A mixed-ligand strategy regulates thorium-based MOFs

Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 49; no. 4; pp. 983 - 987
Main Authors Huang, Zhi-wei, Hu, Kong-qiu, Mei, Lei, Kong, Xiang-he, Yu, Ji-pan, Liu, Kang, Zeng, Li-wen, Chai, Zhi-Fang, Shi, Wei-Qun
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 28.01.2020
Subjects
Carboxylic acids
Catalytic activity
Crystallography
Ligands
Metal-organic frameworks
NMR
Nuclear magnetic resonance
Oxidation
Photocatalysis
Photoelectric effect
Photoelectric emission
Size distribution
Thorium
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Abstract Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO 2 . The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine. A thorium-based MOF formed via the synergistic construction of porphyrin and bipyridyl based on the mixed-ligand strategy has the effect of enhancing photocatalysis.
AbstractList Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO 2 . The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine.
Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO2. The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine.Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO2. The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine.
Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO2. The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine.
Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO 2 . The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine. A thorium-based MOF formed via the synergistic construction of porphyrin and bipyridyl based on the mixed-ligand strategy has the effect of enhancing photocatalysis.
Author Yu, Ji-pan
Hu, Kong-qiu
Mei, Lei
Zeng, Li-wen
Liu, Kang
Huang, Zhi-wei
Kong, Xiang-he
Chai, Zhi-Fang
Shi, Wei-Qun
AuthorAffiliation Ningbo Institute of Industrial Technology
Chinese Academy of Sciences
Laboratory of Nuclear Energy Chemistry. Institute of High Energy Physics
Engineering Laboratory of Advanced Energy Materials
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Snippet Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear...
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SubjectTerms Carboxylic acids
Catalytic activity
Crystallography
Ligands
Metal-organic frameworks
NMR
Nuclear magnetic resonance
Oxidation
Photocatalysis
Photoelectric effect
Photoelectric emission
Size distribution
Thorium
Title A mixed-ligand strategy regulates thorium-based MOFs
URI https://www.ncbi.nlm.nih.gov/pubmed/31904068
https://www.proquest.com/docview/2346334445
https://www.proquest.com/docview/2333932448
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