Green biochar-based adsorbent for radiocesium and Cu, Ni, and Pb removal
Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was characterized by XPS, SEM–EDX, and FT-IR analyses. The biocharˊs adsorption capacity was 20.5(Cs), 25.2(Cu), 12.4(Ni), and 45.9(Pb) mg g −1 and demonstra...
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| Published in | Journal of radioanalytical and nuclear chemistry Vol. 332; no. 10; pp. 4141 - 4155 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cham
Springer International Publishing
01.10.2023
Springer Nature B.V |
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| Abstract | Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was characterized by XPS, SEM–EDX, and FT-IR analyses. The biocharˊs adsorption capacity was 20.5(Cs), 25.2(Cu), 12.4(Ni), and 45.9(Pb) mg g
−1
and demonstrated satisfactory performance for different pH values. The kinetics data evaluation revealed that besides chemisorption, intraparticle diffusion contributes to metal removal. Moreover, the physical and structural properties of biochar play an important role in adsorption. Results indicate the suitability of using GW biochar as an alternative sorbent for both radionuclides and metal extraction. |
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| AbstractList | Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was characterized by XPS, SEM–EDX, and FT-IR analyses. The biocharˊs adsorption capacity was 20.5(Cs), 25.2(Cu), 12.4(Ni), and 45.9(Pb) mg g−1 and demonstrated satisfactory performance for different pH values. The kinetics data evaluation revealed that besides chemisorption, intraparticle diffusion contributes to metal removal. Moreover, the physical and structural properties of biochar play an important role in adsorption. Results indicate the suitability of using GW biochar as an alternative sorbent for both radionuclides and metal extraction. Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was characterized by XPS, SEM–EDX, and FT-IR analyses. The biocharˊs adsorption capacity was 20.5(Cs), 25.2(Cu), 12.4(Ni), and 45.9(Pb) mg g −1 and demonstrated satisfactory performance for different pH values. The kinetics data evaluation revealed that besides chemisorption, intraparticle diffusion contributes to metal removal. Moreover, the physical and structural properties of biochar play an important role in adsorption. Results indicate the suitability of using GW biochar as an alternative sorbent for both radionuclides and metal extraction. Abstract Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was characterized by XPS, SEM–EDX, and FT-IR analyses. The biocharˊs adsorption capacity was 20.5(Cs), 25.2(Cu), 12.4(Ni), and 45.9(Pb) mg g −1 and demonstrated satisfactory performance for different pH values. The kinetics data evaluation revealed that besides chemisorption, intraparticle diffusion contributes to metal removal. Moreover, the physical and structural properties of biochar play an important role in adsorption. Results indicate the suitability of using GW biochar as an alternative sorbent for both radionuclides and metal extraction. |
| Author | Soja, Gerhard Kaňuchová, Mária Šuránek, Matej Pipíška, Martin Mészároš, Lukáš Melichová, Zuzana Frišták, Vladimír Ďuriška, Libor |
| Author_xml | – sequence: 1 givenname: Lukáš surname: Mészároš fullname: Mészároš, Lukáš organization: Department of Chemistry, Faculty of Natural Sciences, Matej Bel University – sequence: 2 givenname: Matej surname: Šuránek fullname: Šuránek, Matej organization: Department of Chemistry, Faculty of Natural Sciences, Matej Bel University – sequence: 3 givenname: Zuzana surname: Melichová fullname: Melichová, Zuzana organization: Department of Chemistry, Faculty of Natural Sciences, Matej Bel University – sequence: 4 givenname: Vladimír surname: Frišták fullname: Frišták, Vladimír organization: Department of Chemistry, Faculty of Education, Trnava University in Trnava – sequence: 5 givenname: Libor surname: Ďuriška fullname: Ďuriška, Libor organization: Institute of Materials Science, Faculty of Materials Science and Technology in Trnava, Slovak University of Technology in Bratislava – sequence: 6 givenname: Mária surname: Kaňuchová fullname: Kaňuchová, Mária organization: Institute of Earth Resources, Faculty of Mining, Ecology, Process Control and Geotechnologies, Technical University of Košice – sequence: 7 givenname: Gerhard surname: Soja fullname: Soja, Gerhard organization: Energy Department, AIT Austrian Institute of Technology GmbH, Institute for Chemical and Energy Engineering, University of Natural Resources and Life Sciences – sequence: 8 givenname: Martin surname: Pipíška fullname: Pipíška, Martin email: martin.pipiska@truni.sk organization: Department of Chemistry, Faculty of Education, Trnava University in Trnava |
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| Keywords | Garden waste Adsorption Biochar Heavy metals Radiocesium |
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| Snippet | Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was... Abstract Thermochemical conversion of garden waste to biochar was carried out to prepare a green adsorbent for the removal of Cs, Cu, Ni, and Pb, which was... |
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| SubjectTerms | Adsorbents Adsorption Cesium 137 Chemisorption Chemistry Chemistry and Materials Science Copper Diagnostic Radiology Hadrons Heavy Ions Inorganic Chemistry Nickel Nuclear Chemistry Nuclear Physics Physical Chemistry Radioisotopes Sorbents X ray photoelectron spectroscopy |
| Title | Green biochar-based adsorbent for radiocesium and Cu, Ni, and Pb removal |
| URI | https://link.springer.com/article/10.1007/s10967-023-09104-y https://www.proquest.com/docview/2874976632/abstract/ |
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