Understanding the mobilisation of metal pollution associated with historical mining in a carboniferous upland catchment

Point and diffuse pollution from metal mining has led to severe environmental damage worldwide. Mine drainage is a significant problem for riverine ecosystems, it is commonly acidic (AMD), but neutral mine drainage (NMD) can also occur. A representative environment for studying metal pollution from...

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Published inEnvironmental science--processes & impacts Vol. 19; no. 8; pp. 1061 - 1074
Main Authors Valencia-Avellan, Magaly, Slack, Rebecca, Stockdale, Anthony, Mortimer, Robert John George
Format Journal Article
LanguageEnglish
Published England 16.08.2017
Subjects
Carbonates - analysis
Environmental Monitoring - methods
Geologic Sediments - chemistry
Lead - analysis
Mining
Rivers - chemistry
United Kingdom
Waste Water - chemistry
Water Pollutants, Chemical - analysis
Zinc - analysis
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Abstract Point and diffuse pollution from metal mining has led to severe environmental damage worldwide. Mine drainage is a significant problem for riverine ecosystems, it is commonly acidic (AMD), but neutral mine drainage (NMD) can also occur. A representative environment for studying metal pollution from NMD is provided by carboniferous catchments characterised by a circumneutral pH and high concentrations of carbonates, supporting the formation of secondary metal-minerals as potential sinks of metals. The present study focuses on understanding the mobility of metal pollution associated with historical mining in a carboniferous upland catchment. In the uplands of the UK, river water, sediments and spoil wastes were collected over a period of fourteen months, samples were chemically analysed to identify the main metal sources and their relationships with geological and hydrological factors. Correlation tests and principal component analysis suggest that the underlying limestone bedrock controls pH and weathering reactions. Significant metal concentrations from mining activities were measured for zinc (4.3 mg l ), and lead (0.3 mg l ), attributed to processes such as oxidation of mined ores (e.g. sphalerite, galena) or dissolution of precipitated secondary metal-minerals (e.g. cerussite, smithsonite). Zinc and lead mobility indicated strong dependence on biogeochemistry and hydrological conditions (e.g. pH and flow) at specific locations in the catchment. Annual loads of zinc and lead (2.9 and 0.2 tonnes per year) demonstrate a significant source of both metals to downstream river reaches. Metal pollution results in a large area of catchment having a depleted chemical status with likely effects on the aquatic ecology. This study provides an improved understanding of geological and hydrological processes controlling water chemistry, which is critical to assessing metal sources and mobilization, especially in neutral mine drainage areas.
AbstractList Point and diffuse pollution from metal mining has led to severe environmental damage worldwide. Mine drainage is a significant problem for riverine ecosystems, it is commonly acidic (AMD), but neutral mine drainage (NMD) can also occur. A representative environment for studying metal pollution from NMD is provided by carboniferous catchments characterised by a circumneutral pH and high concentrations of carbonates, supporting the formation of secondary metal-minerals as potential sinks of metals. The present study focuses on understanding the mobility of metal pollution associated with historical mining in a carboniferous upland catchment. In the uplands of the UK, river water, sediments and spoil wastes were collected over a period of fourteen months, samples were chemically analysed to identify the main metal sources and their relationships with geological and hydrological factors. Correlation tests and principal component analysis suggest that the underlying limestone bedrock controls pH and weathering reactions. Significant metal concentrations from mining activities were measured for zinc (4.3 mg l-1), and lead (0.3 mg l-1), attributed to processes such as oxidation of mined ores (e.g. sphalerite, galena) or dissolution of precipitated secondary metal-minerals (e.g. cerussite, smithsonite). Zinc and lead mobility indicated strong dependence on biogeochemistry and hydrological conditions (e.g. pH and flow) at specific locations in the catchment. Annual loads of zinc and lead (2.9 and 0.2 tonnes per year) demonstrate a significant source of both metals to downstream river reaches. Metal pollution results in a large area of catchment having a depleted chemical status with likely effects on the aquatic ecology. This study provides an improved understanding of geological and hydrological processes controlling water chemistry, which is critical to assessing metal sources and mobilization, especially in neutral mine drainage areas.
