Synthesis and nonlinear optical properties of copolymers of fluoro-containing bisphenol A and chromophores

• Published in: Chinese chemical letters Vol. 22; no. 11; pp. 1367 - 1370
• Main Authors: Shi, Jie Ping, Yang, Hui, Wei, Li, Hu, Hong Wen, Lu, Guo Yuan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2011; Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China
• Subjects: Mitsunobu reaction; Mitsunobu反应; NLO chromophores; NLO materials; Ring-locked triene; 双酚A; 可见吸收光谱; 合成; 含氟共聚物; 生色; 非线性光学性质; 非线性光学系数; Ring-locked triene; NLO materials; Mitsunobu reaction; NLO chromophores

A series of new fluoro-containing copolymers have been synthesized by a Mitsunobu reaction with 4,4＇-（hexafluoroisopropylidene） bisphenol A（6FBPA） and the corresponding N,N-dihydroxyethylaminoaryl azo or ring-locked triene compounds, which have high thermal stability and good solubility in organic s...