Visualization of the complexation between chloride and anion receptors using volume change of ionomer gels in organic solvents

Stimuli-responsive gels that can change their volumes drastically in response to various external physical and chemical stimuli have been of much interest due to their various applications. Herein, novel stimuli-responsive gels were achieved through the complexation between anion receptors and the c...

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Published inSoft matter Vol. 8; no. 28; pp. 7490 - 7494
Main Authors Iseda, Kazuya, Haketa, Yohei, Kokado, Kenta, Maeda, Hiromitsu, Furuta, Hiroyuki, Sada, Kazuki
Format Journal Article
LanguageEnglish
Published 01.01.2012
Subjects
Anions
Chlorides
Colour
Complexation
Gels
Ionomers
Receptors
Solvents
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Abstract Stimuli-responsive gels that can change their volumes drastically in response to various external physical and chemical stimuli have been of much interest due to their various applications. Herein, novel stimuli-responsive gels were achieved through the complexation between anion receptors and the chloride anion of polystyrene ionomer gels in aprotic organic solvents. The volume expansions induced by the addition of the receptors originated from breaking the aggregation of ionic groups and enhancing the dissociation of the ion-pairs, accompanied by their colour changes.
AbstractList Stimuli-responsive gels that can change their volumes drastically in response to various external physical and chemical stimuli have been of much interest due to their various applications. Herein, novel stimuli-responsive gels were achieved through the complexation between anion receptors and the chloride anion of polystyrene ionomer gels in aprotic organic solvents. The volume expansions induced by the addition of the receptors originated from breaking the aggregation of ionic groups and enhancing the dissociation of the ion-pairs, accompanied by their colour changes.
Author Maeda, Hiromitsu
Sada, Kazuki
Iseda, Kazuya
Haketa, Yohei
Kokado, Kenta
Furuta, Hiroyuki
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Snippet Stimuli-responsive gels that can change their volumes drastically in response to various external physical and chemical stimuli have been of much interest due...
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SubjectTerms Anions
Chlorides
Colour
Complexation
Gels
Ionomers
Receptors
Solvents
Title Visualization of the complexation between chloride and anion receptors using volume change of ionomer gels in organic solvents
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