Point and diffuse pollution from metal mining has led to severe environmental damage worldwide. Mine drainage is a significant problem for riverine ecosystems, it is commonly acidic (AMD), but neutral mine drainage (NMD) can also occur. A representative environment for studying metal pollution from NMD is provided by carboniferous catchments characterised by a circumneutral pH and high concentrations of carbonates, supporting the formation of secondary metal-minerals as potential sinks of metals. The present study focuses on understanding the mobility of metal pollution associated with historical mining in a carboniferous upland catchment. In the uplands of the UK, river water, sediments and spoil wastes were collected over a period of fourteen months, samples were chemically analysed to identify the main metal sources and their relationships with geological and hydrological factors. Correlation tests and principal component analysis suggest that the underlying limestone bedrock controls pH and weathering reactions. Significant metal concentrations from mining activities were measured for zinc (4.3 mg l ), and lead (0.3 mg l ), attributed to processes such as oxidation of mined ores (e.g. sphalerite, galena) or dissolution of precipitated secondary metal-minerals (e.g. cerussite, smithsonite). Zinc and lead mobility indicated strong dependence on biogeochemistry and hydrological conditions (e.g. pH and flow) at specific locations in the catchment. Annual loads of zinc and lead (2.9 and 0.2 tonnes per year) demonstrate a significant source of both metals to downstream river reaches. Metal pollution results in a large area of catchment having a depleted chemical status with likely effects on the aquatic ecology. This study provides an improved understanding of geological and hydrological processes controlling water chemistry, which is critical to assessing metal sources and mobilization, especially in neutral mine drainage areas.
Point and diffuse pollution from metal mining has led to severe environmental damage worldwide. Mine drainage is a significant problem for riverine ecosystems, it is commonly acidic (AMD), but neutral mine drainage (NMD) can also occur. A representative environment for studying metal pollution from NMD is provided by carboniferous catchments characterised by a circumneutral pH and high concentrations of carbonates, supporting the formation of secondary metal–minerals as potential sinks of metals. The present study focuses on understanding the mobility of metal pollution associated with historical mining in a carboniferous upland catchment. In the uplands of the UK, river water, sediments and spoil wastes were collected over a period of fourteen months, samples were chemically analysed to identify the main metal sources and their relationships with geological and hydrological factors. Correlation tests and principal component analysis suggest that the underlying limestone bedrock controls pH and weathering reactions. Significant metal concentrations from mining activities were measured for zinc (4.3 mg l −1 ), and lead (0.3 mg l −1 ), attributed to processes such as oxidation of mined ores ( e.g. sphalerite, galena) or dissolution of precipitated secondary metal–minerals ( e.g. cerussite, smithsonite). Zinc and lead mobility indicated strong dependence on biogeochemistry and hydrological conditions ( e.g. pH and flow) at specific locations in the catchment. Annual loads of zinc and lead (2.9 and 0.2 tonnes per year) demonstrate a significant source of both metals to downstream river reaches. Metal pollution results in a large area of catchment having a depleted chemical status with likely effects on the aquatic ecology. This study provides an improved understanding of geological and hydrological processes controlling water chemistry, which is critical to assessing metal sources and mobilization, especially in neutral mine drainage areas.
