The X-ray structure of the monoclinic crystal form of [D-Hyi2, L-Hyi4]meso-valinomycin

• Published in: BIOPOLYM Vol. 42; no. 6; pp. 645 - 650
• Main Authors: Pletnev, V. Z., Ivanov, V. T., Langs, D. A., Burkhart, B. M., Duax, W. L.
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc., A Wiley Company 01.11.1997
• Subjects: Conformations; Crystal structure; Crystallization; Crystallography, X-Ray; Hydrogen bonds; ionophore; Molecular Conformation; Molecular structure; structure and function; Valinomycin - analogs & derivatives; Valinomycin - chemistry; valinomycin analogue; X ray crystallography; x-ray direct methods

The conformation and intermolecular association of [D‐Hyi2, L‐Hyi4]meso‐valinomycin {cyclo[‐D‐Val‐D‐Hyi‐L‐Val‐L‐Hyi‐ (D‐Val‐L‐Hyi‐L‐Val‐D‐Hyi)2‐], C60H102N6O18} in a crystal form obtained from ethanol solution has been determined by x‐ray crystallography. Two depsipeptides and one ethanol molecule p...