Thermodynamics of hydrogen bonding and van der Waals interactions of organic solutes in solutions of imidazolium based ionic liquids: “Structure-property” relationships

• Published in: Thermochimica acta Vol. 633; pp. 12 - 23
• Main Authors: Varfolomeev, Mikhail A., Khachatrian, Artashes A., Akhmadeev, Bulat S., Solomonov, Boris N.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 10.06.2016
• Subjects: alcohols; alkanes; amides; Anions; aromatic hydrocarbons; Calorimetry; Cations; Enthalpy; Enthalpy of solution; Enthalpy of solvation; Hydrogen bond; Hydrogen bonding; Ionic liquid; Ionic liquids; solutes; Solution calorimetry; Solvation; Solvent scale; Sulfates; van der Waals forces; van der Waals interactions; Enthalpy of solvation; Solution calorimetry; Solvent scale; Enthalpy of solution; van der Waals interactions; Hydrogen bond; Ionic liquid

[Display omitted] •Solution enthalpies of organic solutes in imidazolium based ionic liquids were measured.•van der Waals interactions scale of imidazolium based ionic liquids was proposed.•Enthalpies of solvation of organic solutes in ionic liquids were determined.•Hydrogen bond enthalpies of organ...