Metal-organic framework-based materials for hybrid supercapacitor application

• Published in: Coordination chemistry reviews Vol. 404; p. 213093
• Main Authors: Wang, De-Gao, Liang, Zibin, Gao, Song, Qu, Chong, Zou, Ruqiang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.02.2020
• Subjects: Battery-like electrodes; Capacitive electrodes; Derivatives; Hybrid supercapacitors; Metal-organic frameworks; Hybrid supercapacitors; Derivatives; Battery-like electrodes; Metal-organic frameworks; Capacitive electrodes
• ISSN: 0010-8545; 1873-3840
• DOI: 10.1016/j.ccr.2019.213093

[Display omitted] •Three types of supercapacitor’s electrode materials are introduced.•Hybrid supercapacitors are constructed with capacitive and battery-like electrode.•Recent progress of MOF-based materials for hybrid supercapacitors were summarized.•Challenges and future directions of MOF-based materials for HSCs are provided. Constructed with both capacitive and battery-like electrodes, hybrid supercapacitor devices have been adopted as promising energy storage devices for their favorable power and energy densities. Design and fabrication of capacitive and battery-like electrode materials endowed with high specific capacitances/capacities, high rate performance and desirable durability are crucial to improve the overall energy storage performances of hybrid supercapacitors. As emerging porous crystalline materials, metal-organic frameworks with favorable porous properties, tunable chemical compositions and adjustable structures/morphologies can lead to desirable energy storage performances of hybrid supercapacitors. In this review, started from the classification of supercapacitors and electrode materials, the recent advances of pristine metal-organic frameworks, metal-organic framework composites and metal-organic frameworks derived materials applied for hybrid supercapacitor were elaborated. Furthermore, based on previous contributions, challenges and perspectives of metal-organic framework-based materials for hybrid supercapacitor application were summarized.