Author Slack, Rebecca
Stockdale, Anthony
Mortimer, Robert John George
Valencia-Avellan, Magaly
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crossref_primary_10_1071_EN17133
crossref_primary_10_1016_j_scitotenv_2023_162274
crossref_primary_10_3390_min10080721
Cites_doi 10.1016/j.apgeochem.2007.10.011
10.1021/es970452k
10.1016/j.geoderma.2009.01.023
10.1016/j.jhydrol.2007.05.004
10.1016/j.apgeochem.2009.09.012
10.1016/S0883-2927(01)00065-8
10.1016/j.chemgeo.2004.10.001
10.2113/gselements.7.6.381
10.1111/j.1752-1688.2007.00002.x
10.1016/0375-6742(94)00041-9
10.1016/S0048-9697(96)05381-8
10.1007/s10230-008-0056-2
10.1016/S0883-2927(99)00008-6
10.1016/j.chemgeo.2005.02.001
10.1111/j.1752-1688.2007.00008.x
10.1007/978-3-642-12419-8
10.1016/S0013-7952(00)00101-0
10.1002/hyp.3360070406
10.1002/ieam.5630020114
10.1016/j.envpol.2007.05.011
10.1007/s10230-015-0344-6
10.1007/s11356-013-1515-2
10.1002/(SICI)1099-1085(199602)10:2<227::AID-HYP357>3.0.CO;2-X
10.1016/0269-7491(89)90242-X
10.1021/es9500724
10.1016/j.apgeochem.2011.06.002
10.5539/ep.v2n4p22
10.1016/j.scitotenv.2009.06.019
10.1016/j.jhydrol.2007.11.022
10.1016/j.apgeochem.2005.01.011
10.1021/es980823c
10.1080/10643389.2011.574103
10.1016/j.gexplo.2011.06.001
10.1007/s102300200033
10.1016/S0375-6742(96)00064-7
10.1016/j.jclepro.2004.09.006
10.1016/j.crte.2003.09.006
10.1016/j.scitotenv.2004.05.012
10.1007/s10646-014-1246-2
10.1016/j.scitotenv.2003.08.011
10.1016/j.apgeochem.2006.09.008
10.1002/esp.1762
10.1007/s11356-013-1513-4
10.1016/j.ncon.2016.10.003
10.1007/s00267-007-9033-y
10.1073/pnas.201150998
10.1016/j.proeps.2016.12.056
10.3390/min4010052
10.1180/0026461036720095
10.1016/j.ecss.2004.09.017
10.1016/j.apgeochem.2007.10.003
10.1016/S0375-6742(96)00073-8
10.1016/S0012-8252(01)00032-0
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References Mayes (C7EM00171A-(cit21)/*[position()=1]) 2009; 407
US Environmental Protection Agency and Office of Research and Development (C7EM00171A-(cit42)/*[position()=1]) 1982
Environment Agency (C7EM00171A-(cit81)/*[position()=1]) 2014
Horowitz (C7EM00171A-(cit74)/*[position()=1]) 1991
Cave (C7EM00171A-(cit36)/*[position()=1]) 2005; 62
Carroll (C7EM00171A-(cit50)/*[position()=1]) 1998; 32
Sánchez España (C7EM00171A-(cit28)/*[position()=1]) 2005; 20
Ball (C7EM00171A-(cit46)/*[position()=1]) 1991
Iavazzo (C7EM00171A-(cit60)/*[position()=1]) 2012; 113
Drever (C7EM00171A-(cit47)/*[position()=1]) 1997
Lottermoser (C7EM00171A-(cit32)/*[position()=1]) 2010
Dunham (C7EM00171A-(cit59)/*[position()=1]) 1985
Sims (C7EM00171A-(cit68)/*[position()=1]) 2013; 2
Macklin (C7EM00171A-(cit2)/*[position()=1]) 1996
Cravotta III (C7EM00171A-(cit27)/*[position()=1]) 2008; 23
Parkhurst (C7EM00171A-(cit44)/*[position()=1]) 1999
Balistrieri (C7EM00171A-(cit55)/*[position()=1]) 1999; 33
Hudson-Edwards (C7EM00171A-(cit69)/*[position()=1]) 1996; 30
Desbarats (C7EM00171A-(cit30)/*[position()=1]) 2007; 22
Navarro (C7EM00171A-(cit24)/*[position()=1]) 2015; 34
Hudson-Edwards (C7EM00171A-(cit35)/*[position()=1]) 2005; 219
Barber (C7EM00171A-(cit39)/*[position()=1]) 2014
Jones (C7EM00171A-(cit14)/*[position()=1]) 2013; 20
Byrne (C7EM00171A-(cit64)/*[position()=1]) 19–23 October 2009
Meyer (C7EM00171A-(cit20)/*[position()=1]) 2007; 43
Johnston (C7EM00171A-(cit38)/*[position()=1]) 2008
Apha (C7EM00171A-(cit41)/*[position()=1]) 1995
Cravotta III (C7EM00171A-(cit26)/*[position()=1]) 2008; 23
Lindsay (C7EM00171A-(cit29)/*[position()=1]) 2009; 24
Dennis (C7EM00171A-(cit78)/*[position()=1]) 2009; 34
Elder (C7EM00171A-(cit16)/*[position()=1]) 1988; vol. 1013
Jarvis (C7EM00171A-(cit80)/*[position()=1]) 2015
C7EM00171A-(cit76)/*[position()=1]
Gosar (C7EM00171A-(cit34)/*[position()=1]) 1997; 58
Luoma (C7EM00171A-(cit15)/*[position()=1]) 2008
Miller (C7EM00171A-(cit5)/*[position()=1]) 2004; 320
Hudson-Edwards (C7EM00171A-(cit11)/*[position()=1]) 1997; 194
