Widening Electrochemical Window of Mg Salt by Weakly Coordinating Perfluoroalkoxyaluminate Anion for Mg Battery Electrolyte
Energy storage concepts based on multivalent ion chemistries, such as Mg2+, promise very high volumetric energy density, however require improvements in electrolyte (Mg salt and solvent) electrochemical window to reach their full potential. Hypothetically the window of Mg salt could be widened by di...
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Published in | Journal of the Electrochemical Society Vol. 166; no. 8; pp. A1510 - A1519 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
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United States
The Electrochemical Society
2019
IOP Publishing |
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Abstract | Energy storage concepts based on multivalent ion chemistries, such as Mg2+, promise very high volumetric energy density, however require improvements in electrolyte (Mg salt and solvent) electrochemical window to reach their full potential. Hypothetically the window of Mg salt could be widened by disfavoring the cathodic decomposition pathway of a thermodynamically and anodically stable anion, rendering it kinetically inert toward Mg+-mediated reduction. Computational and electrochemical analyses on Mg[TPFA]2 ([TPFA]− = [Al{OC(CF3)3}4]−) support this hypothesis, and showcase a widened electrochemical window as a result of mitigated cathodic decomposition as well as enhanced anodic stability from electron-withdrawing CF3 groups. Detailed NMR and IR spectroscopy and scanning electron microscopy/energy-dispersive X-ray spectroscopy further support that the weak coordination to Mg2+ in solution is important for maintaining the wide electrochemical window of Mg salt. |
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AbstractList | Energy storage concepts based on multivalent ion chemistries, such as Mg2+, promise very high volumetric energy density, however require improvements in electrolyte (Mg salt and solvent) electrochemical window to reach their full potential. Hypothetically the window of Mg salt could be widened by disfavoring the cathodic decomposition pathway of a thermodynamically and anodically stable anion, rendering it kinetically inert toward Mg+-mediated reduction. Computational and electrochemical analyses on Mg[TPFA]2 ([TPFA]- = [Al{OC(CF3)3}4]-) support this hypothesis, and showcase a widened electrochemical window as a result of mitigated cathodic decomposition as well as enhanced anodic stability from electron-withdrawing CF3 groups. Detailed NMR and IR spectroscopy and scanning electron microscopy/energy-dispersive X-ray spectroscopy further support that the weak coordination to Mg2+ in solution is important for maintaining the wide electrochemical window of Mg salt. Energy storage concepts based on multivalent ion chemistries, such as Mg2+, promise very high volumetric energy density, however require improvements in electrolyte (Mg salt and solvent) electrochemical window to reach their full potential. Hypothetically the window of Mg salt could be widened by disfavoring the cathodic decomposition pathway of a thermodynamically and anodically stable anion, rendering it kinetically inert toward Mg+-mediated reduction. Computational and electrochemical analyses on Mg[TPFA]2 ([TPFA]− = [Al{OC(CF3)3}4]−) support this hypothesis, and showcase a widened electrochemical window as a result of mitigated cathodic decomposition as well as enhanced anodic stability from electron-withdrawing CF3 groups. Detailed NMR and IR spectroscopy and scanning electron microscopy/energy-dispersive X-ray spectroscopy further support that the weak coordination to Mg2+ in solution is important for maintaining the wide electrochemical window of Mg salt. |
