  contributor:
    fullname: Xu
– ident: ref_31
– volume: 32
  start-page: 5640
  year: 2013
  ident: ref_18
  article-title: (Multi)ferrocenyl Five-Membered Heterocycles: Excellent Connecting Units for Electron Transfer Studies
  publication-title: Organometallics
  doi: 10.1021/om400453m
  contributor:
    fullname: Hildebrandt
– ident: ref_2
– ident: ref_1
  doi: 10.1007/978-94-011-3939-7
– volume: 7
  start-page: 2138
  year: 2020
  ident: ref_11
  article-title: On the Molecular Architectures of Siloxane Coordination Compounds: (re-)Investigating the Coordination of the Cyclodimethylsiloxanes Dn (n = 5–8) towards Alkali Metal Ions
  publication-title: Inorg. Chem. Front.
  doi: 10.1039/D0QI00109K
  contributor:
    fullname: Dankert
– volume: 19
  start-page: 275
  year: 2000
  ident: ref_36
  article-title: Synthesis, Characterization, and Ring-opening Polymerization of a Novel [1]Silaferrocenophane with two Ferrocenyl Substituents at Silicon
  publication-title: Polyhedron
  doi: 10.1016/S0277-5387(99)00357-5
  contributor:
    fullname: MacLachlan
– volume: 12
  start-page: 35
  year: 2009
  ident: ref_13
  article-title: Surprising Formation of a Silicon Containing Macrocycle
  publication-title: Inorg. Chem. Commun.
  doi: 10.1016/j.inoche.2008.10.025
– volume: 8
  start-page: 825
  year: 2016
  ident: ref_16
  article-title: Oligomeric Ferrocene Rings
  publication-title: Nature Chem.
  doi: 10.1038/nchem.2553
  contributor:
    fullname: Inkpen
– volume: 48
  start-page: 7052
  year: 2009
  ident: ref_29
  article-title: The Photochemical Irradiation of R3SiH in the Presence of [(η5-C5H5)Fe(CO)2CH3] in DMF Leads to Disiloxanes not Disilanes
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/anie.200903021
  contributor:
    fullname: Sharma
– volume: 35
  start-page: 3507
  year: 2016
  ident: ref_26
  article-title: Multi-Ferrocene-Containing Silanols as Redox-Active Anion Receptors
  publication-title: Organometallics
  doi: 10.1021/acs.organomet.6b00559
  contributor:
    fullname: Perles
– volume: 46
  start-page: 467
  year: 1990
  ident: ref_33
  article-title: Phase Annealing in SHELX-90: Direct Methods for Larger Structures
  publication-title: Acta Crystallogr. A
  doi: 10.1107/S0108767390000277
  contributor:
    fullname: Sheldrick
– volume: 25
  start-page: 1198
  year: 2019
  ident: ref_43
  article-title: The Quest for Stable Silaaldehydes: Synthesis and Reactivity of a Masked Silacarbonyl
  publication-title: Chem. Eur. J.
  doi: 10.1002/chem.201805604
  contributor:
    fullname: Sarkar
– volume: 50
  start-page: 3262
  year: 2014
  ident: ref_4
  article-title: Organosilicon Platforms: Bridging Homogeneous, Heterogeneous, and Bioinspired Catalysis
  publication-title: Chem. Commun.
  doi: 10.1039/C3CC48766K
  contributor:
    fullname: Kung
– volume: 314
  start-page: 64
  year: 2016
  ident: ref_10
  article-title: Serendipitous Reactions Involving a Silicone Grease
  publication-title: Coord. Chem. Rev.
  doi: 10.1016/j.ccr.2015.07.005
  contributor:
    fullname: Pop
– volume: 34
  start-page: 2679
  year: 1996
  ident: ref_7
  article-title: Two Diorganopotassates: Crystal Structure of [K(C6H6)][K{C(SiMe3)2(SiMe2Ph)}2]
  publication-title: Angew. Chem. Int. Ed. Engl.
  doi: 10.1002/anie.199526791
  contributor:
    fullname: Eaborn
– volume: 89
  start-page: 6783
  year: 1967
  ident: ref_35
  article-title: Germylation of Ferrocene under Friedel-Crafts Conditions. Question of the Existence of Germonium Ions
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja01001a082
  contributor:
    fullname: Sollott
– volume: 42
  start-page: 9199
  year: 2009
  ident: ref_27
  article-title: Polyferrocenyldisiloxane from the Platinum-Catalyzed Reactions of Tertiary Bis(dimethylsilyl)ferrocene in a Polar Aprotic Solvent
  publication-title: Macromolecules
  doi: 10.1021/ma9018608
  contributor:
    fullname: Miles
– volume: 32
  start-page: 2398
  year: 2013
  ident: ref_9
  article-title: Unusual Reactivity of a C,N-Chelated Stannylene with Siloxanes and Silanols
  publication-title: Organometallics
  doi: 10.1021/om400123y
  contributor:
    fullname: Semler
– volume: 2021
  start-page: 2907
  year: 2021
  ident: ref_5
  article-title: Siloxane Coordination Revisited: Si−O Bond Character, Reactivity and Magnificent Molecular Shapes
  publication-title: Eur. J. Inorg. Chem.
  doi: 10.1002/ejic.202100275
  contributor:
    fullname: Dankert
– volume: 29
  start-page: 2796
  year: 2010
  ident: ref_21
  article-title: Vinyl-Functionalized Silanes and Disiloxanes with Electronically Communicated Ferrocenes
  publication-title: Organometallics
  doi: 10.1021/om1002733
  contributor:
    fullname: Nieto
SSID ssj0000760771
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Snippet An intriguing but rare silicon-centered spirocyclic compound, spiro[5.5]octaferrocenylpentasiloxane (4) featuring silicon fused six-membered...
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SubjectTerms Carbonyls
Catalysis
Chemical properties
Chemistry
Chromatography
Crystal structure
cyclosiloxanes
Diffraction
Dimethylformamide
ferrocene
inorganic macrocycles
Iron compounds
Jewelry
Mass spectrometry
Metallocenes
SCXRD
Silica
Silicates
Silicon
Silicon compounds
Siloxanes
Single crystals
Solvents
spirocyclic
X-rays
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Title Unexpected Formation of a Silicon-Centered Spirocyclic Oligosiloxane Bearing Eight Pendant Ferrocene Units
URI https://www.proquest.com/docview/2706175178
https://doaj.org/article/ce27216889404a5691fc1398e5714c13
Volume 12
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