Gill (C7EM00171A-(cit40)/*[position()=1]) 1993
Carmona (C7EM00171A-(cit51)/*[position()=1]) 2009; 150
Heikkinen (C7EM00171A-(cit31)/*[position()=1]) 2009; 28
Ettler (C7EM00171A-(cit54)/*[position()=1]) 2003; 335
Langmuir (C7EM00171A-(cit71)/*[position()=1]) 1997
Nuttall (C7EM00171A-(cit49)/*[position()=1]) 2002; vol. 198
Taylor (C7EM00171A-(cit37)/*[position()=1]) 2008; 152
Nordstrom (C7EM00171A-(cit56)/*[position()=1]) 2011; 26
Byrne (C7EM00171A-(cit13)/*[position()=1]) 2012; 42
Nordstrom (C7EM00171A-(cit62)/*[position()=1]) 1982
Macklin (C7EM00171A-(cit7)/*[position()=1]) 1997; vol. 201–238
Miller (C7EM00171A-(cit33)/*[position()=1]) 1997; 58
Olías (C7EM00171A-(cit9)/*[position()=1]) 2004; 333
Freeman (C7EM00171A-(cit18)/*[position()=1]) 2007; 43
Cánovas (C7EM00171A-(cit65)/*[position()=1]) 2008; 350
Horowitz (C7EM00171A-(cit1)/*[position()=1]) 1993; 7
Hudson-Edwards (C7EM00171A-(cit8)/*[position()=1]) 2003; 67
C7EM00171A-(cit75)/*[position()=1]
Osbourn (C7EM00171A-(cit57)/*[position()=1])
Dodds (C7EM00171A-(cit19)/*[position()=1]) 2008; 41
Apitz (C7EM00171A-(cit17)/*[position()=1]) 2006; 2
Rothwell (C7EM00171A-(cit66)/*[position()=1]) 2007; 341
Nagorski (C7EM00171A-(cit4)/*[position()=1]) 2002; 21
Mulligan (C7EM00171A-(cit79)/*[position()=1]) 2001; 60
Templeton (C7EM00171A-(cit61)/*[position()=1]) 2001; 98
Banks (C7EM00171A-(cit22)/*[position()=1]) 2002; vol. 198
Lynch (C7EM00171A-(cit67)/*[position()=1]) 2014; 4
Jamieson (C7EM00171A-(cit63)/*[position()=1]) 2005; 215
Douben (C7EM00171A-(cit70)/*[position()=1]) 1989; 61
C7EM00171A-(cit43)/*[position()=1]
Li (C7EM00171A-(cit53)/*[position()=1]) 2001; 16
Tame (C7EM00171A-(cit48)/*[position()=1]) 2017; 17
Byrne (C7EM00171A-(cit82)/*[position()=1]) 2013; 15
Hudson-Edwards (C7EM00171A-(cit3)/*[position()=1]) 1999; 14
Nordstrom (C7EM00171A-(cit45)/*[position()=1]) 1990
Palumbo-Roe (C7EM00171A-(cit58)/*[position()=1]) 2013; 20
Foster (C7EM00171A-(cit72)/*[position()=1]) 1996; 10
Oulton (C7EM00171A-(cit10)/*[position()=1]) 2014; 23
Plumlee (C7EM00171A-(cit25)/*[position()=1]) 1999; vol. 6
Horowitz (C7EM00171A-(cit73)/*[position()=1]) 1995; 52
Jamieson (C7EM00171A-(cit52)/*[position()=1]) 2011; 7
Fernandes (C7EM00171A-(cit6)/*[position()=1]) 2016; 14
Warren (C7EM00171A-(cit12)/*[position()=1]) 2001; 54
Akcil (C7EM00171A-(cit23)/*[position()=1]) 2006; 14
References_xml – volume: 23
  start-page: 166
  year: 2008
  ident: C7EM00171A-(cit26)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/j.apgeochem.2007.10.011
  contributor:
    fullname: Cravotta III
– volume: 32
  start-page: 956
  year: 1998
  ident: C7EM00171A-(cit50)/*[position()=1]
  publication-title: Environ. Sci. Technol.
  doi: 10.1021/es970452k
  contributor:
    fullname: Carroll
– volume: 150
  start-page: 150
  year: 2009
  ident: C7EM00171A-(cit51)/*[position()=1]
  publication-title: Geoderma
  doi: 10.1016/j.geoderma.2009.01.023
  contributor:
    fullname: Carmona
– volume: 341
  start-page: 90
  year: 2007
  ident: C7EM00171A-(cit66)/*[position()=1]
  publication-title: J. Hydrol.
  doi: 10.1016/j.jhydrol.2007.05.004
  contributor:
    fullname: Rothwell
– volume: vol. 198
  volume-title: Alkaline mine drainage from metal sulphide and coal mines: examples from Svalbard and Siberia
  year: 2002
  ident: C7EM00171A-(cit22)/*[position()=1]
  contributor:
    fullname: Banks
– volume: 24
  start-page: 2212
  year: 2009
  ident: C7EM00171A-(cit29)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/j.apgeochem.2009.09.012
  contributor:
    fullname: Lindsay
– ident: C7EM00171A-(cit43)/*[position()=1]
– volume: 16
  start-page: 1693
  year: 2001
  ident: C7EM00171A-(cit53)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/S0883-2927(01)00065-8
  contributor:
    fullname: Li
– volume: 215
  start-page: 387
  year: 2005
  ident: C7EM00171A-(cit63)/*[position()=1]
  publication-title: Chem. Geol.
