Allylpalladium(II) Complexes with Aminophosphane Ligands: Solution Behaviour and X-ray Structure of cis-[Pd(η3-CH2CHCHPh){Ph2PCH2CHPhNH(2,6-C6H3iPr2)}][PF6]

• Published in: European journal of inorganic chemistry Vol. 2004; no. 5; pp. 1081 - 1091
• Main Authors: Camus, Jean-Michel, Andrieu, Jacques, Richard, Philippe, Poli, Rinaldo
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.03.2004; WILEY‐VCH Verlag; Wiley
• Subjects: Allyl ligands; Chemistry; Chemistry, Inorganic & Nuclear; N,P ligands; P ligands; Palladium; Physical Sciences; Science & Technology; syn-anti exchange; COORDINATION CHEMISTRY; N,P ligands; PALLADIUM COMPLEXES; ALKYLATION; CRYSTAL-STRUCTURES; (PHOSPHANYLOXAZOLINE)PALLADIUM COMPLEXES; allyl ligands; NMR INVESTIGATIONS; BIDENTATE LIGANDS; CATALYZED ALLYLIC SUBSTITUTION; palladium; syn-anti exchange; CONTAINING OXAZOLINE LIGANDS; BITE ANGLE

A new β‐aminophosphane L2 [Ph2PCH2CH(Ph)NH(2,6‐C6H3iPr2)], bearing an asymmetric carbon atom and a vicinal prochiral nitrogen centre and (η3‐allyl)palladium complexes of general formula [Pd(η3‐C3H4R){η2‐Ph2PCH2CH(Ph)NHAr}][PF6] (1−6) (R = H, Me or Ph and Ar = Ph or 2,6‐C6H3iPr2) have been synthesise...