Author | Liao, Chen Ingram, Brian J. Connell, Justin G. Lau, Ka-Cheong Persson, Kristin A. Zavadil, Kevin R. Carino, Emily V. Hahn, Nathan T. Seguin, Trevor J. |
Author_xml | – sequence: 1 givenname: Ka-Cheong orcidid: 0000-0002-3726-163X surname: Lau fullname: Lau, Ka-Cheong organization: Argonne National Laboratory Chemical Sciences and Engineering Division, , USA – sequence: 2 givenname: Trevor J. surname: Seguin fullname: Seguin, Trevor J. organization: Lawrence Berkeley National Laboratory Energy Technologies Division, , USA – sequence: 3 givenname: Emily V. surname: Carino fullname: Carino, Emily V. organization: Joint Center for Energy Storage Research , USA – sequence: 4 givenname: Nathan T. surname: Hahn fullname: Hahn, Nathan T. organization: Sandia National Laboratories Material, Physical and Chemical Sciences Center, , USA – sequence: 5 givenname: Justin G. surname: Connell fullname: Connell, Justin G. organization: Joint Center for Energy Storage Research , USA – sequence: 6 givenname: Brian J. surname: Ingram fullname: Ingram, Brian J. organization: Argonne National Laboratory Chemical Sciences and Engineering Division, , USA – sequence: 7 givenname: Kristin A. surname: Persson fullname: Persson, Kristin A. organization: University of California Berkeley Department of Materials Science and Engineering, , USA – sequence: 8 givenname: Kevin R. surname: Zavadil fullname: Zavadil, Kevin R. organization: Sandia National Laboratories Material, Physical and Chemical Sciences Center, , USA – sequence: 9 givenname: Chen orcidid: 0000-0001-5168-6493 surname: Liao fullname: Liao, Chen organization: Argonne National Laboratory Chemical Sciences and Engineering Division, , USA |
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Cites_doi | 10.1002/anie.201412202 10.1021/acsenergylett.6b00356 10.1021/acsenergylett.6b00549 10.1038/35037553 10.1021/cr980461r 10.1016/j.mattod.2014.10.040 10.1021/acs.langmuir.7b01609 10.1021/om061076s 10.1021/cr9904009 10.1039/C2EE23686A 10.1021/ar970230r 10.1021/jacs.8b05967 10.1021/acs.jpclett.6b00384 10.1149/1.1387980 10.1039/C3CC47896C 10.1039/C7TA02237A 10.1021/acsenergylett.7b00269 10.1021/jacs.6b04319 10.1021/jacs.6b05626 10.1016/0301-0104(81)85090-2 10.1016/S0022-0728(99)00146-1 10.1016/j.electacta.2010.01.091 10.1039/C4EE03389B 10.1016/j.jpowsour.2010.11.141 10.1021/jacs.5b01004 10.1016/j.ccr.2005.10.023 10.1016/S0065-3055(08)60482-7 10.1002/anie.201902009 10.1038/ncomms1435 10.1039/C5QI00171D 10.1021/acs.chemrev.6b00614 10.1021/acs.jpcc.7b10332 10.1021/ar400188g 10.1039/C5TA00118H 10.1002/chem.200800417 10.1002/anie.201700673 10.1021/ja00072a028 10.1063/1.2834918 10.1021/ja1098512 10.1039/c2ee03029b 10.1002/anie.200300620 10.1021/cr030203g 10.1021/acs.accounts.5b00247 10.1039/c3ta14825d 10.1002/anie.201204913 10.1149/2.0451610jes 10.1016/j.commatsci.2015.02.050 10.1149/1.1391150 10.1021/acsami.6b07262 10.1149/1.1837882 10.1021/acs.chemmater.5b01907 10.1002/ejic.200400436 10.1021/acs.langmuir.7b02243 10.1039/c3ee40871j 10.1039/C8TA10295C |
