Organic and solution-processed tandem solar cells with 17.3% efficiency
Tandem solar cells can boost efficiency by using a wider range of the solar spectrum. The bandgap of organic semiconductors can be tuned over a wide range, but, for a two-terminal device that directly connects the cells, the currents produced must be nearly equal. Meng et al. used a semiempirical an...
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| Published in | Science (American Association for the Advancement of Science) Vol. 361; no. 6407; pp. 1094 - 1098 |
|---|---|
| Main Authors | , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
The American Association for the Advancement of Science
14.09.2018
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Tandem solar cells can boost efficiency by using a wider range of the solar spectrum. The bandgap of organic semiconductors can be tuned over a wide range, but, for a two-terminal device that directly connects the cells, the currents produced must be nearly equal. Meng
et al.
used a semiempirical analysis to choose well-matched top- and bottom-cell active layers. They used solution processing to fabricate an inverted tandem device that has a power conversion efficiency as high as 17.4%.
Science
, this issue p.
1094
A semi-empirical analysis helped to optimize materials for a tandem organic solar cell with high power conversion efficiency.
Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved. |
|---|---|
| AbstractList | Tandem solar cells can boost efficiency by using a wider range of the solar spectrum. The bandgap of organic semiconductors can be tuned over a wide range, but, for a two-terminal device that directly connects the cells, the currents produced must be nearly equal. Meng
et al.
used a semiempirical analysis to choose well-matched top- and bottom-cell active layers. They used solution processing to fabricate an inverted tandem device that has a power conversion efficiency as high as 17.4%.
Science
, this issue p.
1094
A semi-empirical analysis helped to optimize materials for a tandem organic solar cell with high power conversion efficiency.
Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved. Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved. Tailoring tandem organicsTandem solar cells can boost efficiency by using a wider range of the solar spectrum. The bandgap of organic semiconductors can be tuned over a wide range, but, for a two-terminal device that directly connects the cells, the currents produced must be nearly equal. Meng et al. used a semiempirical analysis to choose well-matched top- and bottom-cell active layers. They used solution processing to fabricate an inverted tandem device that has a power conversion efficiency as high as 17.4%.Science, this issue p. 1094Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved. Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved.Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental reason for their low performance is the low charge mobility of organic materials, leading to a limit on the active-layer thickness and efficient light absorption. In this work, guided by a semi-empirical model analysis and using the tandem cell strategy to overcome such issues, and taking advantage of the high diversity and easily tunable band structure of organic materials, a record and certified 17.29% power conversion efficiency for a two-terminal monolithic solution-processed tandem OPV is achieved. |
| Author | Zhang, Xin Xiao, Zuo Cao, Yong Ke, Xin Li, Chenxi Yip, Hin-Lap Wang, Yanbo Xia, Ruoxi Meng, Lingxian Chen, Yongsheng Zhang, Yamin Wan, Xiangjian Ding, Liming |
| Author_xml | – sequence: 1 givenname: Lingxian orcidid: 0000-0003-2464-6247 surname: Meng fullname: Meng, Lingxian organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China – sequence: 2 givenname: Yamin surname: Zhang fullname: Zhang, Yamin organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China – sequence: 3 givenname: Xiangjian orcidid: 0000-0001-5266-8510 surname: Wan fullname: Wan, Xiangjian organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China – sequence: 4 givenname: Chenxi surname: Li fullname: Li, Chenxi organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China – sequence: 5 givenname: Xin orcidid: 0000-0002-4611-0286 surname: Zhang fullname: Zhang, Xin organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China – sequence: 6 givenname: Yanbo surname: Wang fullname: Wang, Yanbo organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China – sequence: 7 givenname: Xin surname: Ke fullname: Ke, Xin organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China – sequence: 8 givenname: Zuo orcidid: 0000-0003-3705-7716 surname: Xiao fullname: Xiao, Zuo organization: Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China – sequence: 9 givenname: Liming orcidid: 0000-0001-6437-9150 surname: Ding fullname: Ding, Liming organization: Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China – sequence: 10 givenname: Ruoxi surname: Xia fullname: Xia, Ruoxi organization: Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, China – sequence: 11 givenname: Hin-Lap orcidid: 0000-0002-5750-9751 surname: Yip fullname: Yip, Hin-Lap organization: Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, China – sequence: 12 givenname: Yong surname: Cao fullname: Cao, Yong organization: Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, China – sequence: 13 givenname: Yongsheng orcidid: 0000-0003-1448-8177 surname: Chen fullname: Chen, Yongsheng organization: State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, Tianjin, 300071, China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30093603$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works |
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| DOI | 10.1126/science.aat2612 |
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| Snippet | Tandem solar cells can boost efficiency by using a wider range of the solar spectrum. The bandgap of organic semiconductors can be tuned over a wide range,... Although organic photovoltaic (OPV) cells have many advantages, their performance still lags far behind that of other photovoltaic platforms. A fundamental... Tailoring tandem organicsTandem solar cells can boost efficiency by using a wider range of the solar spectrum. The bandgap of organic semiconductors can be... |
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| SubjectTerms | Charge materials Efficiency Electromagnetic absorption Empirical analysis Energy conversion efficiency Organic materials Organic semiconductors Photovoltaic cells Photovoltaics Solar cells Thickness |
| Title | Organic and solution-processed tandem solar cells with 17.3% efficiency |
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