Application of waterborne acrylic emulsions in coated controlled release fertilizer using reacted layer technology
Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl...
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| Published in | Chinese journal of chemical engineering Vol. 23; no. 1; pp. 309 - 314 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
2015
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature Tgof coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection. |
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| AbstractList | Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature T sub(g) of coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and T sub(g). Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection. Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature Tg of coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection. Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and produced excellent aqueous acrylic emulsion for coated controlled release fertilizer. The 30-day cumulative nutrient release was reduced to 16% and the nutrient release duration was estimated as 190days. [Display omitted] Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature Tgof coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection. |
| Author | Yazhen Shen Cong Zhao Jianmin Zhou Changwen Du |
| AuthorAffiliation | State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China |
| Author_xml | – sequence: 1 givenname: Yazhen surname: Shen fullname: Shen, Yazhen – sequence: 2 givenname: Cong surname: Zhao fullname: Zhao, Cong – sequence: 3 givenname: Jianmin surname: Zhou fullname: Zhou, Jianmin – sequence: 4 givenname: Changwen surname: Du fullname: Du, Changwen email: chwdu@issas.ac.cn |
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| Keywords | Reacted layer technology Acrylic emulsion Crosslinker Controlled release fertilizer Siloxane |
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| Notes | Controlled release fertilizer; Acrylic emulsion; Siloxane; Crosslinker; Reacted layer technology 11-3270/TQ Waterborne acrylic emulsions modified with organic siloxanes and aziridine crosslinker were synthesized and applied as coating of controlled release fertilizer. The free films were characterized and the nutrient release profiles of the coated fertilizers were determined. The results show that methyl silicone oil and methylsilanolate sodium could not improve water resistance performance and glass transition temperature Tgof coatings, while the firmness is enhanced. Aziridine crosslinker improves the water resistance performance, firmness and Tg. Incorporation of methyl silicone oil and aziridine crosslinker gives an excellent aqueous acrylic emulsion for coated controlled release fertilizer, with the 30-day cumulative nutrient release reduced to 16% and an estimated nutrient release duration over 190 days. Therefore, this waterborne coating is promising to meet the requirements for controlled release of nutrient and environmental protection. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| SubjectTerms | Acrylic emulsion Coating Controlled release Controlled release fertilizer Crosslinker Crosslinking Emulsions Fertilizing Firmness Nutrients Reacted layer technology Silicones Siloxane 养分释放曲线 包膜控释肥料 反应层 应用 抗水性能 有机聚硅氧烷 水性丙烯酸 玻璃化转变温度 |
| Title | Application of waterborne acrylic emulsions in coated controlled release fertilizer using reacted layer technology |
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