Carbon dots from eco-friendly precursors for optical sensing application: an up-to-date review

Carbon dots (CDs) are zero-dimensional quasi-spherical nanoparticles endowed with excellent advantages including good luminescence features, photostability, low cytotoxicity, remarkable aqueous solubility, favourable biocompatibility, low risk to environment and great flexibility in surface modifica...

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Published inChemical papers Vol. 76; no. 10; pp. 6097 - 6127
Main Authors Ullal, Namratha, Muthamma, Kashmitha, Sunil, Dhanya
Format Journal Article
LanguageEnglish
Published Warsaw Versita 01.10.2022
Springer Nature B.V
Subjects
Biochemistry
Biocompatibility
Biological properties
Biotechnology
Carbon
Carbon dots
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Fluorescence
Industrial Chemistry/Chemical Engineering
Materials Science
Medicinal Chemistry
Nanomaterials
Nanoparticles
Photoluminescence
Precursors
Raw materials
Review
Sensors
Toxicity
Fluorescence
Eco-friendly precursors
Carbon dots
Green strategies
Optical sensing
Online AccessGet full text

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Abstract Carbon dots (CDs) are zero-dimensional quasi-spherical nanoparticles endowed with excellent advantages including good luminescence features, photostability, low cytotoxicity, remarkable aqueous solubility, favourable biocompatibility, low risk to environment and great flexibility in surface modification. Fluorescent CDs that can selectively respond to specific inorganic/organic target molecules in environmental and biological samples are of prime significance amongst the new generation intelligent sensors due to the critical involvement of different ions/molecular species in not only human health, but also in environment processes. In this context, preparation of CDs from bioprecursors has immense significance due to the involvement of green principles, inexpensive, clean, nontoxic, easily accessible, renewable and large-scale production can be realized. This article aims at exploring different types of green raw materials including plant biomass, animal products, food items and waste materials as carbon sources for the synthesis of both undoped and doped CDs. The emphasis is given on different synthetic approaches adopted for improving the quantum yield without any chemical modification, the characterization techniques, mechanistic origin of photoluminescence and fluorescence response mechanisms involved in the sensing action towards various analytes. The significant benefits and limitations of CDs obtained from eco-friendly precursors through green approaches are summarized. Various challenges and the future prospects of these carbonaceous nanomaterials as sensors are also discussed. Graphical abstract
AbstractList Carbon dots (CDs) are zero-dimensional quasi-spherical nanoparticles endowed with excellent advantages including good luminescence features, photostability, low cytotoxicity, remarkable aqueous solubility, favourable biocompatibility, low risk to environment and great flexibility in surface modification. Fluorescent CDs that can selectively respond to specific inorganic/organic target molecules in environmental and biological samples are of prime significance amongst the new generation intelligent sensors due to the critical involvement of different ions/molecular species in not only human health, but also in environment processes. In this context, preparation of CDs from bioprecursors has immense significance due to the involvement of green principles, inexpensive, clean, nontoxic, easily accessible, renewable and large-scale production can be realized. This article aims at exploring different types of green raw materials including plant biomass, animal products, food items and waste materials as carbon sources for the synthesis of both undoped and doped CDs. The emphasis is given on different synthetic approaches adopted for improving the quantum yield without any chemical modification, the characterization techniques, mechanistic origin of photoluminescence and fluorescence response mechanisms involved in the sensing action towards various analytes. The significant benefits and limitations of CDs obtained from eco-friendly precursors through green approaches are summarized. Various challenges and the future prospects of these carbonaceous nanomaterials as sensors are also discussed.
Carbon dots (CDs) are zero-dimensional quasi-spherical nanoparticles endowed with excellent advantages including good luminescence features, photostability, low cytotoxicity, remarkable aqueous solubility, favourable biocompatibility, low risk to environment and great flexibility in surface modification. Fluorescent CDs that can selectively respond to specific inorganic/organic target molecules in environmental and biological samples are of prime significance amongst the new generation intelligent sensors due to the critical involvement of different ions/molecular species in not only human health, but also in environment processes. In this context, preparation of CDs from bioprecursors has immense significance due to the involvement of green principles, inexpensive, clean, nontoxic, easily accessible, renewable and large-scale production can be realized. This article aims at exploring different types of green raw materials including plant biomass, animal products, food items and waste materials as carbon sources for the synthesis of both undoped and doped CDs. The emphasis is given on different synthetic approaches adopted for improving the quantum yield without any chemical modification, the characterization techniques, mechanistic origin of photoluminescence and fluorescence response mechanisms involved in the sensing action towards various analytes. The significant benefits and limitations of CDs obtained from eco-friendly precursors through green approaches are summarized. Various challenges and the future prospects of these carbonaceous nanomaterials as sensors are also discussed. Graphical abstract
Author Muthamma, Kashmitha
Sunil, Dhanya
Ullal, Namratha
Author_xml – sequence: 1
  givenname: Namratha
  surname: Ullal
  fullname: Ullal, Namratha
  organization: Department of Chemistry, Manipal Institute of Technology, Manipal Academy of Higher Education
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  fullname: Muthamma, Kashmitha
  organization: Department of Chemistry, Manipal Institute of Technology, Manipal Academy of Higher Education
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  givenname: Dhanya
  orcidid: 0000-0002-0727-5125
  surname: Sunil
  fullname: Sunil, Dhanya
  email: dhanya.s@manipal.edu
  organization: Department of Chemistry, Manipal Institute of Technology, Manipal Academy of Higher Education
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Snippet Carbon dots (CDs) are zero-dimensional quasi-spherical nanoparticles endowed with excellent advantages including good luminescence features, photostability,...
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springer
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SubjectTerms Biochemistry
Biocompatibility
Biological properties
Biotechnology
Carbon
Carbon dots
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Fluorescence
Industrial Chemistry/Chemical Engineering
Materials Science
Medicinal Chemistry
Nanomaterials
Nanoparticles
Photoluminescence
Precursors
Raw materials
Review
Sensors
Toxicity
Title Carbon dots from eco-friendly precursors for optical sensing application: an up-to-date review
URI https://link.springer.com/article/10.1007/s11696-022-02353-3
https://www.proquest.com/docview/2714915063
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