Rheological characterization of liquid electrolytes for drop-on-demand inkjet printing

Physico-chemical properties of inkjet printing liquids significantly affect the quality of print-out, thus being the key parameter in the performance of printed electronic device (PEDs). Complex hydrodynamic interactions that inks are subjected to in an inkjet printing device has an influence on the...

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Published inOrganic electronics Vol. 38; pp. 307 - 315
Main Authors Özkan, Merve, Dimic-Misic, Katarina, Karakoc, Alp, Hashmi, Syed Ghufran, Lund, Peter, Maloney, Thad, Paltakari, Jouni
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.11.2016
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Abstract Physico-chemical properties of inkjet printing liquids significantly affect the quality of print-out, thus being the key parameter in the performance of printed electronic device (PEDs). Complex hydrodynamic interactions that inks are subjected to in an inkjet printing device has an influence on their rheological response, thus final drop formation, jetting, and drying kinetics. This paper provides a systematic comparison of three PED electrolytes based on different solvents i.e. Sulfolane, 3-Methoxypropionitrile and Acetonitrile that gave them different physico-chemical properties. Rheological properties of printed electrolytes were found to strongly influence the quality of print-outs, which is investigated both optically and morphologically. Best printing results were obtained with the sulfolane-based electrolyte that has the most uniform temperature and shear rate dependent rheological behavior as well as the lowest evaporation rate. By carefully controlling the printing temperature window, it is possible to subject PED electrolytes to higher shearing viscosity profiles while avoiding undesirable dilatant behavior which results in clogged printing nozzles and disrupted droplet trajectory. [Display omitted] •The degree of dilatancy decreases the quality of inkjet printed patterns.•High printing temperature lowers dilatant behavior of inks, thus, accumulation of ink on nozzle edges.•In rapid evaporation case, less dilatancy can be dominated by agglomeration, which jeopardizes functionality of nozzles.
AbstractList Physico-chemical properties of inkjet printing liquids significantly affect the quality of print-out, thus being the key parameter in the performance of printed electronic device (PEDs). Complex hydrodynamic interactions that inks are subjected to in an inkjet printing device has an influence on their rheological response, thus final drop formation, jetting, and drying kinetics. This paper provides a systematic comparison of three PED electrolytes based on different solvents i.e. Sulfolane, 3-Methoxypropionitrile and Acetonitrile that gave them different physico-chemical properties. Rheological properties of printed electrolytes were found to strongly influence the quality of print-outs, which is investigated both optically and morphologically. Best printing results were obtained with the sulfolane-based electrolyte that has the most uniform temperature and shear rate dependent rheological behavior as well as the lowest evaporation rate. By carefully controlling the printing temperature window, it is possible to subject PED electrolytes to higher shearing viscosity profiles while avoiding undesirable dilatant behavior which results in clogged printing nozzles and disrupted droplet trajectory. [Display omitted] •The degree of dilatancy decreases the quality of inkjet printed patterns.•High printing temperature lowers dilatant behavior of inks, thus, accumulation of ink on nozzle edges.•In rapid evaporation case, less dilatancy can be dominated by agglomeration, which jeopardizes functionality of nozzles.
Author Karakoc, Alp
Hashmi, Syed Ghufran
Özkan, Merve
Paltakari, Jouni
Maloney, Thad
Dimic-Misic, Katarina
Lund, Peter
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Keywords Inkjet printing
Dye-sensitized solar cells
Electrolyte
Rheology
Dilatancy
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Snippet Physico-chemical properties of inkjet printing liquids significantly affect the quality of print-out, thus being the key parameter in the performance of...
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SubjectTerms Dilatancy
Dye-sensitized solar cells
Electrolyte
Inkjet printing
Rheology
Title Rheological characterization of liquid electrolytes for drop-on-demand inkjet printing
URI https://dx.doi.org/10.1016/j.orgel.2016.09.001
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