Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices

•Overviews the current research on luminescent MOFs/LCPs as phosphor materials.•Outlines design strategies for these materials and provides representative examples.•Discusses various luminescence mechanisms in detail.•Highlights the applications of LMOFs/LCPs in energy efficient lighting technologie...

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Published inCoordination chemistry reviews Vol. 373; pp. 116 - 147
Main Authors Lustig, William P., Li, Jing
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.10.2018
Subjects
Online AccessGet full text
ISSN0010-8545
1873-3840
DOI10.1016/j.ccr.2017.09.017

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Abstract •Overviews the current research on luminescent MOFs/LCPs as phosphor materials.•Outlines design strategies for these materials and provides representative examples.•Discusses various luminescence mechanisms in detail.•Highlights the applications of LMOFs/LCPs in energy efficient lighting technologies. The development of lower cost and higher performance phosphor materials for energy efficient lighting and other optoelectronic applications is both necessary and feasible. Luminescent metal–organic frameworks and coordination polymers (LMOFs and LCPs, respectively) are a class of materials that hold great promise for this application. Their luminescence is eminently tunable, and a myriad of structures with incredibly diverse properties have been reported, with emission wavelengths covering the entire visible spectrum, white light emission from a variety of mechanisms, and quantum yields approaching unity. This review will briefly describe the luminescence mechanisms commonly observed in these materials, discuss strategies for the rational design of LMOF/LCP phosphors, and present a number of representative examples of each mechanism and/or design strategy.
AbstractList •Overviews the current research on luminescent MOFs/LCPs as phosphor materials.•Outlines design strategies for these materials and provides representative examples.•Discusses various luminescence mechanisms in detail.•Highlights the applications of LMOFs/LCPs in energy efficient lighting technologies. The development of lower cost and higher performance phosphor materials for energy efficient lighting and other optoelectronic applications is both necessary and feasible. Luminescent metal–organic frameworks and coordination polymers (LMOFs and LCPs, respectively) are a class of materials that hold great promise for this application. Their luminescence is eminently tunable, and a myriad of structures with incredibly diverse properties have been reported, with emission wavelengths covering the entire visible spectrum, white light emission from a variety of mechanisms, and quantum yields approaching unity. This review will briefly describe the luminescence mechanisms commonly observed in these materials, discuss strategies for the rational design of LMOF/LCP phosphors, and present a number of representative examples of each mechanism and/or design strategy.
Author Lustig, William P.
Li, Jing
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  givenname: Jing
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  fullname: Li, Jing
  email: jingli@rutgers.edu
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Snippet •Overviews the current research on luminescent MOFs/LCPs as phosphor materials.•Outlines design strategies for these materials and provides representative...
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Title Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices
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