  doi: 10.1016/j.chemgeo.2004.10.001
  contributor:
    fullname: Jamieson
– volume-title: Environmental Monitoring and Support Laboratory: Handbook for sampling and sample preservation of water and wastewater
  year: 1982
  ident: C7EM00171A-(cit42)/*[position()=1]
  contributor:
    fullname: US Environmental Protection Agency and Office of Research and Development
– volume: 7
  start-page: 381
  year: 2011
  ident: C7EM00171A-(cit52)/*[position()=1]
  publication-title: Elements
  doi: 10.2113/gselements.7.6.381
  contributor:
    fullname: Jamieson
– volume: 43
  start-page: 5
  issue: 1
  year: 2007
  ident: C7EM00171A-(cit18)/*[position()=1]
  publication-title: J. Am. Water Resour. Assoc.
  doi: 10.1111/j.1752-1688.2007.00002.x
  contributor:
    fullname: Freeman
– ident: C7EM00171A-(cit76)/*[position()=1]
– volume: 52
  start-page: 135
  year: 1995
  ident: C7EM00171A-(cit73)/*[position()=1]
  publication-title: J. Geochem. Explor.
  doi: 10.1016/0375-6742(94)00041-9
  contributor:
    fullname: Horowitz
– volume-title: Abandoned mines and the water environment. Science project: SC030136-41
  year: 2008
  ident: C7EM00171A-(cit38)/*[position()=1]
  contributor:
    fullname: Johnston
– volume: 194
  start-page: 437
  year: 1997
  ident: C7EM00171A-(cit11)/*[position()=1]
  publication-title: Sci. Total Environ.
  doi: 10.1016/S0048-9697(96)05381-8
  contributor:
    fullname: Hudson-Edwards
– volume: 28
  start-page: 30
  year: 2009
  ident: C7EM00171A-(cit31)/*[position()=1]
  publication-title: Mine Water Environ.
  doi: 10.1007/s10230-008-0056-2
  contributor:
    fullname: Heikkinen
– volume: 14
  start-page: 1015
  year: 1999
  ident: C7EM00171A-(cit3)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/S0883-2927(99)00008-6
  contributor:
    fullname: Hudson-Edwards
– volume: 219
  start-page: 175
  year: 2005
  ident: C7EM00171A-(cit35)/*[position()=1]
  publication-title: Chem. Geol.
  doi: 10.1016/j.chemgeo.2005.02.001
  contributor:
    fullname: Hudson-Edwards
– volume: 43
  start-page: 86
  issue: 1
  year: 2007
  ident: C7EM00171A-(cit20)/*[position()=1]
  publication-title: J. Am. Water Resour. Assoc.
  doi: 10.1111/j.1752-1688.2007.00008.x
  contributor:
    fullname: Meyer
– volume-title: Proceedings of the International Mine Water Conference
  year: 19–23 October 2009
  ident: C7EM00171A-(cit64)/*[position()=1]
  contributor:
    fullname: Byrne
– volume-title: Revised chemical equilibrium data for major water–mineral reactions and their limitations
  year: 1990
  ident: C7EM00171A-(cit45)/*[position()=1]
  contributor:
    fullname: Nordstrom
– volume: vol. 201–238
  volume-title: Fluvial Geomorphology of Great Britain
  year: 1997
  ident: C7EM00171A-(cit7)/*[position()=1]
  contributor:
    fullname: Macklin
– volume-title: Mine Wastes: Charaterization, Treatment and Environmental Impacts
  year: 2010
  ident: C7EM00171A-(cit32)/*[position()=1]
  doi: 10.1007/978-3-642-12419-8
  contributor:
    fullname: Lottermoser
– volume-title: Metal contamination in Aquatic Environments: Science and Lateral Management
  year: 2008
  ident: C7EM00171A-(cit15)/*[position()=1]
  contributor:
    fullname: Luoma
– volume-title: Aqueous environmental geochemistry
  year: 1997
  ident: C7EM00171A-(cit71)/*[position()=1]
  contributor:
    fullname: Langmuir
– volume-title: User's guide to PHREEQC (Version 2): a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations
  year: 1999
  ident: C7EM00171A-(cit44)/*[position()=1]
  contributor:
    fullname: Parkhurst
– volume: 60
  start-page: 193
  year: 2001
  ident: C7EM00171A-(cit79)/*[position()=1]
  publication-title: Eng. Geol.
