Multifunctional CNTs-PAA/MIL101(Fe)@Pt Composite Membrane for High-throughput Oily Wastewater Remediation
•A CNTs-based membrane has been presented for purifying oily waste water.•Its flux has exceeded most of the multifunctional separation membranes previously reported.•It has shown excellent physical and chemical stability. A surge of effort has been devoted to establishing super-wetting membranes wit...
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Published in | Journal of hazardous materials Vol. 403; p. 123547 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
05.02.2021
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Abstract | •A CNTs-based membrane has been presented for purifying oily waste water.•Its flux has exceeded most of the multifunctional separation membranes previously reported.•It has shown excellent physical and chemical stability.
A surge of effort has been devoted to establishing super-wetting membranes with versatility for oily waste water purification. However, persistent challenge remains the lower separation flux. Moreover, the majorities of catalysts are only adsorbed on the surface and easily fall off after multiple cyclic separations. In this work, an effective strategy has been taken to construct a composite membrane consisting of polyacrylic acid functionalized carbon nanotubes (CNTs-PAA) and MIL101(Fe)@platinum nanoparticles (MIL101(Fe)@Pt NPs). The obtained CNTs-PAA/MIL101(Fe)@Pt composite membrane can achieve degradation of dye molecules and at the same time effective separation of oil-in-water emulsions. The separation throughput of this composite membrane can reach up to 11000 L m−2 h-1 bar-1, which has exceeded most of the previous reported multifunctional separation membranes. Furthermore, this composite membrane has presented stable mechanical property and excellent anti-corrosion ability. This work gives comprehensive consideration to excellent separation performance, versatility and stability, which could have potential applications in practical oily wastewater treatment. |
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AbstractList | •A CNTs-based membrane has been presented for purifying oily waste water.•Its flux has exceeded most of the multifunctional separation membranes previously reported.•It has shown excellent physical and chemical stability.
A surge of effort has been devoted to establishing super-wetting membranes with versatility for oily waste water purification. However, persistent challenge remains the lower separation flux. Moreover, the majorities of catalysts are only adsorbed on the surface and easily fall off after multiple cyclic separations. In this work, an effective strategy has been taken to construct a composite membrane consisting of polyacrylic acid functionalized carbon nanotubes (CNTs-PAA) and MIL101(Fe)@platinum nanoparticles (MIL101(Fe)@Pt NPs). The obtained CNTs-PAA/MIL101(Fe)@Pt composite membrane can achieve degradation of dye molecules and at the same time effective separation of oil-in-water emulsions. The separation throughput of this composite membrane can reach up to 11000 L m−2 h-1 bar-1, which has exceeded most of the previous reported multifunctional separation membranes. Furthermore, this composite membrane has presented stable mechanical property and excellent anti-corrosion ability. This work gives comprehensive consideration to excellent separation performance, versatility and stability, which could have potential applications in practical oily wastewater treatment. A surge of effort has been devoted to establishing super-wetting membranes with versatility for oily waste water purification. However, persistent challenge remains the lower separation flux. Moreover, the majorities of catalysts are only adsorbed on the surface and easily fall off after multiple cyclic separations. In this work, an effective strategy has been taken to construct a composite membrane consisting of polyacrylic acid functionalized carbon nanotubes (CNTs-PAA) and MIL101(Fe)@platinum nanoparticles (MIL101(Fe)@Pt NPs). The obtained CNTs-PAA/MIL101(Fe)@Pt composite membrane can achieve degradation of dye molecules and at the same time effective separation of oil-in-water emulsions. The separation throughput of this composite membrane can reach up to 11000 L m h bar , which has exceeded most of the previous reported multifunctional separation membranes. Furthermore, this composite membrane has presented stable mechanical property and excellent anti-corrosion ability. This work gives comprehensive consideration to excellent separation performance, versatility and stability, which could have potential applications in practical oily wastewater treatment. |
ArticleNumber | 123547 |
Author | Liu, Chaohui Liu, Qingquan Chen, Tao Gu, Jincui Yan, Luke Wang, Wenqin Xia, Junyuan |
Author_xml | – sequence: 1 givenname: Chaohui surname: Liu fullname: Liu, Chaohui organization: Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang’ an University, Xi'an, 710064, China – sequence: 2 givenname: Junyuan surname: Xia fullname: Xia, Junyuan organization: Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Science, Ningbo 315201, China – sequence: 3 givenname: Jincui surname: Gu fullname: Gu, Jincui email: gujincui@nimte.ac.cn organization: Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Science, Ningbo 315201, China – sequence: 4 givenname: Wenqin surname: Wang fullname: Wang, Wenqin organization: Faculty of Materials Science and Chemical Engineering, Ningbo University, 818 Fenghua Road, Ningbo 315211, China – sequence: 5 givenname: Qingquan surname: Liu fullname: Liu, Qingquan organization: Institute of Materials Science and Engineering, Hunan University of Science and Technology, Xiangtan 411201, China – sequence: 6 givenname: Luke surname: Yan fullname: Yan, Luke email: yanlk_79@hotmail.com organization: Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang’ an University, Xi'an, 710064, China – sequence: 7 givenname: Tao surname: Chen fullname: Chen, Tao email: tao.chen@nimte.ac.cn organization: Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang’ an University, Xi'an, 710064, China |
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Keywords | CNTs-PAA membrane Synergistic separation Stability MIL101(Fe)@Pt NPs Versatility |
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Snippet | •A CNTs-based membrane has been presented for purifying oily waste water.•Its flux has exceeded most of the multifunctional separation membranes previously... A surge of effort has been devoted to establishing super-wetting membranes with versatility for oily waste water purification. However, persistent challenge... |
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SubjectTerms | CNTs-PAA membrane MIL101(Fe)@Pt NPs Stability Synergistic separation Versatility |
Title | Multifunctional CNTs-PAA/MIL101(Fe)@Pt Composite Membrane for High-throughput Oily Wastewater Remediation |
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