Rheological characterization of liquid electrolytes for drop-on-demand inkjet printing
Physico-chemical properties of inkjet printing liquids significantly affect the quality of print-out, thus being the key parameter in the performance of printed electronic device (PEDs). Complex hydrodynamic interactions that inks are subjected to in an inkjet printing device has an influence on the...
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Published in | Organic electronics Vol. 38; pp. 307 - 315 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.11.2016
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Abstract | Physico-chemical properties of inkjet printing liquids significantly affect the quality of print-out, thus being the key parameter in the performance of printed electronic device (PEDs). Complex hydrodynamic interactions that inks are subjected to in an inkjet printing device has an influence on their rheological response, thus final drop formation, jetting, and drying kinetics. This paper provides a systematic comparison of three PED electrolytes based on different solvents i.e. Sulfolane, 3-Methoxypropionitrile and Acetonitrile that gave them different physico-chemical properties. Rheological properties of printed electrolytes were found to strongly influence the quality of print-outs, which is investigated both optically and morphologically. Best printing results were obtained with the sulfolane-based electrolyte that has the most uniform temperature and shear rate dependent rheological behavior as well as the lowest evaporation rate. By carefully controlling the printing temperature window, it is possible to subject PED electrolytes to higher shearing viscosity profiles while avoiding undesirable dilatant behavior which results in clogged printing nozzles and disrupted droplet trajectory.
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•The degree of dilatancy decreases the quality of inkjet printed patterns.•High printing temperature lowers dilatant behavior of inks, thus, accumulation of ink on nozzle edges.•In rapid evaporation case, less dilatancy can be dominated by agglomeration, which jeopardizes functionality of nozzles. |
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AbstractList | Physico-chemical properties of inkjet printing liquids significantly affect the quality of print-out, thus being the key parameter in the performance of printed electronic device (PEDs). Complex hydrodynamic interactions that inks are subjected to in an inkjet printing device has an influence on their rheological response, thus final drop formation, jetting, and drying kinetics. This paper provides a systematic comparison of three PED electrolytes based on different solvents i.e. Sulfolane, 3-Methoxypropionitrile and Acetonitrile that gave them different physico-chemical properties. Rheological properties of printed electrolytes were found to strongly influence the quality of print-outs, which is investigated both optically and morphologically. Best printing results were obtained with the sulfolane-based electrolyte that has the most uniform temperature and shear rate dependent rheological behavior as well as the lowest evaporation rate. By carefully controlling the printing temperature window, it is possible to subject PED electrolytes to higher shearing viscosity profiles while avoiding undesirable dilatant behavior which results in clogged printing nozzles and disrupted droplet trajectory.
[Display omitted]
•The degree of dilatancy decreases the quality of inkjet printed patterns.•High printing temperature lowers dilatant behavior of inks, thus, accumulation of ink on nozzle edges.•In rapid evaporation case, less dilatancy can be dominated by agglomeration, which jeopardizes functionality of nozzles. |
Author | Karakoc, Alp Hashmi, Syed Ghufran Özkan, Merve Paltakari, Jouni Maloney, Thad Dimic-Misic, Katarina Lund, Peter |
Author_xml | – sequence: 1 givenname: Merve surname: Özkan fullname: Özkan, Merve email: merve.ozkan@aalto.fi, merve.ozkan85@gmail.com organization: Department of Forest Products Technology, School of Chemical Technology, Aalto University, Finland – sequence: 2 givenname: Katarina surname: Dimic-Misic fullname: Dimic-Misic, Katarina organization: Department of Forest Products Technology, School of Chemical Technology, Aalto University, Finland – sequence: 3 givenname: Alp surname: Karakoc fullname: Karakoc, Alp organization: Department of Forest Products Technology, School of Chemical Technology, Aalto University, Finland – sequence: 4 givenname: Syed Ghufran surname: Hashmi fullname: Hashmi, Syed Ghufran organization: New Energy Technologies Group, Department of Applied Physics, Aalto University, Finland – sequence: 5 givenname: Peter surname: Lund fullname: Lund, Peter organization: New Energy Technologies Group, Department of Applied Physics, Aalto University, Finland – sequence: 6 givenname: Thad surname: Maloney fullname: Maloney, Thad organization: Department of Forest Products Technology, School of Chemical Technology, Aalto University, Finland – sequence: 7 givenname: Jouni surname: Paltakari fullname: Paltakari, Jouni organization: Department of Forest Products Technology, School of Chemical Technology, Aalto University, Finland |
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Keywords | Inkjet printing Dye-sensitized solar cells Electrolyte Rheology Dilatancy |
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