  doi: 10.1016/S0013-7952(00)00101-0
  contributor:
    fullname: Mulligan
– volume: 7
  start-page: 403
  year: 1993
  ident: C7EM00171A-(cit1)/*[position()=1]
  publication-title: Hydrol. Processes
  doi: 10.1002/hyp.3360070406
  contributor:
    fullname: Horowitz
– volume: 2
  start-page: 80
  year: 2006
  ident: C7EM00171A-(cit17)/*[position()=1]
  publication-title: Integr. Environ. Assess. Manage.
  doi: 10.1002/ieam.5630020114
  contributor:
    fullname: Apitz
– volume-title: A primer on sediment-trace element chemistry
  year: 1991
  ident: C7EM00171A-(cit74)/*[position()=1]
  contributor:
    fullname: Horowitz
– volume: 152
  start-page: 193
  year: 2008
  ident: C7EM00171A-(cit37)/*[position()=1]
  publication-title: Environ. Pollut.
  doi: 10.1016/j.envpol.2007.05.011
  contributor:
    fullname: Taylor
– volume-title: User's manual for WATEQ4F, with revised thermodynamic data base and test cases for calculating speciation of major, trace, and redox elements in natural waters
  year: 1991
  ident: C7EM00171A-(cit46)/*[position()=1]
  contributor:
    fullname: Ball
– volume: 34
  start-page: 329
  year: 2015
  ident: C7EM00171A-(cit24)/*[position()=1]
  publication-title: Mine Water Environ.
  doi: 10.1007/s10230-015-0344-6
  contributor:
    fullname: Navarro
– volume: 20
  start-page: 7699
  year: 2013
  ident: C7EM00171A-(cit58)/*[position()=1]
  publication-title: Environ. Sci. Pollut. Res.
  doi: 10.1007/s11356-013-1515-2
  contributor:
    fullname: Palumbo-Roe
– volume: 10
  start-page: 227
  year: 1996
  ident: C7EM00171A-(cit72)/*[position()=1]
  publication-title: Hydrol. Processes
  doi: 10.1002/(SICI)1099-1085(199602)10:2<227::AID-HYP357>3.0.CO;2-X
  contributor:
    fullname: Foster
– ident: C7EM00171A-(cit75)/*[position()=1]
– volume-title: Aqueous pyrite oxidation and the consequent formation of secondary iron minerals
  year: 1982
  ident: C7EM00171A-(cit62)/*[position()=1]
  contributor:
    fullname: Nordstrom
– volume: 61
  start-page: 211
  year: 1989
  ident: C7EM00171A-(cit70)/*[position()=1]
  publication-title: Environ. Pollut.
  doi: 10.1016/0269-7491(89)90242-X
  contributor:
    fullname: Douben
– volume-title: Geology of the Northern Pennine orefield, Stainmore to Craven. Economic Memoir of British Geological Survey
  year: 1985
  ident: C7EM00171A-(cit59)/*[position()=1]
  contributor:
    fullname: Dunham
– volume: 30
  start-page: 72
  year: 1996
  ident: C7EM00171A-(cit69)/*[position()=1]
  publication-title: Environ. Sci. Technol.
  doi: 10.1021/es9500724
  contributor:
    fullname: Hudson-Edwards
– volume-title: Report on ecological sampling to assess the impacts of metal pollution: Hebden Beck and Ashfoldside Beck
  year: 2014
  ident: C7EM00171A-(cit81)/*[position()=1]
  contributor:
    fullname: Environment Agency
– volume: 26
  start-page: 1777
  year: 2011
  ident: C7EM00171A-(cit56)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/j.apgeochem.2011.06.002
  contributor:
    fullname: Nordstrom
– volume: 2
  start-page: 22
  year: 2013
  ident: C7EM00171A-(cit68)/*[position()=1]
  publication-title: Environ. Pollut.
  doi: 10.5539/ep.v2n4p22
  contributor:
    fullname: Sims
– volume: 407
  start-page: 5435
  year: 2009
  ident: C7EM00171A-(cit21)/*[position()=1]
  publication-title: Sci. Total Environ.
  doi: 10.1016/j.scitotenv.2009.06.019
  contributor:
    fullname: Mayes
– volume: 350
  start-page: 25
  year: 2008
  ident: C7EM00171A-(cit65)/*[position()=1]
  publication-title: J. Hydrol.