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References | 2019050213340179000_166.8.A1510.24 2019050213340179000_166.8.A1510.23 2019050213340179000_166.8.A1510.26 2019050213340179000_166.8.A1510.25 2019050213340179000_166.8.A1510.28 2019050213340179000_166.8.A1510.27 2019050213340179000_166.8.A1510.29 2019050213340179000_166.8.A1510.31 2019050213340179000_166.8.A1510.30 2019050213340179000_166.8.A1510.33 2019050213340179000_166.8.A1510.32 2019050213340179000_166.8.A1510.35 2019050213340179000_166.8.A1510.34 2019050213340179000_166.8.A1510.37 2019050213340179000_166.8.A1510.36 2019050213340179000_166.8.A1510.39 2019050213340179000_166.8.A1510.38 2019050213340179000_166.8.A1510.40 2019050213340179000_166.8.A1510.42 2019050213340179000_166.8.A1510.41 2019050213340179000_166.8.A1510.44 2019050213340179000_166.8.A1510.43 2019050213340179000_166.8.A1510.1 2019050213340179000_166.8.A1510.2 2019050213340179000_166.8.A1510.5 2019050213340179000_166.8.A1510.6 2019050213340179000_166.8.A1510.3 2019050213340179000_166.8.A1510.4 2019050213340179000_166.8.A1510.9 2019050213340179000_166.8.A1510.46 2019050213340179000_166.8.A1510.45 2019050213340179000_166.8.A1510.7 2019050213340179000_166.8.A1510.48 2019050213340179000_166.8.A1510.8 2019050213340179000_166.8.A1510.47 2019050213340179000_166.8.A1510.49 2019050213340179000_166.8.A1510.51 2019050213340179000_166.8.A1510.50 2019050213340179000_166.8.A1510.53 2019050213340179000_166.8.A1510.52 2019050213340179000_166.8.A1510.11 2019050213340179000_166.8.A1510.55 2019050213340179000_166.8.A1510.10 2019050213340179000_166.8.A1510.54 2019050213340179000_166.8.A1510.13 2019050213340179000_166.8.A1510.57 2019050213340179000_166.8.A1510.12 2019050213340179000_166.8.A1510.56 2019050213340179000_166.8.A1510.15 2019050213340179000_166.8.A1510.59 2019050213340179000_166.8.A1510.14 2019050213340179000_166.8.A1510.58 2019050213340179000_166.8.A1510.17 2019050213340179000_166.8.A1510.16 2019050213340179000_166.8.A1510.19 2019050213340179000_166.8.A1510.18 2019050213340179000_166.8.A1510.60 2019050213340179000_166.8.A1510.20 2019050213340179000_166.8.A1510.22 2019050213340179000_166.8.A1510.21 |
References_xml | – ident: 2019050213340179000_166.8.A1510.21 doi: 10.1002/anie.201412202 – ident: 2019050213340179000_166.8.A1510.20 doi: 10.1021/acsenergylett.6b00356 – ident: 2019050213340179000_166.8.A1510.49 doi: 10.1021/acsenergylett.6b00549 – ident: 2019050213340179000_166.8.A1510.10 doi: 10.1038/35037553 – ident: 2019050213340179000_166.8.A1510.34 doi: 10.1021/cr980461r – ident: 2019050213340179000_166.8.A1510.1 doi: 10.1016/j.mattod.2014.10.040 – ident: 2019050213340179000_166.8.A1510.27 doi: 10.1021/acs.langmuir.7b01609 – ident: 2019050213340179000_166.8.A1510.11 doi: 10.1021/om061076s – ident: 2019050213340179000_166.8.A1510.59 doi: 10.1021/cr9904009 – ident: 2019050213340179000_166.8.A1510.8 doi: 10.1039/C2EE23686A – ident: 2019050213340179000_166.8.A1510.29 doi: 10.1021/ar970230r – ident: 2019050213340179000_166.8.A1510.23 doi: 10.1021/jacs.8b05967 – ident: 2019050213340179000_166.8.A1510.2 doi: 10.1021/acs.jpclett.6b00384 – ident: 2019050213340179000_166.8.A1510.50 doi: 10.1149/1.1387980 – ident: 2019050213340179000_166.8.A1510.13 doi: 