Modern Approaches in the Synthesis of Noble Metal Porphyrins for Their Practical Application (Review)

Being inert in the elemental state and as compounds, noble metals—ruthenium, osmium, rhodium, iridium, palladium, platinum, silver, and gold—and rhenium, whose compounds have similar properties, form macrocyclic complexes with specific reactivity. This review highlights the achievements of the last...

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Bibliographic Details
Published inRussian journal of inorganic chemistry Vol. 64; no. 14; pp. 1775 - 1802
Main Author Tyulyaeva, E. Yu
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.12.2019
Springer Nature B.V
Subjects
Catalysis
Chemical synthesis
Chemistry
Chemistry and Materials Science
Coordination Compounds
Inorganic Chemistry
Iridium
Magnetic properties
Noble metals
Optical properties
Organic chemistry
Osmium
Palladium
Photovoltaic cells
Platinum
Porphyrins
Rhenium
Rhodium
Ruthenium
Silver
synthesis
noble metals
applied properties
metalloporphyrins
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Summary:Being inert in the elemental state and as compounds, noble metals—ruthenium, osmium, rhodium, iridium, palladium, platinum, silver, and gold—and rhenium, whose compounds have similar properties, form macrocyclic complexes with specific reactivity. This review highlights the achievements of the last two decades in the chemistry of complexes of these metals with porphyrins and some of their modified analogues. Emphasis is placed on the results of studies of approaches to synthesis and chemical, physical, electrochemical, electron-optical, magnetic, and catalytic properties of complexes as a theoretical basis for the practical application of compounds of this class in catalysis, photovoltaics, and medicine.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023619140110