  doi: 10.1016/j.jhydrol.2007.11.022
  contributor:
    fullname: Cánovas
– volume: 20
  start-page: 1320
  year: 2005
  ident: C7EM00171A-(cit28)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/j.apgeochem.2005.01.011
  contributor:
    fullname: Sánchez España
– start-page: 37
  volume-title: Humber River Basin District: Hebden Beck: WFD Investigation, Mining Pollution: Catchment Characterisation Report
  year: 2014
  ident: C7EM00171A-(cit39)/*[position()=1]
  contributor:
    fullname: Barber
– volume: 33
  start-page: 3347
  year: 1999
  ident: C7EM00171A-(cit55)/*[position()=1]
  publication-title: Environ. Sci. Technol.
  doi: 10.1021/es980823c
  contributor:
    fullname: Balistrieri
– volume: 42
  start-page: 2017
  year: 2012
  ident: C7EM00171A-(cit13)/*[position()=1]
  publication-title: Crit. Rev. Environ. Sci. Technol.
  doi: 10.1080/10643389.2011.574103
  contributor:
    fullname: Byrne
– volume: 113
  start-page: 56
  year: 2012
  ident: C7EM00171A-(cit60)/*[position()=1]
  publication-title: J. Geochem. Explor.
  doi: 10.1016/j.gexplo.2011.06.001
  contributor:
    fullname: Iavazzo
– volume: 21
  start-page: 121
  year: 2002
  ident: C7EM00171A-(cit4)/*[position()=1]
  publication-title: Mine Water Environ.
  doi: 10.1007/s102300200033
  contributor:
    fullname: Nagorski
– volume: 58
  start-page: 125
  year: 1997
  ident: C7EM00171A-(cit34)/*[position()=1]
  publication-title: J. Geochem. Explor.
  doi: 10.1016/S0375-6742(96)00064-7
  contributor:
    fullname: Gosar
– volume: 14
  start-page: 1139
  year: 2006
  ident: C7EM00171A-(cit23)/*[position()=1]
  publication-title: J. Cleaner Prod.
  doi: 10.1016/j.jclepro.2004.09.006
  contributor:
    fullname: Akcil
– volume: 335
  start-page: 1013
  year: 2003
  ident: C7EM00171A-(cit54)/*[position()=1]
  publication-title: C. R. Geosci.
  doi: 10.1016/j.crte.2003.09.006
  contributor:
    fullname: Ettler
– volume: 333
  start-page: 267
  year: 2004
  ident: C7EM00171A-(cit9)/*[position()=1]
  publication-title: Sci. Total Environ.
  doi: 10.1016/j.scitotenv.2004.05.012
  contributor:
    fullname: Olías
– volume: 23
  start-page: 1022
  year: 2014
  ident: C7EM00171A-(cit10)/*[position()=1]
  publication-title: Ecotoxicology
  doi: 10.1007/s10646-014-1246-2
  contributor:
    fullname: Oulton
– volume: 320
  start-page: 189
  year: 2004
  ident: C7EM00171A-(cit5)/*[position()=1]
  publication-title: Sci. Total Environ.
  doi: 10.1016/j.scitotenv.2003.08.011
  contributor:
    fullname: Miller
– volume: 22
  start-page: 415
  year: 2007
  ident: C7EM00171A-(cit30)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/j.apgeochem.2006.09.008
  contributor:
    fullname: Desbarats
– volume: 34
  start-page: 453
  year: 2009
  ident: C7EM00171A-(cit78)/*[position()=1]
  publication-title: Earth Surf. Processes Landforms
  doi: 10.1002/esp.1762
  contributor:
    fullname: Dennis
– volume: 15
  start-page: 393
  year: 2013
  ident: C7EM00171A-(cit82)/*[position()=1]
  publication-title: Environ. Sci.: Processes Impacts
  contributor:
    fullname: Byrne
– volume: 20
  start-page: 7570
  year: 2013
  ident: C7EM00171A-(cit14)/*[position()=1]
  publication-title: Environ. Sci. Pollut. Res.
  doi: 10.1007/s11356-013-1513-4
  contributor:
    fullname: Jones
– volume: 14
  start-page: 35
  year: 2016
  ident: C7EM00171A-(cit6)/*[position()=1]
  publication-title: Nat. Conservat.
  doi: 10.1016/j.ncon.2016.10.003
  contributor:
    fullname: Fernandes
– start-page: 20
  volume-title: Standard methods for the Examination of Water and Wastewater
  year: 1995
  ident: C7EM00171A-(cit41)/*[position()=1]
  contributor:
    fullname: Apha
– volume-title: Floodplain processes.