10.1039/C3CC47896C – ident: 2019050213340179000_166.8.A1510.19 doi: 10.1039/C7TA02237A – ident: 2019050213340179000_166.8.A1510.15 doi: 10.1021/acsenergylett.7b00269 – ident: 2019050213340179000_166.8.A1510.26 doi: 10.1021/jacs.6b04319 – ident: 2019050213340179000_166.8.A1510.32 doi: 10.1021/jacs.6b05626 – ident: 2019050213340179000_166.8.A1510.60 doi: 10.1016/0301-0104(81)85090-2 – ident: 2019050213340179000_166.8.A1510.25 doi: 10.1016/S0022-0728(99)00146-1 – ident: 2019050213340179000_166.8.A1510.56 doi: 10.1016/j.electacta.2010.01.091 – ident: 2019050213340179000_166.8.A1510.7 doi: 10.1039/C4EE03389B – ident: 2019050213340179000_166.8.A1510.51 doi: 10.1016/j.jpowsour.2010.11.141 – ident: 2019050213340179000_166.8.A1510.28 doi: 10.1021/jacs.5b01004 – ident: 2019050213340179000_166.8.A1510.52 doi: 10.1016/j.ccr.2005.10.023 – ident: 2019050213340179000_166.8.A1510.44 – ident: 2019050213340179000_166.8.A1510.33 doi: 10.1016/S0065-3055(08)60482-7 – ident: 2019050213340179000_166.8.A1510.39 doi: 10.1002/anie.201902009 – ident: 2019050213340179000_166.8.A1510.16 doi: 10.1038/ncomms1435 – ident: 2019050213340179000_166.8.A1510.22 doi: 10.1039/C5QI00171D – ident: 2019050213340179000_166.8.A1510.3 doi: 10.1021/acs.chemrev.6b00614 – ident: 2019050213340179000_166.8.A1510.37 doi: 10.1021/acs.jpcc.7b10332 – ident: 2019050213340179000_166.8.A1510.31 doi: 10.1021/ar400188g – ident: 2019050213340179000_166.8.A1510.17 doi: 10.1039/C5TA00118H – ident: 2019050213340179000_166.8.A1510.55 – ident: 2019050213340179000_166.8.A1510.54 doi: 10.1002/chem.200800417 – ident: 2019050213340179000_166.8.A1510.45 – ident: 2019050213340179000_166.8.A1510.6 doi: 10.1002/anie.201700673 – ident: 2019050213340179000_166.8.A1510.43 doi: 10.1021/ja00072a028 – ident: 2019050213340179000_166.8.A1510.58 doi: 10.1063/1.2834918 – ident: 2019050213340179000_166.8.A1510.42 – ident: 2019050213340179000_166.8.A1510.12 doi: 10.1021/ja1098512 – ident: 2019050213340179000_166.8.A1510.4 doi: 10.1039/c2ee03029b – ident: 2019050213340179000_166.8.A1510.30 doi: 10.1002/anie.200300620 – ident: 2019050213340179000_166.8.A1510.47 doi: 10.1021/cr030203g – ident: 2019050213340179000_166.8.A1510.36 doi: 10.1021/acs.accounts.5b00247 – ident: 2019050213340179000_166.8.A1510.14 doi: 10.1039/c3ta14825d – ident: 2019050213340179000_166.8.A1510.9 doi: 10.1002/anie.201204913 – ident: 2019050213340179000_166.8.A1510.18 doi: 10.1149/2.0451610jes – ident: 2019050213340179000_166.8.A1510.57 doi: 10.1016/j.commatsci.2015.02.050 – ident: 2019050213340179000_166.8.A1510.35 doi: 10.1149/1.1391150 – ident: 2019050213340179000_166.8.A1510.40 doi: 10.1021/acsami.6b07262 – ident: 2019050213340179000_166.8.A1510.24 doi: 10.1149/1.1837882 – ident: 2019050213340179000_166.8.A1510.38 doi: 10.1021/acs.chemmater.5b01907 – ident: 2019050213340179000_166.8.A1510.53 doi: 10.1002/ejic.200400436 – ident: 2019050213340179000_166.8.A1510.48 doi: 10.1021/acs.langmuir.7b02243 – ident: 2019050213340179000_166.8.A1510.5 doi: 10.1039/c3ee40871j – ident: 2019050213340179000_166.8.A1510.41 doi: 10.1039/C8TA10295C – ident: 2019050213340179000_166.8.A1510.46 |
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Title | Widening Electrochemical Window of Mg Salt by Weakly Coordinating Perfluoroalkoxyaluminate Anion for Mg Battery Electrolyte |
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