High-performance arabinoglucuronoxylan-based biosurfactants for oily sludge separation

Arabinoglucuronoxylan (AGX), an important carbohydrate polymer in lignocellulosic biomass, contains many functional groups. It has excellent amphiphilic modification properties and has potential application in the separation of oily sludge. In this study, a simple strategy for producing high-perform...

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Published inCarbohydrate polymers Vol. 303; p. 120461
Main Authors Huang, Haibo, Li, Zhihan, Ma, Yun, Yao, Mingzhu, Yao, Shuangquan, Zhang, Zhiwei, Qin, Chengrong
Format Journal Article
LanguageEnglish
Published England Elsevier Ltd 01.03.2023
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Abstract Arabinoglucuronoxylan (AGX), an important carbohydrate polymer in lignocellulosic biomass, contains many functional groups. It has excellent amphiphilic modification properties and has potential application in the separation of oily sludge. In this study, a simple strategy for producing high-performance AGX-based biosurfactants was studied and the raw AGX was extracted from bamboo by hydrothermal treatment. AGX-based biosurfactants with amphiphilic structure were produced by AGX and dodecanal succinic anhydride (DDSA) using rapid homogeneous esterification reactions in deep eutectic solvents (DES). This resulted in a significant reduction in the surface tension of the water from 72.32 to 29.76 mN·m−1. These parameters are similar to those achieved using sodium dodecyl sulfate (SDS), a widely employed synthetic surfactant. Other physicochemical properties, including foamability, emulsification activity, stability, solubilization, and detergency were significantly improved compared to the unmodified AGX, demonstrate that AGX-based biosurfactants are promising detergents for oily sludge remediation and oil recovery. The results provide a new pathway for high value utilization of arabinoglucuronoxylan. [Display omitted]
AbstractList Arabinoglucuronoxylan (AGX), an important carbohydrate polymer in lignocellulosic biomass, contains many functional groups. It has excellent amphiphilic modification properties and has potential application in the separation of oily sludge. In this study, a simple strategy for producing high-performance AGX-based biosurfactants was studied and the raw AGX was extracted from bamboo by hydrothermal treatment. AGX-based biosurfactants with amphiphilic structure were produced by AGX and dodecanal succinic anhydride (DDSA) using rapid homogeneous esterification reactions in deep eutectic solvents (DES). This resulted in a significant reduction in the surface tension of the water from 72.32 to 29.76 mN·m−1. These parameters are similar to those achieved using sodium dodecyl sulfate (SDS), a widely employed synthetic surfactant. Other physicochemical properties, including foamability, emulsification activity, stability, solubilization, and detergency were significantly improved compared to the unmodified AGX, demonstrate that AGX-based biosurfactants are promising detergents for oily sludge remediation and oil recovery. The results provide a new pathway for high value utilization of arabinoglucuronoxylan. [Display omitted]
Arabinoglucuronoxylan (AGX), an important carbohydrate polymer in lignocellulosic biomass, contains many functional groups. It has excellent amphiphilic modification properties and has potential application in the separation of oily sludge. In this study, a simple strategy for producing high-performance AGX-based biosurfactants was studied and the raw AGX was extracted from bamboo by hydrothermal treatment. AGX-based biosurfactants with amphiphilic structure were produced by AGX and dodecanal succinic anhydride (DDSA) using rapid homogeneous esterification reactions in deep eutectic solvents (DES). This resulted in a significant reduction in the surface tension of the water from 72.32 to 29.76 mN·m . These parameters are similar to those achieved using sodium dodecyl sulfate (SDS), a widely employed synthetic surfactant. Other physicochemical properties, including foamability, emulsification activity, stability, solubilization, and detergency were significantly improved compared to the unmodified AGX, demonstrate that AGX-based biosurfactants are promising detergents for oily sludge remediation and oil recovery. The results provide a new pathway for high value utilization of arabinoglucuronoxylan.
ArticleNumber 120461
Author Yao, Mingzhu
Li, Zhihan
Zhang, Zhiwei
Ma, Yun
Huang, Haibo
Yao, Shuangquan
Qin, Chengrong
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Keywords Amphipathic arabinoglucuronoxylan derivatives
Oily sludge
Oil recovery
Bio-surfactants
Language English
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Snippet Arabinoglucuronoxylan (AGX), an important carbohydrate polymer in lignocellulosic biomass, contains many functional groups. It has excellent amphiphilic...
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SubjectTerms Amphipathic arabinoglucuronoxylan derivatives
Bio-surfactants
Oil recovery
Oily sludge
Sewage
Sodium Dodecyl Sulfate
Surface-Active Agents - chemistry
Title High-performance arabinoglucuronoxylan-based biosurfactants for oily sludge separation
URI https://dx.doi.org/10.1016/j.carbpol.2022.120461
https://www.ncbi.nlm.nih.gov/pubmed/36657858
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