  year: 1996
  ident: C7EM00171A-(cit2)/*[position()=1]
  contributor:
    fullname: Macklin
– volume: 41
  start-page: 367
  year: 2008
  ident: C7EM00171A-(cit19)/*[position()=1]
  publication-title: Environ. Manage.
  doi: 10.1007/s00267-007-9033-y
  contributor:
    fullname: Dodds
– volume: vol. 1013
  volume-title: Metal biogeochemistry in surface-water systems; a review of principles and concepts
  year: 1988
  ident: C7EM00171A-(cit16)/*[position()=1]
  contributor:
    fullname: Elder
– ident: C7EM00171A-(cit57)/*[position()=1]
  contributor:
    fullname: Osbourn
– volume: 98
  start-page: 11897
  year: 2001
  ident: C7EM00171A-(cit61)/*[position()=1]
  publication-title: Proc. Natl. Acad. Sci. U. S. A.
  doi: 10.1073/pnas.201150998
  contributor:
    fullname: Templeton
– volume: vol. 198
  volume-title: Secondary minerals in the abandoned mines of Nenthead, Cumbria as sinks for pollutant metals
  year: 2002
  ident: C7EM00171A-(cit49)/*[position()=1]
  contributor:
    fullname: Nuttall
– volume-title: The Grassington Mines
  year: 1993
  ident: C7EM00171A-(cit40)/*[position()=1]
  contributor:
    fullname: Gill
– volume-title: Metal removal and secondary contamination in a passive metal mine drainage treatment system. 10th International Conference on Acid Rock Drainage & IMWA International Conference
  year: 2015
  ident: C7EM00171A-(cit80)/*[position()=1]
  contributor:
    fullname: Jarvis
– volume: 17
  start-page: 284
  year: 2017
  ident: C7EM00171A-(cit48)/*[position()=1]
  publication-title: Procedia Earth Planet. Sci.
  doi: 10.1016/j.proeps.2016.12.056
  contributor:
    fullname: Tame
– volume: 4
  start-page: 52
  year: 2014
  ident: C7EM00171A-(cit67)/*[position()=1]
  publication-title: Minerals
  doi: 10.3390/min4010052
  contributor:
    fullname: Lynch
– volume: 67
  start-page: 205
  year: 2003
  ident: C7EM00171A-(cit8)/*[position()=1]
  publication-title: Mineral. Mag.
  doi: 10.1180/0026461036720095
  contributor:
    fullname: Hudson-Edwards
– volume: 62
  start-page: 547
  year: 2005
  ident: C7EM00171A-(cit36)/*[position()=1]
  publication-title: Estuarine, Coastal Shelf Sci.
  doi: 10.1016/j.ecss.2004.09.017
  contributor:
    fullname: Cave
– volume: 23
  start-page: 203
  year: 2008
  ident: C7EM00171A-(cit27)/*[position()=1]
  publication-title: Appl. Geochem.
  doi: 10.1016/j.apgeochem.2007.10.003
  contributor:
    fullname: Cravotta III
– volume: 58
  start-page: 101
  year: 1997
  ident: C7EM00171A-(cit33)/*[position()=1]
  publication-title: J. Geochem. Explor.
  doi: 10.1016/S0375-6742(96)00073-8
  contributor:
    fullname: Miller
– volume: vol. 6
  volume-title: The environmental geochemistry of mineral deposits. Part B: case studies and research topics
  year: 1999
  ident: C7EM00171A-(cit25)/*[position()=1]
  contributor:
    fullname: Plumlee
– volume: 54
  start-page: 261
  year: 2001
  ident: C7EM00171A-(cit12)/*[position()=1]
  publication-title: Earth-Sci. Rev.
  doi: 10.1016/S0012-8252(01)00032-0
  contributor:
    fullname: Warren
– start-page: 436
  volume-title: The Geochemistry of Natural Waters: Surface and Groundwater Environments
  year: 1997
  ident: C7EM00171A-(cit47)/*[position()=1]
  contributor:
    fullname: Drever
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Snippet Point and diffuse pollution from metal mining has led to severe environmental damage worldwide. Mine drainage is a significant problem for riverine ecosystems,...
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StartPage 1061
SubjectTerms Carbonates - analysis
Environmental Monitoring - methods
Geologic Sediments - chemistry
Lead - analysis
Mining
Rivers - chemistry
United Kingdom
Waste Water - chemistry
Water Pollutants, Chemical - analysis
Zinc - analysis
Title Understanding the mobilisation of metal pollution associated with historical mining in a carboniferous upland catchment
URI https://www.ncbi.nlm.nih.gov/pubmed/28752871
https://search.proquest.com/docview/1924597757
Volume 19
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