Ferrocene-contained metal organic frameworks: From synthesis to applications
•The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs and their corresponding applications were reviewed.•The challenges and further research directions of Fc-contained MOFs were presented. Recen...
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Published in | Coordination chemistry reviews Vol. 430; p. 213737 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.03.2021
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Abstract | •The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs and their corresponding applications were reviewed.•The challenges and further research directions of Fc-contained MOFs were presented.
Recently, metal organic frameworks (MOFs) have attracted tremendous research attention in many fields, including gas separation, wastewater treatment, energy storage and conversion, catalysis, sensors, etc. To satisfy various demands of special practical applications, the pristine MOFs were usually hybridized with other molecules to form multifunctional materials. Due to their unique reversible redox properties, outstanding optical and electrochemical activities, ferrocene (Fc) and its derivatives have been employed as the guest molecules or functional units in MOFs, these Fc-contained MOFs usually exhibit unique performance in many fields compared with pristine MOFs and bare Fc molecules. In this review, the recent progresses of Fc-contained MOFs and their derived materials are reviewed, including the role of Fc in Fc-contained MOFs, synthesis methods and corresponding applications. The challenges and potential research directions of Fc-contained MOFs are also presented and highlighted. |
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AbstractList | •The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs and their corresponding applications were reviewed.•The challenges and further research directions of Fc-contained MOFs were presented.
Recently, metal organic frameworks (MOFs) have attracted tremendous research attention in many fields, including gas separation, wastewater treatment, energy storage and conversion, catalysis, sensors, etc. To satisfy various demands of special practical applications, the pristine MOFs were usually hybridized with other molecules to form multifunctional materials. Due to their unique reversible redox properties, outstanding optical and electrochemical activities, ferrocene (Fc) and its derivatives have been employed as the guest molecules or functional units in MOFs, these Fc-contained MOFs usually exhibit unique performance in many fields compared with pristine MOFs and bare Fc molecules. In this review, the recent progresses of Fc-contained MOFs and their derived materials are reviewed, including the role of Fc in Fc-contained MOFs, synthesis methods and corresponding applications. The challenges and potential research directions of Fc-contained MOFs are also presented and highlighted. |
ArticleNumber | 213737 |
Author | Liu, Xiaowei Yu, Haojie Wang, Li Lemenovskiy, Dmitry A. Huang, Zhikun Vatsadze, Sergey Z. Lin, Tengfei Haq, Fazal |
Author_xml | – sequence: 1 givenname: Zhikun surname: Huang fullname: Huang, Zhikun organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 2 givenname: Haojie surname: Yu fullname: Yu, Haojie email: hjyu@zju.edu.cn organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 3 givenname: Li surname: Wang fullname: Wang, Li organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 4 givenname: Xiaowei surname: Liu fullname: Liu, Xiaowei organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 5 givenname: Tengfei surname: Lin fullname: Lin, Tengfei organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 6 givenname: Fazal surname: Haq fullname: Haq, Fazal organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 7 givenname: Sergey Z. surname: Vatsadze fullname: Vatsadze, Sergey Z. organization: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp, 119991 Moscow, Russia – sequence: 8 givenname: Dmitry A. surname: Lemenovskiy fullname: Lemenovskiy, Dmitry A. organization: Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russia |
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Title | Ferrocene-contained metal organic frameworks: From synthesis to applications |
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