Theory of A.c. Polarization and A.c. Polarography and Voltammetry of Two-step Surface Redox Reactions

• Published in: Bulletin of the Chemical Society of Japan Vol. 53; no. 7; pp. 1942 - 1948
• Main Authors: Kakutani, Tadaaki, Senda, Mitsugi
• Format: Journal Article
• Language: English
• Published: Tokyo The Chemical Society of Japan 01.07.1980; Chemical Society of Japan

Theoretical expressions are presented of the a.c. polarization and of the a.c. polarography and voltammetry for a two-step surface redox reaction (Oad+n1e\ightleftharpoonsSad,Sad+n2e\ightleftharpoonsRad) in which the charge transfer reactions take place exclusively between the adsorbed reactants Oad...