Spin crossover and valence tautomerism conductors

•Spin crossover (SCO) and valence tautomerism (VT) conductors are summarized.•Magnetic properties and conductivities of SCO and VT conductors are discussed.•Synergistic and cooperative properties of bistability and conductivity are presented. Multifunctional molecular materials exhibiting both magne...

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Bibliographic Details
Published inCoordination chemistry reviews Vol. 435; p. 213819
Main Authors Wang, Min, Li, Zhao-Yang, Ishikawa, Ryuta, Yamashita, Masahiro
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.05.2021
Subjects
Electrical conductivity
Magnetic bistability
Spin crossover
Valence tautomerism
Valence tautomerism
Electrical conductivity
Magnetic bistability
Spin crossover
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Summary:•Spin crossover (SCO) and valence tautomerism (VT) conductors are summarized.•Magnetic properties and conductivities of SCO and VT conductors are discussed.•Synergistic and cooperative properties of bistability and conductivity are presented. Multifunctional molecular materials exhibiting both magnetic bistability and electrical conductivity have excellent application potential in microelectronic devices. In the last two decades, research into conductive magnets and switching materials has continuously expanded and provided materials with practical application prospects. In this review, we present the recent progress on spin crossover and valence tautomerism conductors, focusing on syntheses, strategies, crystal structures, magnetic properties, and conductivities of such materials as well as synergistic and cooperative properties of bistability and conductivity.
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2021.213819