Epoxy resins as anticorrosive polymeric materials: A review
Epoxy resins (ERs) represent a special class of organic macromolecules that are comprehensively used for different industrial applications. Because of their macromolecular nature, ERs provide better surface coverage and anticorrosive activities than simple organic corrosion inhibitors. The periphera...
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| Published in | Reactive & functional polymers Vol. 156; p. 104741 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
01.11.2020
Elsevier BV |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Epoxy resins (ERs) represent a special class of organic macromolecules that are comprehensively used for different industrial applications. Because of their macromolecular nature, ERs provide better surface coverage and anticorrosive activities than simple organic corrosion inhibitors. The peripheral polar functional groups of ERs act as adsorption centers during metal-inhibitor interactions. Several ERs in pure and cured forms had been used as anti-corrosive coating materials, especially for carbon steel in acidic and sodium chloride (3% and 3.5%) solutions. Most ERs act as interface and mixed-type corrosion inhibitors. Numerous computational simulations had been used to demonstrate the anticorrosive effects and adsorption behavior of ERs on metallic surfaces. However, most ERs have limited solubility; therefore they are better applied as coating materials for anticorrosive purposes. Literature survey showed that numerous ER-based coatings are developed and successfully employed for carbon steel and aluminum in brine solution. The anticorrosive effect of ER coatings can be further enhanced by adding organic and inorganic additives. The additives block the surface micropores present in ER coatings through which corrosive species can penetrate or diffuse and rapture the coating structures. This review article serves as a comprehensive collection of published reports on anticorrosive effects of pure and cured ERs for different metals and alloys in different electrolytes.
[Display omitted]
•This review article serves describes anticorrosive effects of pure and cured ERs.•Because of their macromolecular nature, they provide much better surface coverage and anticorrosive activity.•Presence of peripheral functional groups enhances their solubilities in polar electrolytes.•Most ERs act as interface and mixed type corrosion inhibitors.•Most ERs have limited solubility; therefore they are better applied as coating materials for anticorrosive purposes. |
|---|---|
| AbstractList | Epoxy resins (ERs) represent a special class of organic macromolecules that are comprehensively used for different industrial applications. Because of their macromolecular nature, ERs provide better surface coverage and anticorrosive activities than simple organic corrosion inhibitors. The peripheral polar functional groups of ERs act as adsorption centers during metal-inhibitor interactions. Several ERs in pure and cured forms had been used as anti-corrosive coating materials, especially for carbon steel in acidic and sodium chloride (3% and 3.5%) solutions. Most ERs act as interface and mixed-type corrosion inhibitors. Numerous computational simulations had been used to demonstrate the anticorrosive effects and adsorption behavior of ERs on metallic surfaces. However, most ERs have limited solubility; therefore they are better applied as coating materials for anticorrosive purposes. Literature survey showed that numerous ER-based coatings are developed and successfully employed for carbon steel and aluminum in brine solution. The anticorrosive effect of ER coatings can be further enhanced by adding organic and inorganic additives. The additives block the surface micropores present in ER coatings through which corrosive species can penetrate or diffuse and rapture the coating structures. This review article serves as a comprehensive collection of published reports on anticorrosive effects of pure and cured ERs for different metals and alloys in different electrolytes. Epoxy resins (ERs) represent a special class of organic macromolecules that are comprehensively used for different industrial applications. Because of their macromolecular nature, ERs provide better surface coverage and anticorrosive activities than simple organic corrosion inhibitors. The peripheral polar functional groups of ERs act as adsorption centers during metal-inhibitor interactions. Several ERs in pure and cured forms had been used as anti-corrosive coating materials, especially for carbon steel in acidic and sodium chloride (3% and 3.5%) solutions. Most ERs act as interface and mixed-type corrosion inhibitors. Numerous computational simulations had been used to demonstrate the anticorrosive effects and adsorption behavior of ERs on metallic surfaces. However, most ERs have limited solubility; therefore they are better applied as coating materials for anticorrosive purposes. Literature survey showed that numerous ER-based coatings are developed and successfully employed for carbon steel and aluminum in brine solution. The anticorrosive effect of ER coatings can be further enhanced by adding organic and inorganic additives. The additives block the surface micropores present in ER coatings through which corrosive species can penetrate or diffuse and rapture the coating structures. This review article serves as a comprehensive collection of published reports on anticorrosive effects of pure and cured ERs for different metals and alloys in different electrolytes. [Display omitted] •This review article serves describes anticorrosive effects of pure and cured ERs.