Meta-bauxite deposit in the Tavşanlı Zone, NW Turkey: A new locality for gem-quality diaspore formation

• Published in: Journal of Asian Earth Sciences: X Vol. 8; p. 100114
• Main Author: Gündoğan, İbrahim
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.12.2022; Elsevier
• Subjects: Gem-quality diaspore; Meta-bauxite; Tavşanlı zone; Tavşanlı zone; Gem-quality diaspore; Meta-bauxite
• DOI: 10.1016/j.jaesx.2022.100114
• ISSN: 2590-0560

[Display omitted] •The Tavşanlı Zone marbles in western Anatolia contain karstic-type meta-bauxites.•The bauxite contains mainly diaspore, chloritoid, muscovite, paragonite and hercynite.•The bauxites were largely derived from redeposited argillic sediments.•Blueschist metamorphic conditions are estimated as 20–27 kbar and 330–470 °C. The tectonic units of Sakarya Zone (Pontides) and Tavşanlı Zone (Anatolides) are exposed in the Mihalıççık area of central Anatolia. A Cretaceous accretionary complex that forms the İzmir-Ankara-Erzincan suture zone separates the units. Within this region, the Tavşanlı Zone is made up of a coherent series and tectonically overlying late Cretaceous mélange, which has undergone blueschist facies metamorphism. Coherent series consist of strongly retrogressed schists and conformably overlying platform-type thick marbles, known as the İnönü marbles. The İnönü marbles contain meta-bauxite lenses in the lower levels, which can be classified as karstic bauxites deposited in the karst holes within the original limestone. Considering the general stratigraphy of the Tavşanlı Zone, a middle Jurassic age can be envisaged for the bauxite formation. Geochemical data suggest that the bauxites were largely derived from redeposited argillic sediments, with minor and variable inputs from the weathering of intermediate to acidic rock. The mineral assemblage of the meta-bauxite consists of diaspore, chloritoid, muscovite, paragonite, Al-spinel (hercynite), magnetite, hematite and ilmenite. In addition, apatite, rutile, monazite, xenotime and zircon occur as accessory minerals. Limonite, goethite, akaganeite and kaolinite also formed during the latest stage of alteration. P-T conditions for the meta-bauxites are estimated as 20–27 kbar and 330–470 °C that are indicative of formation under high-P / low-T blueschist facies conditions. The meta-bauxites are cut by veins of diaspore, muscovite-paragonite, goethite, calcite and ankerite, and include gem-quality diaspore crystals up to 6 cm long. Textural evidence indicates that the diaspore formation is related to the extraction of aluminium from the meta-bauxite body and migration of Al-rich fluids into the shear zones during the last stage of the high-P metamorphism. During exhumation of the Tavşanlı Zone, these veins were brecciated by brittle deformation and the fractured minerals were cemented by granoblastic calcite and ankerite during the latest stage of the vein formation.