Evidence for production of surface formate upon direct reaction of CO with alumina and magnesia
The observation of adsorbed formate ion produced by the reaction of CO with MgO or γ-Al 2O 3 surfaces at temperatures between 375 and 575 K is reported. Infrared bands observed near 1590, 1380, 1360, and 1050 are assigned to the fundamentals of adsorbed HCO 2 − ion on the basis of spectra that have...
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| Published in | Journal of catalysis Vol. 105; no. 2; pp. 366 - 372 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier Inc
01.06.1987
Elsevier |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The observation of adsorbed formate ion produced by the reaction of CO with MgO or γ-Al
2O
3 surfaces at temperatures between 375 and 575 K is reported. Infrared bands observed near 1590, 1380, 1360, and 1050 are assigned to the fundamentals of adsorbed HCO
2
− ion on the basis of spectra that have been reported for formate ion in solution. The spectral bands and observed isotopic shifts for adsorbed formate produced by reaction of the oxide surface with CO agree with the spectra of formates produced by reaction of methanol or formic acid with the same surfaces. The intensity of IR bands due to formate produced by reaction of the oxide surfaces with CO depends upon the hydroxyl group concentration at the surface. A mechanism for conversion of CO to formate via a surface acylium ion is proposed. |
|---|---|
| AbstractList | The observation of adsorbed formate ion produced by the reaction of CO with MgO or γ-Al
2O
3 surfaces at temperatures between 375 and 575 K is reported. Infrared bands observed near 1590, 1380, 1360, and 1050 are assigned to the fundamentals of adsorbed HCO
2
− ion on the basis of spectra that have been reported for formate ion in solution. The spectral bands and observed isotopic shifts for adsorbed formate produced by reaction of the oxide surface with CO agree with the spectra of formates produced by reaction of methanol or formic acid with the same surfaces. The intensity of IR bands due to formate produced by reaction of the oxide surfaces with CO depends upon the hydroxyl group concentration at the surface. A mechanism for conversion of CO to formate via a surface acylium ion is proposed. |
| Author | Gopal, Pradip G. Schneider, Roger L. Watters, Kenneth L. |
| Author_xml | – sequence: 1 givenname: Pradip G. surname: Gopal fullname: Gopal, Pradip G. – sequence: 2 givenname: Roger L. surname: Schneider fullname: Schneider, Roger L. – sequence: 3 givenname: Kenneth L. surname: Watters fullname: Watters, Kenneth L. |
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| Keywords | Infrared spectrometry Surface reaction Magnesia Reaction mechanism Formate Carbon monoxide Alumina Catalyst |
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| References | Oscowtos, Heil, Marko (BIB20) 1972; 37 Evans, Whateley, Smart, Slager, Little, Greenler, Gatehouse, Livingston, Nyholm, Fujita, Martell, Nakamoto (BIB15) 1967; 63 Solymosi, Erdohelyi, Kocsis (BIB13) 1980; 65 Kleir (BIB23) 1984; Vol. 19 Harvey, Morrow, Shurwell (BIB17) 1963; 41 Kagel (BIB6) 1967; 71 Corso (BIB7) 1964; 259 Dalla Betta, Shelef (BIB8) 1977; 48 Schneider, Howe, Watters (BIB11) 1983; 79 Hammaker, Walters (BIB16) 1964; 20 March (BIB21) 1977 Kroeker, Kaska, Hansma (BIB25) 1980; 61 Greenler (BIB3) 1962; 37 Ueno, Onishi, Tamaru (BIB10) 1970; 66 Kagel, Greenler (BIB5) 1968; 49 Gopal, Watters (BIB12) 1984; Vol. 7 Yankerson, Lafer, Danyushevskii, Rubinstein (BIB1) 1964; 19 Rosenblum, Nethercot, Townes (BIB22) 1958; 109 Itoh, Bernstein (BIB2) 1958; 34 Amenomya (BIB24) 1979; 57 Amenomiya (BIB9) 1978; 32 Stephenson, Wilkenson (BIB19) 1967; 29 Robinson, Uttley (BIB18) 1973 Donaldson, Kifton, Ross (BIB4) 1964; 20 Schneider, Howe, Watters (BIB14) 1984; 23 |
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| Snippet | The observation of adsorbed formate ion produced by the reaction of CO with MgO or γ-Al
2O
3 surfaces at temperatures between 375 and 575 K is reported.... |
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| SubjectTerms | Applied sciences Catalysis Catalysts: preparations and properties Catalytic reactions Chemistry Exact sciences and technology General and physical chemistry General. Nomenclature, chemical documentation, computer chemistry Other techniques and industries Theory of reactions, general kinetics Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| Title | Evidence for production of surface formate upon direct reaction of CO with alumina and magnesia |
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