•Because of their macromolecular nature, they provide much better surface coverage and anticorrosive activity.•Presence of peripheral functional groups enhances their solubilities in polar electrolytes.•Most ERs act as interface and mixed type corrosion inhibitors.•Most ERs have limited solubility; therefore they are better applied as coating materials for anticorrosive purposes. |
| ArticleNumber | 104741 |
| Author | Akpan, Ekemini D. Quraishi, M.A. Sherif, El-Sayed M. El Gouri, M. Ebenso, Eno E. Olasunkanmi, Lukman O. Dagdag, O. Verma, Chandrabhan |
| Author_xml | – sequence: 1 givenname: Chandrabhan surname: Verma fullname: Verma, Chandrabhan organization: Center of Research Excellence in Corrosion, Research Institute, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia – sequence: 2 givenname: Lukman O. surname: Olasunkanmi fullname: Olasunkanmi, Lukman O. organization: Department of Chemistry, School of Physical and Chemical Sciences and Materials Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Sciences, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa – sequence: 3 givenname: Ekemini D. surname: Akpan fullname: Akpan, Ekemini D. organization: Department of Chemistry, School of Physical and Chemical Sciences and Materials Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Sciences, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa – sequence: 4 givenname: M.A. surname: Quraishi fullname: Quraishi, M.A. organization: Center of Research Excellence in Corrosion, Research Institute, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia – sequence: 5 givenname: O. surname: Dagdag fullname: Dagdag, O. organization: Laboratory of Industrial Technologies and Services (LITS), Department of Process Engineering, Height School of Technology, Sidi Mohammed Ben Abdallah University, P.O. Box 2427, 30000 Fez, Morocco – sequence: 6 givenname: M. surname: El Gouri fullname: El Gouri, M. organization: Laboratory of Industrial Technologies and Services (LITS), Department of Process Engineering, Height School of Technology, Sidi Mohammed Ben Abdallah University, P.O. Box 2427, 30000 Fez, Morocco – sequence: 7 givenname: El-Sayed M. surname: Sherif fullname: Sherif, El-Sayed M. organization: Center of Excellence for Research in Engineering Materials (CEREM), King Saud University, P.O. Box 800, Al-Riyadh 11421,Saudi Arabia – sequence: 8 givenname: Eno E. surname: Ebenso fullname: Ebenso, Eno E. email: Eno.Ebenso@nwu.ac.za organization: Department of Chemistry, School of Physical and Chemical Sciences and Materials Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Sciences, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa |
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| IngestDate | Mon Jul 14 07:49:17 EDT 2025 Tue Jul 01 03:35:08 EDT 2025 Thu Apr 24 22:56:14 EDT 2025 Fri Feb 23 02:47:52 EST 2024 |
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| Keywords | Cps FT-IR Ecorr XRD MDA Computational simulations BMIM-Cl AA1 GDP Epoxy resins UCIL MCNSs MIC Interface and mixed type inhibitors MHNTs ER EIS Curing process TGEEBA EEW SEM TBBPA RGO HGEMDA Rct NP PGEPBAP Icorr GNP LPR XPS ZPH or ZP PDP Rp HMC TGETBAE DGEDDS ERs GO EDS or EDX LED ECH BADGE or DGEBA NaCl solution HPGCP NACE Anticorrosive coating DGAB TEM PANI-TiN |
| Language | English |
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| PublicationDate | November 2020 2020-11-00 20201101 |
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| PublicationTitle | Reactive & functional polymers |
| PublicationYear | 2020 |
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| Snippet | Epoxy resins (ERs) represent a special class of organic macromolecules that are comprehensively used for different industrial applications. Because of their... |
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| SubjectTerms | Additives Adsorption Aluminum Anticorrosive coating Carbon steels Coating effects Computational simulations Corrosion inhibitors Corrosion prevention Curing process Electrolytes Epoxy resins Functional groups Industrial applications Interface and mixed type inhibitors Literature reviews Macromolecules NaCl solution Polymers Protective coatings Sodium chloride Species diffusion Studies Surface chemistry |
| Title | Epoxy resins as anticorrosive polymeric materials: A review |
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