Ferrocene-contained metal organic frameworks: From synthesis to applications

•The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs and their corresponding applications were reviewed.•The challenges and further research directions of Fc-contained MOFs were presented. Recen...

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Published inCoordination chemistry reviews Vol. 430; p. 213737
Main Authors Huang, Zhikun, Yu, Haojie, Wang, Li, Liu, Xiaowei, Lin, Tengfei, Haq, Fazal, Vatsadze, Sergey Z., Lemenovskiy, Dmitry A.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.03.2021
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Abstract •The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs and their corresponding applications were reviewed.•The challenges and further research directions of Fc-contained MOFs were presented. Recently, metal organic frameworks (MOFs) have attracted tremendous research attention in many fields, including gas separation, wastewater treatment, energy storage and conversion, catalysis, sensors, etc. To satisfy various demands of special practical applications, the pristine MOFs were usually hybridized with other molecules to form multifunctional materials. Due to their unique reversible redox properties, outstanding optical and electrochemical activities, ferrocene (Fc) and its derivatives have been employed as the guest molecules or functional units in MOFs, these Fc-contained MOFs usually exhibit unique performance in many fields compared with pristine MOFs and bare Fc molecules. In this review, the recent progresses of Fc-contained MOFs and their derived materials are reviewed, including the role of Fc in Fc-contained MOFs, synthesis methods and corresponding applications. The challenges and potential research directions of Fc-contained MOFs are also presented and highlighted.
AbstractList •The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs and their corresponding applications were reviewed.•The challenges and further research directions of Fc-contained MOFs were presented. Recently, metal organic frameworks (MOFs) have attracted tremendous research attention in many fields, including gas separation, wastewater treatment, energy storage and conversion, catalysis, sensors, etc. To satisfy various demands of special practical applications, the pristine MOFs were usually hybridized with other molecules to form multifunctional materials. Due to their unique reversible redox properties, outstanding optical and electrochemical activities, ferrocene (Fc) and its derivatives have been employed as the guest molecules or functional units in MOFs, these Fc-contained MOFs usually exhibit unique performance in many fields compared with pristine MOFs and bare Fc molecules. In this review, the recent progresses of Fc-contained MOFs and their derived materials are reviewed, including the role of Fc in Fc-contained MOFs, synthesis methods and corresponding applications. The challenges and potential research directions of Fc-contained MOFs are also presented and highlighted.
ArticleNumber 213737
Author Liu, Xiaowei
Yu, Haojie
Wang, Li
Lemenovskiy, Dmitry A.
Huang, Zhikun
Vatsadze, Sergey Z.
Lin, Tengfei
Haq, Fazal
Author_xml – sequence: 1
  givenname: Zhikun
  surname: Huang
  fullname: Huang, Zhikun
  organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China
– sequence: 2
  givenname: Haojie
  surname: Yu
  fullname: Yu, Haojie
  email: hjyu@zju.edu.cn
  organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China
– sequence: 3
  givenname: Li
  surname: Wang
  fullname: Wang, Li
  organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China
– sequence: 4
  givenname: Xiaowei
  surname: Liu
  fullname: Liu, Xiaowei
  organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China
– sequence: 5
  givenname: Tengfei
  surname: Lin
  fullname: Lin, Tengfei
  organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China
– sequence: 6
  givenname: Fazal
  surname: Haq
  fullname: Haq, Fazal
  organization: State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, PR China
– sequence: 7
  givenname: Sergey Z.
  surname: Vatsadze
  fullname: Vatsadze, Sergey Z.
  organization: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp, 119991 Moscow, Russia
– sequence: 8
  givenname: Dmitry A.
  surname: Lemenovskiy
  fullname: Lemenovskiy, Dmitry A.
  organization: Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russia
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Keywords Metal organic frameworks
Applications
Synthesis methods
Ferrocene
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Snippet •The Fc-contained MOFs was first reviewed.•The Fc-contained MOFs can be clearly divided into four basic categories.•The synthesis methods of Fc-contained MOFs...
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SubjectTerms Applications
Ferrocene
Metal organic frameworks
Synthesis methods
Title Ferrocene-contained metal organic frameworks: From synthesis to applications
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