Extraction and theoretical study on the complexation of the strontium cation with beauvericin
From extraction experiments and γ -activity measurements, the extraction constant corresponding to the equilibrium Sr 2+ (aq) + 2A − (aq) + 1 (nb) ⇔ 1 ·Sr 2+ (nb) + 2A − (nb) taking place in the two-phase water–nitrobenzene system (A − = picrate, 1 = beauvericin; aq = aqueous phase, nb = nitrobenz...
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Published in | Journal of radioanalytical and nuclear chemistry Vol. 295; no. 2; pp. 1119 - 1122 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Dordrecht
Springer Netherlands
01.02.2013
Springer |
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Abstract | From extraction experiments and
γ
-activity measurements, the extraction constant corresponding to the equilibrium Sr
2+
(aq) + 2A
−
(aq) +
1
(nb) ⇔
1
·Sr
2+
(nb) + 2A
−
(nb) taking place in the two-phase water–nitrobenzene system (A
−
= picrate,
1
= beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log
K
ex
(
1
·Sr
2+
,2A
−
) = −0.6 ± 0.1. Further, the stability constant of the
1
·Sr
2+
complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log
β
nb
(
1
·Sr
2+
) = 8.5 ± 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex
1
·Sr
2+
was derived. |
---|---|
AbstractList | From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Sr2+(aq) + 2A?(aq) +1(nb) ? 1ADTSr2+(nb) + 2A?(nb) taking place in the two-phase wateranitrobenzene system (A? = picrate, 1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K ex(1ADTSr2+,2A?) = ?0.6 A- 0.1. Further, the stability constant of the 1ADTSr2+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 degree C: log ? nb(1ADTSr2+) = 8.5 A- 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex 1ADTSr2+ was derived. From extraction experiments and γ-activity measurements, the extraction constant corresponding to the equilibrium [Sr.sup.2+](aq) + 2[A.sup.-](aq) + 1(nb) [??] 1 x [Sr.sup.2+](nb) + 2[A.sup.-](nb) taking place in the two-phase water-nitrobenzene system ([A.sup.-] = picrate, 1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log [K.sub.ex](1 x [Sr.sup.2+], 2[A.sup.-]) = -0.6 ± 0.1. Further, the stability constant of the 1 x [Sr.sup.2+] complex in nitrobenzene saturated with water was calculated for a temperature of 25°C: log [β.sub.nb](1 x [Sr.sup.2+]) = 8.5 ± 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex 1 x [Sr.sup.2+] was derived. Keywords Strontium cation * Beauvericin * Complexation * Water-nitrobenzene system * Extraction and stability constants * DFT calculations * Complex structure From extraction experiments and γ -activity measurements, the extraction constant corresponding to the equilibrium Sr 2+ (aq) + 2A − (aq) + 1 (nb) ⇔ 1 ·Sr 2+ (nb) + 2A − (nb) taking place in the two-phase water–nitrobenzene system (A − = picrate, 1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K ex ( 1 ·Sr 2+ ,2A − ) = −0.6 ± 0.1. Further, the stability constant of the 1 ·Sr 2+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log β nb ( 1 ·Sr 2+ ) = 8.5 ± 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex 1 ·Sr 2+ was derived. |
Audience | Academic |
Author | Vaňura, P. Toman, P. Makrlík, E. |
Author_xml | – sequence: 1 givenname: E. surname: Makrlík fullname: Makrlík, E. email: makrlik@centrum.cz organization: Faculty of Environmental Sciences, Czech University of Life Sciences – sequence: 2 givenname: P. surname: Toman fullname: Toman, P. organization: Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic – sequence: 3 givenname: P. surname: Vaňura fullname: Vaňura, P. organization: Department of Analytical Chemistry, Institute of Chemical Technology |
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CitedBy_id | crossref_primary_10_1007_s10967_013_2686_5 crossref_primary_10_1016_j_chemphys_2014_05_011 crossref_primary_10_1016_j_molstruc_2015_06_086 crossref_primary_10_1007_s00706_014_1392_5 crossref_primary_10_1007_s00706_014_1165_1 crossref_primary_10_1007_s00706_014_1370_y |
Cites_doi | 10.1021/jp805757d 10.1080/02652030410001713906 10.1135/cccc19840039 10.1063/1.464913 10.1007/s00706-007-0816-x 10.1021/cr9800255 10.1016/S0040-4039(01)88668-8 10.1007/s00706-010-0395-0 10.1021/jp101080h 10.1007/s00706-009-0217-4 10.1080/10610270601089360 10.1128/AEM.68.1.82-85.2002 10.1128/AEM.64.8.3084-3088.1998 10.1103/PhysRevB.37.785 10.1080/10610270701422065 10.1016/0039-9140(85)80110-7 10.1007/s00706-005-0422-8 10.1007/s00706-008-0003-8 10.1080/10610270701278251 10.1021/jp9012575 10.1007/s10967-010-0598-1 10.1002/bip.20506 10.1007/s10967-006-0142-5 10.1080/00268977000101561 10.1021/jp203221k 10.1135/cccc19713253 10.1073/pnas.58.5.1949 10.1021/cr00031a007 10.1007/s00706-009-0178-7 |
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Keywords | Water–nitrobenzene system Complexation Complex structure Beauvericin Strontium cation DFT calculations Extraction and stability constants |
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Snippet | From extraction experiments and
γ
-activity measurements, the extraction constant corresponding to the equilibrium Sr
2+
(aq) + 2A
−
(aq) +
1
(nb) ⇔
1
·Sr
2+... From extraction experiments and γ-activity measurements, the extraction constant corresponding to the equilibrium [Sr.sup.2+](aq) + 2[A.sup.-](aq) + 1(nb) [??]... From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Sr2+(aq) + 2A?(aq) +1(nb) ? 1ADTSr2+(nb) +... |
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StartPage | 1119 |
SubjectTerms | Cationic Chemistry Chemistry and Materials Science Complexation Constants Diagnostic Radiology Extraction Hadrons Heavy Ions Inorganic Chemistry Mathematical analysis Nitrobenzenes Nuclear Chemistry Nuclear Physics Physical Chemistry Strontium |
Title | Extraction and theoretical study on the complexation of the strontium cation with beauvericin |
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