Spin crossover and valence tautomerism conductors

•Spin crossover (SCO) and valence tautomerism (VT) conductors are summarized.•Magnetic properties and conductivities of SCO and VT conductors are discussed.•Synergistic and cooperative properties of bistability and conductivity are presented. Multifunctional molecular materials exhibiting both magne...

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Published inCoordination chemistry reviews Vol. 435; p. 213819
Main Authors Wang, Min, Li, Zhao-Yang, Ishikawa, Ryuta, Yamashita, Masahiro
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.05.2021
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Abstract •Spin crossover (SCO) and valence tautomerism (VT) conductors are summarized.•Magnetic properties and conductivities of SCO and VT conductors are discussed.•Synergistic and cooperative properties of bistability and conductivity are presented. Multifunctional molecular materials exhibiting both magnetic bistability and electrical conductivity have excellent application potential in microelectronic devices. In the last two decades, research into conductive magnets and switching materials has continuously expanded and provided materials with practical application prospects. In this review, we present the recent progress on spin crossover and valence tautomerism conductors, focusing on syntheses, strategies, crystal structures, magnetic properties, and conductivities of such materials as well as synergistic and cooperative properties of bistability and conductivity.
AbstractList •Spin crossover (SCO) and valence tautomerism (VT) conductors are summarized.•Magnetic properties and conductivities of SCO and VT conductors are discussed.•Synergistic and cooperative properties of bistability and conductivity are presented. Multifunctional molecular materials exhibiting both magnetic bistability and electrical conductivity have excellent application potential in microelectronic devices. In the last two decades, research into conductive magnets and switching materials has continuously expanded and provided materials with practical application prospects. In this review, we present the recent progress on spin crossover and valence tautomerism conductors, focusing on syntheses, strategies, crystal structures, magnetic properties, and conductivities of such materials as well as synergistic and cooperative properties of bistability and conductivity.
ArticleNumber 213819
Author Li, Zhao-Yang
Yamashita, Masahiro
Wang, Min
Ishikawa, Ryuta
Author_xml – sequence: 1
  givenname: Min
  surname: Wang
  fullname: Wang, Min
  organization: School of Materials Science and Engineering, Nankai University, 38 Tongyan Road, Haihe Educational Park, Tianjin 300350, China
– sequence: 2
  givenname: Zhao-Yang
  surname: Li
  fullname: Li, Zhao-Yang
  email: zhaoyang@nankai.edu.cn
  organization: School of Materials Science and Engineering, Nankai University, 38 Tongyan Road, Haihe Educational Park, Tianjin 300350, China
– sequence: 3
  givenname: Ryuta
  surname: Ishikawa
  fullname: Ishikawa, Ryuta
  email: ryutaishikawa@fukuoka-u.ac.jp
  organization: Department of Chemistry, Faculty of Science, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan
– sequence: 4
  givenname: Masahiro
  surname: Yamashita
  fullname: Yamashita, Masahiro
  email: yamasita@agnus.chem.tohoku.ac.jp
  organization: Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba Aramaki, Aoba-ku, Sendai, Miyagi 980-8578, Japan
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Keywords Valence tautomerism
Electrical conductivity
Magnetic bistability
Spin crossover
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Snippet •Spin crossover (SCO) and valence tautomerism (VT) conductors are summarized.•Magnetic properties and conductivities of SCO and VT conductors are...
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StartPage 213819
SubjectTerms Electrical conductivity
Magnetic bistability
Spin crossover
Valence tautomerism
Title Spin crossover and valence tautomerism conductors
URI https://dx.doi.org/10.1016/j.ccr.2021.213819
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